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Basic Information
CAS No.: 7783-70-2
Name: ANTIMONY PENTAFLUORIDE
Article Data: 63
Molecular Structure:
Molecular Structure of 7783-70-2 (ANTIMONY PENTAFLUORIDE)
Formula: F5Sb
Molecular Weight: 216.742
Synonyms: Antimonypentafluoride;Antimony(V) fluoride;Pentafluoroantimony;
EINECS: 232-021-8
Density: 2.993 g/mL at 25 °C(lit.)
Melting Point: 7 °C(lit.)
Boiling Point: 149.4 °C
Flash Point: 149.5°C
Solubility: reacts vigorously with H2O, becoming hydrolyzed [HAW93] [KIR78]
Appearance: colourless oily liquid
Hazard Symbols: ToxicT,OxidizingO,CorrosiveC,DangerousN,HarmfulXn
Risk Codes: 23/24/25-34-51/53-20/22
Safety: 61-45-36/37/39-28-27-26-22
Transport Information: UN 2923 8/PG 2
PSA: 0.00000
LogP: 2.10100
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Conditions
ConditionsYield
In neat (no solvent) cylinder fiited with dry powdered element, NF3O condensed into cylinder at -196°C, mixt. heated at 210°C for 24h; not isolated, monitored by NMR, IR;90%
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antimonypentachloride

A

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SF5N=SCl2

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((pentafluorosulfanyl)imino)chlorofluorosulfane

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Conditions
ConditionsYield
sulfane was condesed on SbCl5 at -196°C, heated at 100°C to initiate the reaction; fractionation through a series of traps at -6, -45, -78, -112 and -196°C in vac., a -45°C trap contained the product;A 35%
B n/a
C n/a
...Expand
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H2F(1+)*SbClF5(1-)=H2FSbClF5

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Conditions
ConditionsYield
In neat (no solvent) byproducts: HCl, HF; decomposition above -50°C;;
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Conditions
ConditionsYield
In neat (no solvent) powdered metal treated with XeF2 (air-tight autoclave, 200-300°C);
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fluorine

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antimony pentafluoride

Conditions
ConditionsYield
burning antimony filings in F2 atmosphere; without isolation of intermediates the end product liq. SbF5;
in a stream of HF-free F2; distn. in vac.;
In not given
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hydrogen fluoride

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Conditions
ConditionsYield
HF free of water;;
HF free of water;;
at 100℃; for 3h; Autoclave; Inert atmosphere;
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antimony(V) chloride

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hydrogen fluoride

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Conditions
ConditionsYield
In hydrogen fluoride
In hydrogen fluoride HF (liquid);

antimonic acid

7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
With hydrogen fluoride by addn. antimonic acid into HF soln.; evapn. in vac.; cannot be crystallized;
With calcium fluoride; sulfuric acid by distn.;0%
With hydrogen fluoride anhydrous antimonic acid with concd. HF soln.;0%

mercury(II) fluoride

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7783-70-2

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Conditions
ConditionsYield
by glowing antimonic acid with dry HgF2;0%
by glowing antimonic acid with dry HgF2;0%

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Conditions
ConditionsYield
With diethyl ether In dichloromethane Kinetics; byproducts: Et2O, CH3CH2F; vac. line; 298 - 343 K;
With 1,3-dioxolan In dichloromethane Kinetics; byproducts: Et2O, CH3CH2F; vac. line; 298 - 343 K;
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Consensus Reports

Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right-To-Know List. EPA Extremely Hazardous Substances List.

Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Sb)/m3
ACGIH TLV: TWA 0.5 mg(Sb)/m3
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3
DOT Classification:  8; Label: Corrosive, Poison

Specification

The Antimony(V) pentafluoride with the cas number7783-70-2, is also called (1) Antimony (V) fluoride ; (2) Antimony fluoride ; (3) Antimony fluoride (SbF5) ; (4) Antimony pentafluoride ; (5) Antimony(V) fluoride ; (6) Antimony(V) pentafluoride ; (7) Pentafluoroantimony . It belongs to the following Product Categories: (1)Inorganics; (2)Inorganic Fluorides; (3)Antimony Salts; (4)Metal and Ceramic Science; (5)Salts

The Antimony(V) pentafluoride is a colorless, oily liquid. It is quite toxic by inhalation, in contact with skin and if swallowed. Hence，when you are using this chmical, please wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds and take off immediately all contaminated clothing. If you feel unwell, seek medical advice immediately (show the label whenever possible.) Besides, It is toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so avoid release to the environment refering to special instructions / safety data sheets.

You can still convert the following datas into molecular structure :
1. [F-].[F-].[F-].[F-].[F-].[SbH3+3]
2. InChI=1/5FH.Sb.3H/h5*1H;;;;/q;;;;;+3;;;/p-5/r5FH.H3Sb/h5*1H;1H3/q;;;;;+3/p-5

The Antimony(V) pentafluoride toxic data can be showed in the following sheet.|

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 270mg/m3 (270mg/m3) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: OTHER CHANGES

KIDNEY, URETER, AND BLADDER: OTHER CHANGES		 Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 35(7), Pg. 25, 1970.