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Antimony trifluoride

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Antimony trifluoride

EINECS 232-009-2
CAS No. 7783-56-4 Density 4.38 g/mL at 25 °C(lit.)
PSA 0.00000 LogP 1.26060
Solubility water: 385 g/100 mL (20°C) Melting Point 292 °C
Formula SbF3 Boiling Point 19.5 °C at 760 mmHg
Molecular Weight 178.745 Flash Point 376oC
Transport Information UN 3260 8/PG 2 Appearance white to grey crystalline powder
Safety 7-26-45-61 Risk Codes 23/24/25-51/53
Molecular Structure Molecular Structure of 7783-56-4 (Antimony (III) fluoride) Hazard Symbols ToxicT,DangerousN,CorrosiveC
Synonyms

Antimonyfluoride (SbF3) (6CI);Antimonous fluoride;Antimony(3+)fluoride;Antimony(III) fluoride;Trifluoroantimony;Trifluorostibine;

Article Data 76

Antimony trifluoride Chemical Properties

Molecular Structure:

Molecular Formula: F3Sb
Molecular Weight: 178.7552
IUPAC Name: Antimony(3+) trifluoride
Synonyms of Antimony trifluoride (CAS NO.7783-56-4): Antimoine fluorure ; Antimoine fluorure [French] ; Antimonous fluoride ; Antimony fluoride ; Antimony trifluoride ; Antimony(III) fluoride (1:3) ; EINECS 232-009-2 ; HSDB 438 ; Stibine, trifluoro- ; Trifluoroantimony ; Trifluorostibine ; Antimony trifluoride, solid ; Antimony trifluoride, solid [NA1549] [Corrosive] ; Antimony trifluoride, solution ; Antimony trifluoride, solution [NA1549] [Corrosive] ; NA1549
CAS NO: 7783-56-4
Classification Code: Reportable Quantity (RQ) = 1000 lb
Melting point: 292 °C 
Enthalpy of Vaporization: 25.54 kJ/mol
Boiling Point: 19.5 °C at 760 mmHg
Vapour Pressure: 922 mmHg at 25°C

Antimony trifluoride Uses

 Antimony trifluoride (CAS NO.7783-56-4) is used as a fluorination reagent in organic chemistry. It is often used in dyeing and pottery.

Antimony trifluoride Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LDLo subcutaneous 224mg/kg (224mg/kg)   Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 124, Pg. 133, 1937.
mouse LD50 oral 804mg/kg (804mg/kg)   Osaka Shiritsu Daigaku Igaku Zasshi. Journal of the Osaka City Medical Center. Vol. 8, Pg. 817, 1959.
mouse LDLo subcutaneous 22900ug/kg (22.9mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 8(7), Pg. 25, 1964.

Antimony trifluoride Consensus Reports

Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right-To-Know List.

Antimony trifluoride Safety Profile

Hazard Codes of Antimony trifluoride (CAS NO.7783-56-4): ToxicT,DangerousN,CorrosiveC
Risk Statements: 23/24/25-51/53 
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. 
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 7-26-45-61 
S7: Keep container tightly closed. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
RTECS: CC5150000
F: 10
Hazard Note: Corrosive/Highly Toxic
HazardClass: 8
PackingGroup: III
Poison by subcutaneous route. Corrosive to skin and eyes. See also FLUORIDES and ANTIMONY COMPOUNDS. When heated to decomposition it emits very toxic fumes of F and Sb.

Antimony trifluoride Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Sb)/m3; TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift; TWA 0.5 mg(Sb)/m3
NIOSH REL: TWA 0.5 mg(Sb)/m3
DOT Classification:  8; Label: Corrosive

Antimony trifluoride Specification

Such as: When on the skin: first,should  flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Do not induce vomiting.Wash mouth out with water,and get medical aid immediately.
In addition,  Antimony trifluoride (CAS NO.7783-56-4) can be stable under normal temperature and pressure conditions.It is not compatible with metals, strong acids, and you must not take it with incompatible materials and not be exposured to moist air or water.And also prevent it to broken down into hazardous decomposition products: hydrogen fluoride gas, antimony/antimony oxides.

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