chlorotris(triphenylphosphine)rhodium(i) basic information
reactions
product name: chlorotris(triphenylphosphine)rhodium(i)
synonyms: decarbon;chlorotris(triphenylphosphine)rhodium(i);chlorotris(triphenylphosphine)rhodate (i);tris(triphenylphosphine)chlororhodium;tris(triphenylphosphine)rhodium(1) chloride;tris(triphenylphosphine)rhodium(i) chloride;tris(triphenylphosphine)rhodium(i) chloride polymer bound;wilkinson catalyst
cas: 14694-95-2
mf: c54h45clp3rh
mw: 925.21
einecs: 238-744-5
product categories: metal compounds;catalysts for organic synthesis;classes of metal compounds;homogeneous catalysts;metal complexes;rh (rhodium) compounds;synthetic organic chemistry;transition metal compounds;metal-phosphine complexes;chemical reaction,pharm,electronic,materials;rh
mol file: 14694-95-2.mol
chlorotris(triphenylphosphine)rhodium(i) structure
chlorotris(triphenylphosphine)rhodium(i) chemical properties
melting point 245-250 °c (dec.)
boiling point >170°c
density 1.363; d 1.379
storage temp. 2-8°c
solubility soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. reacts with o{2} in solution
form crystalline powder
color red-brown to maroon
water solubility insoluble
sensitive air sensitive
merck 14,9758
inchikey qeyyhujfsqctae-uhfffaoysa-m
cas database reference 14694-95-2(cas database reference)
nist chemistry reference chlorotris(triphenylphosphine)rhodium(14694-95-2)
epa substance registry system rhodium, chlorotris(triphenylphosphine)-, (sp-4-2)-(14694-95-2)
safety information
hazard codes c,xi
risk statements 34-36/38
safety statements 22-24/25-37/39-28a-26-15-45-36/37/39
ridadr 1759
wgk germany 1
f 8-10-23
tsca yes
hs code 28439090