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Cas Database

Name

Di-1-adamantylphosphine

EINECS

N/A

CAS No.

131211-27-3

Density

N/A

PSA

13.59000

LogP

5.60250

Solubility

N/A

Melting Point

181-185 °C

Formula

C20H31P

Boiling Point

407.8±12.0 °C(Predicted)

Molecular Weight

302.44

Flash Point

N/A

Transport Information

N/A

Appearance

N/A

Safety

Hazard Codes	T
Risk Statements	23/24/25-36/37/38
Safety Statements	36/37/39-45
RIDADR	UN 2811 6.1/PG 3

Risk Codes

23/24/25-36/37/38

Molecular Structure

Hazard Symbols

Synonyms

DI-1-ADAMANTYLPHOSPHINE;Di-1-adamantylphosphine,min.97%;Bis(adamant-1-yl)phosphine, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine;Di-1-adamantylphosphine, min. 97%

Article Data

Di-1-adamantylphosphine Synthetic route

: 126683-99-6
1-(1-adamantyl)chlorophosphinoyladamantane

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran for 16h; Ambient temperature;	94.3%
With trichlorosilane In toluene for 264h; Ambient temperature;	93%
With lithium aluminium tetrahydride In tetrahydrofuran at -10 - 20℃; for 14h;	90%

: 157282-19-4
di-1-adamantylchlorophosphane

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 4h;	70%

: 97580-87-5
(1-adamantyl)magnesium chloride

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 69 percent / diethyl ether / Heating 2: 70 percent / LiAlH4 / diethyl ether / 4 h / 20 °C View Scheme

: 23906-91-4
(1-adamantyl)dichlorophosphine

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 69 percent / diethyl ether / Heating 2: 70 percent / LiAlH4 / diethyl ether / 4 h / 20 °C View Scheme

: 281-23-2
adamantane

Fe(CO)5: Fe(CO)5

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) PCl3, AlCl3, 2.) H2O / 1.) reflux, 6 h, 2.) chloroform 2: 94.3 percent / LiAlH4 / tetrahydrofuran / 16 h / Ambient temperature View Scheme

: 281-23-2
adamantane

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 95 percent / phosphorus trichloride, aluminum chloride / 5 h / Heating 2: 62 percent / LiAlH4 / diethyl ether / 3 h / Heating View Scheme
Multi-step reaction with 2 steps 1: phosphorus trichloride; aluminum (III) chloride / 6.17 h / Reflux 2: lithium aluminium tetrahydride / tetrahydrofuran / 20 h / -10 - 20 °C View Scheme
Multi-step reaction with 2 steps 1.1: aluminum (III) chloride; phosphorus trichloride / Reflux 1.2: Cooling with ice 2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere View Scheme

: 131266-79-0
bis(1-adamantyl)phosphine oxide

: 131211-27-3
di-1-adamantylphosphine

Conditions

Conditions	Yield
With copper(II) trifluoromethanesulfonate; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 9h; Inert atmosphere;
With diethoxymethylane; Bis(p-nitrophenyl) phosphate In toluene at 110℃; Inert atmosphere; chemoselective reaction;	99 %Spectr.

: 131211-27-3
di-1-adamantylphosphine

: 157282-19-4
di-1-adamantylchlorophosphane

Conditions

Conditions	Yield
With tetrachloromethane at 50℃; for 16h;	100%
With tetrachloromethane at 50℃; for 24h;	98%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 16h; Ambient temperature;	93.7%
With phosgene; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at -10℃;	67%
Multi-step reaction with 2 steps 1: phosgen / toluene / Ambient temperature 2: Et3N / toluene / a) 60 deg C, 4 h, b) reflux, 3 h View Scheme

: 100-39-0
benzyl bromide

: 131211-27-3
di-1-adamantylphosphine

: di(1-adamantyl)benzylphosphonium hydrobromide

Conditions

Conditions	Yield
In toluene Glovebox; Schlenk technique; Inert atmosphere; Reflux;	100%
In toluene Glovebox; Schlenk technique; Inert atmosphere; Reflux;	100%
In toluene at 90℃; for 14h;	92%

: 131211-27-3
di-1-adamantylphosphine

: C20H30P(1-)*Li(1+)

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 3h;	100%

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