999-99-5Relevant articles and documents
Synthesis, characterization, and theoretical analysis of soluble poly(oxothiazenes): The ambient temperature lewis acid catalyzed in situ polymerization of N-silylsulfonimidoyl chlorides
Aldeva, Victoria,Gezahegn, Sossina,Panahi, Babak,Shuoprasad, Michelle,Ward, Jon,Foucher, Daniel A.,Gossage, Robert A.,McWilliams, Andrew R.
, p. 2562 - 2568 (2013/05/22)
The ambient temperature condensation, to yield low molecular weight poly(methyloxothiazene) (Mw = 1 × 104; PDI = 1.4), can be achieved by the reaction of MeS(O2)NHSiMe3 and SOCl2 - this latter reactio
Method for preparing sulfonimidoyl halides
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, (2008/06/13)
N-triorganosilylsulfonimidoyl halides are prepared using a novel series of reactions from compounds of hexavalent sulfur selected from amides, chlorides and anhydrides of organosulfonic acids. More specifically, the present method relates to the reaction of an N-triorganosilyl- or an N,N-bis(triorganosilyl)-sulfonamide with a triorganodihalophosphorane to form the corresponding sulfonimidoyl halide.