99865-14-2

Usage

InChI:InChI=1/C11H12O2/c1-9(13)11-7-3-2-5-10(11)6-4-8-12/h2-3,5,7-8H,4,6H2,1H3

Upstream product

• 67-66-3 chloroform 
• 4373-13-1 4-methyl-1,2-dihydronaphthalene 
• 51086-31-8 1-methyl-1,2-tetralindiol 
• 200425-59-8 (S)-(+)-1-methyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 39202-04-5 1-methyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 

Downstream Products

• 51086-31-8 1-methyl-1,2,3,4-tetrahydronaphthalene-r-1,c-2-diol 
• 1352630-74-0 1-(2-(4-methylpent-3-en-1-yl)phenyl)ethanone 
• 133103-12-5 1-[2-(3,3-dimethoxy-propyl)-phenyl]-ethanone 

Relevant academic research and scientific papers

Synthesis of β-acetoxy alcohols by PhI(OAc)2-mediated metal-free diastereoselective β-acetoxylation of alcohols

β-Acetoxy alcohols can be synthesized in good yields with excellent diastereoselectivity from tertiary alcohols through PhI(OAc)2-mediated metal-free β-acetoxylation. Mechanistic studies showed that the β-acetoxylation process might undergo dehydration and sequential highly regioselective and diastereoseletive dioxygenation. Gram scale and diverse useful scaffolds could be prepared via this β-acetoxylation process.

Catalytic ketyl-olefin cyclizations enabled by proton-coupled electron transfer

Concerted proton-coupled electron transfer is a key mechanism of substrate activation in biological redox catalysis. However, its applications in organic synthesis remain largely unexplored. Herein, we report the development of a new catalytic protocol fo

Metal-free intramolecular carbonyl-olefin metathesis of ortho-prenylaryl ketones

On treatment with boron trifluoride etherate as a Lewis acid, acetophenone and benzophenone derivatives bearing a prenyl (or a related) side chain in ortho-position were shown to undergo intramolecular carbonyl-olefin metathesis, in the absence of any tra

Thiazol-2-ylidene catalysis in intramolecular crossed aldehyde-ketone benzoin reactions

Intramolecular crossed aldehyde-ketone benzoin-type reactions catalyzed by nucleophilic carbenes, easily generated from commercially available thiazolium salts as precatalysts, are described. Five- and six-membered cyclic acyloins are obtained in moderate to good yields. Depending on the structure of the aldehyde-ketone substrate, an interchange of the alcohol and ketone function of the resulting acyloin is possible. Simple aldehyde-ketones are not good substrates due to the competing intermolecular reaction. Starting from biphenyl-2,2′-dicarbaldehyde, the intermediate acyloin is converted to 9,10-phenanthrenequinone by mild air oxidation.