1017967-97-3Relevant articles and documents
Inflating face-capped Pd6L8 coordination cages
Jansze, Suzanne M.,Ortiz, Daniel,Fadaei Tirani, Farzaneh,Scopelliti, Rosario,Menin, Laure,Severin, Kay
, p. 9529 - 9532 (2018)
Tritopic metalloligands were used to form two Pd6L8-type coordination cages. With molecular weights of more than 15 kDa and Pd?Pd distances of up to 4.2 nm, these complexes are among the largest palladium cages described to date.
Novel self-assembled 2D networks based on zinc metal ion co-ordination: Synthesis and comparative study with 3D networks
Rajwar, Deepa,Liu, Xinfeng,Lim, Zheng Bang,Cho, Sung Ju,Chen, Shi,Thomas, Jens M. H.,Trewin, Abbie,Lam, Yeng Ming,Sum, Tze Chien,Grimsdale, Andrew C.
, p. 17680 - 17693 (2014)
The synthesis of linear and trigonal terpyridine bearing molecules (tpys) and their self-assembly to form novel extended self-assembled 2D networks of trigonal tpys with linear tpys through zinc metal ion (Zn2+) co-ordination is reported. The r
Multiexcitonic Triplet Pair Generation in Oligoacene Dendrimers as Amorphous Solid-State Miniatures
Chi, Chunyan,Hong, Yongseok,Kim, Dongho,Kim, Hyungjun,Kim, Juno,Oh, Juwon,Teo, Hao Ting
, p. 20956 - 20964 (2020)
Singlet fission in organic semiconducting materials has attracted great attention for the potential application in photovoltaic devices. Research interests have been concentrated on identifying working mechanisms of coherent SF processes in crystalline so
Solution-phase dynamic assembly of permanently interlocked aryleneethynylene cages through alkyne metathesis
Wang, Qi,Yu, Chao,Long, Hai,Du, Ya,Jin, Yinghua,Zhang, Wei
, p. 7550 - 7554 (2015)
Highly stable permanently interlocked aryleneethynylene molecular cages were synthesized from simple triyne monomers using dynamic alkyne metathesis. The interlocked complexes are predominantly formed in the reaction solution in the absence of any recogni
H-BPin/KOtBu Promoted Activation of Cobalt Salt to a Heterotopic Catalyst for Highly Selective Cyclotrimerization of Alkynes
Song, Shuo,Li, Chuhan,Liu, Tianfen,Zhang, Panke,Wang, Xiaoming
supporting information, p. 6925 - 6930 (2021/09/14)
A mixture of HBPin with KOtBu was found to activate cobalt salt to form a heterotopic cobalt species that is highly active for catalytic intermolecular trimerization of alkynes. This protocol affords 1,2,4-regioisomers in good yields with high regioselectivities under mild conditions. These salient features, together with the operational simplicity and high efficiency, as well as obviating the use of any costly and/or air sensitive ligands, renders the protocol promising for practical applications.
Porous organic polymer with: In situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
Dong, Ying,Chen, Yun-Qi,Jv, Jing-Jing,Li, Yue,Li, Wen-Han,Dong, Yu-Bin
, p. 21671 - 21678 (2019/07/30)
A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh3)4 catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromoben
Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
Ochiai, Hidenori,Uetake, Yuta,Niwa, Takashi,Hosoya, Takamitsu
supporting information, p. 2482 - 2486 (2017/02/23)
Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
TRIS(CARBOXYANTHRACENYLPHENYL)BENZENE, AND CRYSTALLINE NETWORK COMPLEX AND GAS STORAGE MATERIAL USING THE SAME
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Paragraph 0042-0043, (2017/02/23)
PROBLEM TO BE SOLVED: To provide: a crystalline network complex available as a gas storage material and excellent in water resistance; and a coordination compound to be included in the crystalline network complex. SOLUTION: The invention provides a coordi
In situ formation of well-dispersed palladium nanoparticles immobilized in imidazolium-based organic ionic polymers
Zhao, Huaixia,Wang, Yangxin,Wang, Ruihu
supporting information, p. 10871 - 10874 (2014/10/15)
A new strategy for in situ generation of well-dispersed palladium nanoparticles (NPs) immobilized in imidazolium-based organic ionic polymers was presented. Without extra addition of palladium species, the as-synthesized ionic polymers showed excellent catalytic activity and good reusability in the hydrogenation of nitroarenes. the Partner Organisations 2014.