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CAS

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918882-53-8

2,6-bis(methylthio)benzaldehyde is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 918882-53-8 Structure

  • Basic information

    1. Product Name: 2,6-bis(methylthio)benzaldehyde
    2. Synonyms: 2,6-bis(methylthio)benzaldehyde
    3. CAS NO:918882-53-8
    4. Molecular Formula: C9H10OS2
    5. Molecular Weight: 198.3051
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 918882-53-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2,6-bis(methylthio)benzaldehyde(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2,6-bis(methylthio)benzaldehyde(918882-53-8)
    11. EPA Substance Registry System: 2,6-bis(methylthio)benzaldehyde(918882-53-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 918882-53-8(Hazardous Substances Data)

918882-53-8 Usage

Appearance

Yellow oil The compound has a yellowish color and is in the form of a liquid, which is often referred to as an "oil" in chemistry.

Usage

Fragrance ingredient It is commonly used in the production of perfumes and other cosmetic products due to its strong, sweet, and floral odor with a sharp, fruity undertone.

Usage

Flavoring agent 2,6-bis(methylthio)benzaldehyde is also used in food and beverages to enhance or modify their flavors.

Usage

Synthesis of other organic compounds This chemical serves as a building block or reagent in the creation of other organic compounds through chemical reactions.

Safety precautions

Skin and eye irritation Handling 2,6-bis(methylthio)benzaldehyde may cause irritation to the skin and eyes, so it's important to take necessary precautions when working with this substance.

Storage

Cool, dry place To maintain the stability and safety of 2,6-bis(methylthio)benzaldehyde, it should be stored in a cool, dry place away from direct sunlight and heat sources.

Check Digit Verification of cas no

The CAS Registry Mumber 918882-53-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,1,8,8,8 and 2 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 918882-53:
(8*9)+(7*1)+(6*8)+(5*8)+(4*8)+(3*2)+(2*5)+(1*3)=218
218 % 10 = 8
So 918882-53-8 is a valid CAS Registry Number.

918882-53-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,6-bis(methylsulfanyl)benzaldehyde

1.2 Other means of identification

Product number -
Other names Benzaldehyde,2,6-bis(methylthio)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:918882-53-8 SDS

918882-53-8Relevant articles and documents

Rhodium(III)-Catalyzed Aldehyde C?H Activation and Functionalization with Dioxazolones: An Entry to Imide Synthesis

Massouh, Joe,Petrelli, Antoine,Bellière-Baca, Virginie,Hérault, Damien,Clavier, Hervé

supporting information, p. 831 - 837 (2022/01/06)

A rhodium(III)-based catalytic system has been used to develop a C?H bond activation of benzaldehyde derivatives and subsequent functionalization with dioxazolones in order to afford imides. The importance of the nature of the directing group to perform selectively the aldehydic C?H bond activation has been highlighted. The scope investigation showed that this transformation could be applied to various dioxazolones and many benzaldehyde derivatives as well as an acrolein derivative. Derivatization reactions of the imide products demonstrated the synthetic utility of this rhodium-catalyzed aldehydic C?H amidation.

The Key Role of the Nonchelating Conformation of the Benzylidene Ligand on the Formation and Initiation of Hoveyda-Grubbs Metathesis Catalysts

Bieszczad, Bartosz,Barbasiewicz, Micha?

supporting information, p. 10322 - 10325 (2015/07/07)

Experimental studies of Hoveyda-Grubbs metathesis catalysts reveal important consequences of substitution at the 6-position of the chelating benzylidene ligand. The structural modification varies conformational preferences of the ligand that affects its exchange due to the interaction of the coordinating site with the ruthenium center. As a consequence, when typical S-chelated systems are formed as kinetic trans-Cl2 products, for 6-substituted benzylidenes the preference is altered toward direct formation of thermodynamic cis-Cl2 isomers. Activity data and reactions with tricyclohexylphosphine (PCy3) support also a similar scenario for O-chelated complexes, which display fast trans-Cl2?cis-Cl2 equilibrium observed by NMR EXSY studies. The presented conformational model reveals that catalysts, which cannot adopt the optimal nonchelating conformation of benzylidene ligand, initiate through a high-energy associative mechanism.

Rhodium-catalysed linear-selective alkyne hydroacylation

Poingdestre, Sarah-Jane,Goodacre, Jonathan D.,Weller, Andrew S.,Willis, Michael C.

supporting information; experimental part, p. 6354 - 6356 (2012/07/14)

The use of the electron-rich diphosphine ligand, dcpe, allows the efficient and highly linear selective hydroacylative coupling of aldehydes, including aryl examples, with a range of alkynes.

A convenient preparation of thioether functionalized porphyrins

Pollard, Michael M.,Vederas, John C.

, p. 11908 - 11915 (2007/10/03)

This paper describes a convenient and high yielding three-step approach for the synthesis of trans-tetraphenylporphyrins possessing two thioethers in the ortho positions, which will facilitate the synthesis of more elaborate and complex porphyrin architec

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