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Name |
Benzeneacetaldehyde, alpha-ethylidene- |
EINECS | 224-567-0 |
CAS No. | 4411-89-6 | Density | 0.99 g/cm3 |
PSA | 17.07000 | LogP | 2.28880 |
Solubility | Soluble in oil and ethanol. Insoluble in water. | Melting Point |
N/A |
Formula | C10H10O | Boiling Point | 271.6 °C at 760 mmHg |
Molecular Weight | 146.189 | Flash Point | 95.9 °C |
Transport Information | N/A | Appearance | N/A |
Safety | 26-36 | Risk Codes | 36/37/38 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
Crotonaldehyde,2-phenyl- (7CI,8CI);Crotonaldehyde, a-phenyl- (4CI);2-Phenyl-2-butenal;2-Phenylcrotonaldehyde;a-Phenylcrotonaldehyde; |
Article Data | 42 |
α-naphthol
4-phenyl-4-vinyl-1,3-dioxolan -2-one
(E/Z)-2-phenylcrotonaldehyde
Conditions | Yield |
---|---|
With bis(η3-allyl-μ-chloropalladium(II)) In toluene at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction; | 95% |
1-Phenylprop-1-yne
carbon monoxide
A
(E/Z)-2-phenylcrotonaldehyde
B
α-methyl-trans-cinnamaldehyde
Conditions | Yield |
---|---|
With hydrogen; palladium diacetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium(II) iodide In toluene at 70℃; under 75007.5 Torr; for 18h; Catalytic behavior; Reagent/catalyst; Autoclave; | A n/a B 83% |
1-methoxy-1,3-diethoxy-2-phenylbutane
(E/Z)-2-phenylcrotonaldehyde
Conditions | Yield |
---|---|
With hydrogenchloride at 70 - 90℃; for 1h; | 77.8% |
4-phenyl-4-vinyl-1,3-dioxolan -2-one
A
(E/Z)-2-phenylcrotonaldehyde
Conditions | Yield |
---|---|
With [1,2-bis-(phenylsulfinyl)ethane]palladium(II) acetate; bis[2-(diphenylphosphino)phenyl] ether In N,N-dimethyl-formamide at 20℃; for 12h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique; | A n/a B 75% |
Conditions | Yield |
---|---|
With copper(II) choride dihydrate; lithium chloride In ethyl acetate for 1.5h; | A 8% B 59% |
2-phenyl-2-vinyloxirane
B
(E/Z)-2-phenylcrotonaldehyde
Conditions | Yield |
---|---|
With copper(II) choride dihydrate; lithium chloride In ethyl acetate for 1.5h; Reflux; Inert atmosphere; | A 59% B 8% |
Conditions | Yield |
---|---|
optically inactive 1-phenyl-butene-(3)-diol-(1.2) of mp: 43 degree; |
Conditions | Yield |
---|---|
With diethyl ether; iodine; mercury(II) oxide anschliessend Behandeln mit AgNO3-Loesung; |
2-amino-1-phenyl-but-3-en-1-ol
(E/Z)-2-phenylcrotonaldehyde
Conditions | Yield |
---|---|
With acetic acid; sodium nitrite at 0℃; |
Conditions | Yield |
---|---|
With ethanol; sodium acetate at 110℃; |
The Benzeneacetaldehyde, alpha-ethylidene-, with the CAS registry number 4411-89-6, is also known as alpha-Phenylcrotonaldehyde. It belongs to the product categories of Alphabetical Listings; Flavors and Fragrances; O-P. Its EINECS registry number is 224-567-0. This chemical's molecular formula is C10H10O and molecular weight is 146.19. Its IUPAC name is called (E)-2-phenylbut-2-enal.
Physical properties of Benzeneacetaldehyde, alpha-ethylidene-: (1)ACD/LogP: 2.68; (2)ACD/LogD (pH 5.5): 2.68; (3)ACD/LogD (pH 7.4): 2.68; (4)ACD/BCF (pH 5.5): 63.59; (5)ACD/BCF (pH 7.4): 63.59; (6)ACD/KOC (pH 5.5): 679.94; (7)ACD/KOC (pH 7.4): 679.94; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 2; (10)Index of Refraction: 1.53; (11)Molar Refractivity: 45.6 cm3; (12)Molar Volume: 147.5 cm3; (13)Surface Tension: 35 dyne/cm; (14)Density: 0.99 g/cm3; (15)Flash Point: 95.9 °C; (16)Enthalpy of Vaporization: 50.98 kJ/mol; (17)Boiling Point: 271.6 °C at 760 mmHg; (18)Vapour Pressure: 0.00639 mmHg at 25°C.
Preparation: this chemical can be prepared by 1-methoxy-1,3-diethoxy-2-phenylbutane. This reaction will need reagent 18percent aq. HCl. The reaction time is 1 hour with reaction temperature of 70 - 90 °C. The yield is about 77.8%.
Uses of Benzeneacetaldehyde, alpha-ethylidene-: it can be used to produce 1-trimethylsilyloxy-2-phenyl-1,3-butadiene at temperature of 50 °C. This reaction will need reagent triethylamine, zinc chloride. The yield is about 61%.
When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC=C(C=O)C1=CC=CC=C1
(2)Isomeric SMILES: C/C=C(/C=O)\C1=CC=CC=C1
(3)InChI: InChI=1S/C10H10O/c1-2-9(8-11)10-6-4-3-5-7-10/h2-8H,1H3/b9-2-
(4)InChIKey: DYAOGZLLMZQVHY-MBXJOHMKSA-N