99893-78-4

Basic information

• Product Name: pent-4-en-1-yl 4-chlorobenzoate
• Synonyms: pent-4-en-1-yl 4-chlorobenzoate
• CAS NO: 99893-78-4
• Molecular Weight: 224.687
• Mol File: 99893-78-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: pent-4-en-1-yl 4-chlorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: pent-4-en-1-yl 4-chlorobenzoate(99893-78-4)
• EPA Substance Registry System: pent-4-en-1-yl 4-chlorobenzoate(99893-78-4)

Safety Data

• Hazardous Substances Data: 99893-78-4(Hazardous Substances Data)

Upstream product

• 74-11-3 para-chlorobenzoic acid 
• 1119-51-3 bromopentene 
• 821-09-0 n-Pent-4-enyl alcohol 
• 122-01-0 4-chloro-benzoyl chloride 

Downstream Products

• 1620563-64-5 7-ethoxy-6,6-difluoro-7-oxoheptyl 4-chlorobenzoate 
• 34672-84-9 1-methoxy-2,2,6,6-tetramethylpiperidine 
• 30764-40-0 1-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propan-2-one 
• 98-86-2 acetophenone 

Relevant articles and documents

Metal-Free Iodoperfluoroalkylation: Photocatalysis versus Frustrated Lewis Pair Catalysis

A comparison of two catalytic, metal-free iodoperfluoroalkylation protocols is presented. Frustrated Lewis pairs [ tBu 3P/B(C 6F 5) 3] or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes as well as insights into the mechanistic details of both reaction pathways are provided.

Halogen-Bond-Promoted Photoactivation of Perfluoroalkyl Iodides: A Photochemical Protocol for Perfluoroalkylation Reactions

A new protocol for photochemical perfluoroalkylation reactions using perfluoroalkyl iodide, amine additive, and THF solvent is reported. This protocol does not require a photoredox catalyst and proceeds at ambient temperature with irradiation from a compact fluorescent lamp, low-intensity UV lamp, or sunlight. This protocol can be applied to the synthesis of perfluoroalkyl-substituted phenanthridines as well as effect the iodo-perfluoroalkylation of alkenes/alkynes and the C-H perfluoroalkylation of electron-rich arenes and heteroarenes. This C-H perfluoroalkylation reaction offers a unique method for site-selective labeling of oligopeptides at the tryptophan residue.