Hot Products

Basic Information

Post buying leads

Suppliers

Cas Database

Name	4-Methoxyphenylmagnesium bromide	EINECS	N/A
CAS No.	13139-86-1	Density	0.955 g/mL at 25 °C
PSA	9.23000	LogP	2.34100
Solubility	Severe reaction	Melting Point	N/A
Formula	C₇H₇BrMgO	Boiling Point	65-67 °C
Molecular Weight	211.341	Flash Point	-4 °F
Transport Information	UN 2924 3/PG 2	Appearance	Clear to brown solution when properly stored
Safety	16-26-36/37/39-43B-43-45-6A	Risk Codes	11-14/15-19-34
Molecular Structure		Hazard Symbols	F,C
Synonyms	Magnesium,bromo(p-methoxyphenyl)- (7CI,8CI);p-Methoxyphenylmagnesium bromide (6CI);(4-Methoxyphenyl)magnesium bromide;(p-Anisyl)bromomagnesium;4-Anisylmagnesiumbromide;Bromo(4-methoxyphenyl)magnesium;Bromo(p-methoxyphenyl)magnesium;p-Anisylmagnesium bromide;	Article Data	38

4-Methoxyphenylmagnesium bromide Synthetic route

: 104-92-7
1-bromo-4-methoxy-benzene

: 13139-86-1
4-methoxyphenyl magnesium bromide

Conditions

Conditions	Yield
With magnesium; bromine In diethyl ether
With magnesium; copper(l) iodide In diethyl ether at -78℃; for 0.5h; Grignard reaction; Title compound not separated from byproducts;
With magnesium In tetrahydrofuran at 80℃; for 0.333333h; microwave irradiation;

: 104-92-7
1-bromo-4-methoxy-benzene

: 173433-59-5
7-chloro-1,2,3,4,4a,9b-hexahydro-2-methyl-5H-1,3-ethanoindeno-[1,2-c]pyridin-5-one

A: 173434-18-9
7-Chloro-5-(p-methoxyphenyl)-2-methyl-1,3-ethano-1,2,3,4,4a,9b-hexahydro-5H-indeno[1,2-c]pyridin-5-ol

B: 13139-86-1
4-methoxyphenyl magnesium bromide

Conditions

Conditions	Yield
With magnesium In tetrahydrofuran; dichloromethane

: 104-92-7
1-bromo-4-methoxy-benzene

: 66-71-7
1,10-Phenanthroline

: 106-93-4
ethylene dibromide

: 13139-86-1
4-methoxyphenyl magnesium bromide

Conditions

Conditions	Yield
With iodine; magnesium In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; iso-butanol

: 104-92-7
1-bromo-4-methoxy-benzene

: 52498-02-9
3-(p-methoxyphenyl)cyclobutanone

A: 52498-11-0
1,3-bis(p-methoxyphenyl)cyclobutanol

B: 13139-86-1
4-methoxyphenyl magnesium bromide

Conditions

Conditions	Yield
In tetrahydrofuran

: 104-92-7
1-bromo-4-methoxy-benzene

: 7439-95-4
magnesium

: 13139-86-1
4-methoxyphenyl magnesium bromide

Conditions

Conditions	Yield
With 1,2-dibromomethane In tetrahydrofuran at 40℃; for 1.5h;
In tetrahydrofuran at 20℃; for 2h;
In tetrahydrofuran
In tetrahydrofuran Inert atmosphere;
With lithium chloride In tetrahydrofuran at 0 - 25℃; for 0.5h; Inert atmosphere; Schlenk technique;

: 104-92-7
1-bromo-4-methoxy-benzene

magnesium: magnesium

: 13139-86-1
4-methoxyphenyl magnesium bromide

Conditions

Conditions	Yield
With diethyl ether; iodine
With diethyl ether; iodine; benzene

: 24759-97-5
2-adamantanespiroxirane

: 13139-86-1
4-methoxyphenyl magnesium bromide

: 109610-24-4
2-(p-methoxy)benzyl-2-adamantanol

Conditions

Conditions	Yield
In diethyl ether for 2h; Ambient temperature;	100%

: Benzoic acid (2S,3S)-2-formyl-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl ester

: 13139-86-1
4-methoxyphenyl magnesium bromide

: Benzoic acid (2R,3S)-2-[hydroxy-(4-methoxy-phenyl)-methyl]-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl ester

Conditions

Conditions	Yield
In tetrahydrofuran at -45℃;	100%

: 134869-78-6
(2S,3S)-3-cyano-2,3-epoxy-1-propanol TBS ether

: 13139-86-1
4-methoxyphenyl magnesium bromide

: 139058-52-9
[(2R,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-(4-methoxy-phenyl)-methanone

Conditions

Conditions	Yield
In toluene at -30℃;	100%

: 141334-25-0
2,2,2-trifluoro-1-triphenylsilylethanone

: 13139-86-1
4-methoxyphenyl magnesium bromide

: 1,1-difluoro-2-(4-methoxyphenyl)-2-triphenylsilyloxyethene

Conditions

Conditions	Yield
In tetrahydrofuran 1) -30 deg C, 15 min, 2) rt, 1 h;	100%

4-Methoxyphenylmagnesium bromide Chemical Properties

Molecular Structure of 4-Methoxyphenylmagnesium bromide (CAS No.13139-86-1):

Molecular Formula: C₇H₇BrMgO
Molecular Weight: 211.3389
CAS No: 13139-86-1
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 2
Polar Surface Area: 9.23 Å²
Systematic Name: Bromo(4-methoxyphenyl)magnesium
InChI: InChI=1/C₇H₇O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1/rC7H7BrMgO/c1-10-7-4-2-6(9-8)3-5-7/h2-5H,1H3
InChIKey: JKXAZEXIOPFJSC-DZVGZYEUAY
Std. InChI: InChI=1S/C₇H₇O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
Std. InChIKey: JKXAZEXIOPFJSC-UHFFFAOYSA-M
Product Categories: Aryl;Grignard Reagents;Organometallic Reagents

4-Methoxyphenylmagnesium bromide Safety Profile

Hazard Codes: F, Corrosive C
Risk Statements: 11-14-19-22-34-14/15
R11:Highly flammable.
R14 :Reacts violently with water.
R22:Harmful if swallowed.
R34:Causes burns.
R15:Contact with water liberates extremely flammable gases.
Safety Statements: 16-26-33-36/37/39-45-6A-43B
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33:Take precautionary measures against static discharges.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S6:Keep under ... (there follows the name of an inert gas).
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
RIDADR: UN 2924 3/PG 2
HazardClass: 4.3
PackingGroup: II

4-Methoxyphenylmagnesium bromide Specification

4-Methoxyphenylmagnesium bromide (CAS No.13139-86-1), its synonyms are p-Anisylmagnesium bromide ; Bromo(4-methoxyphenyl)magnesium ; Magnesium, bromo(4-methoxyphenyl)- .

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 13139-86-1