99838-64-9Relevant academic research and scientific papers
Enantioselective total synthesis of (+)-rogioloxepane A
Crimmins, Michael T.,DeBaillie, Amy C.
, p. 3009 - 3011 (2007/10/03)
(Matrix presented) The enantioselective synthesis of (+)-rogioloxepane A has been achieved in 21 steps from 1,5-hexadien-3-ol. The key steps in the synthesis are an asymmetric glycolate alkylation leading to the diene 2 and a subsequent ring-closing metat
Enantio- and Diastereocontrolled Synthesis of Chiral 1,2-Diol Derivatives from (R)-2,3-Di-O-isopropylideneglyceraldehyde: endo- and exo-Brevicomin
Mulzer, Johann,Angermann, Alfred,Muench, Winfried
, p. 825 - 838 (2007/10/02)
All four possible stereoisomers of the insect pheromone brevicomin have been prepared from (R)-2,3-di-O-isopropylideneglyceraldehyde (1) on stereocontrolled routes with ee more than 98-99percent.
