- Diallyl 2,2'-oxydiethyl dicarbonate
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Cas Database |
| Name |
Diallyl 2,2'-oxydiethyl dicarbonate |
EINECS | 205-528-7 |
| CAS No. | 142-22-3 | Density | 1.129g/cm3 |
| PSA | 80.29000 | LogP | 1.68140 |
| Solubility | 2.36g/L at 20℃ | Melting Point |
−4 °C(lit.) |
| Formula | C12H18 O7 | Boiling Point |
161 °C2 mm Hg(lit.) |
| Molecular Weight | 274.271 | Flash Point | 145.3°C |
| Transport Information | N/A | Appearance | liquid |
| Safety | Poison by intraperitoneal route. A human skin irritant. The allyl compounds are generally toxic. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizing material. To fight fire, use water mist or spray, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS. | Risk Codes | 22-36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
|
| Synonyms |
2,5,8,10-Tetraoxatridec-12-enoicacid, 9-oxo-, 2-propenyl ester (9CI); Carbonic acid, allyl ester, diester withdiethylene glycol (6CI,7CI); Carbonic acid, oxydiethylene diallyl ester (8CI);01M; Allyl diglycol carbonate; Brite 55; CR 39R; Carbonic acid,oxydi-2,1-ethanediyl di-2-propenyl ester; Diallyl diglycol carbonate; Diallyloxydiethylene dicarbonate; Diethylene glycol diallyl dicarbonate; Diethyleneglycol, bis(allyl carbonate); High ADC-CR 39; Hoya HL; NSC 5246; Nouryset 200;RAV 7; RAV 7AT; RAV 7N; TS 16; Transallyl CR 39 |
Article Data | 7 |
Diallyl 2,2'-oxydiethyl dicarbonate Synthetic route
- 14666-78-5
Peroxydikohlensaeure-diethylester
- 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester
| Conditions | Yield |
|---|---|
| at 40℃; Equilibrium constant; Zersetzung; | |
| at 50℃; Equilibrium constant; Zersetzung; | |
| at 60℃; Equilibrium constant; Zersetzung; |
| Conditions | Yield |
|---|---|
| at 40℃; Zersetung; | |
| at 50℃; Zersetung; | |
| at 60℃; Zersetung; |
- 106-75-2
diethylene glycol bischloroformate
- 107-18-6
allyl alcohol
- 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester
| Conditions | Yield |
|---|---|
| With calcium carbonate at 50 - 90℃; |
- 2937-50-0
Allyl chloroformate
- 111-46-6
diethylene glycol
- 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester
| Conditions | Yield |
|---|---|
| With pyridine | |
| With pyridine |
- 124-38-9
carbon dioxide
- 107-05-1
3-chloroprop-1-ene
- 111-46-6
diethylene glycol
- 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester
| Conditions | Yield |
|---|---|
| With 2-cyclohexyl-1,1,3,3-tetramethylguanidine 1.) CH3CN 80 psi, 2.) 80 psi, 55 deg C, 14 h; Yield given. Multistep reaction; |
- 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester
| Conditions | Yield |
|---|---|
| 1,1-bis(tert-hexylperoxy)-3,3,5-trimethycyclohexane at 110 - 130℃; for 4h; Product distribution / selectivity; |
Diallyl 2,2'-oxydiethyl dicarbonate Chemical Properties
Molecular Formula: C12H18O7
Molar mass: 274.27 g/mol
EINECS: 205-528-7
Density: 1.129 g/cm3
Flash Point: 145.3 °C
Index of Refraction: 1.454
Boiling Point: 337.4 °C at 760 mmHg
Vapour Pressure: 0.000105 mmHg at 25°C
Melting point: -4 °C(lit.)
Appearance: Liquid
Stable: SStability Combustible. Incompatible with strong oxidizing agents
Product categories of Allyl diglycol carbonate (142-22-3): Monomer
Structure of Allyl diglycol carbonate (142-22-3):
XLogP3-AA: 2
H-Bond Donor: 0
H-Bond Acceptor: 7
Systematic Name: Allyl 2-(2-allyloxycarbonyloxyethoxy)ethyl carbonate
SMILES: O=C(OCCOCCOC(=O)OC\C=C)OC\C=C
InChI: InChI=1/C12H18O7/c1-3-5-16-11(13)18-9-7-15-8-10-19-12(14)17-6-4-2/h3-4H,1-2,5-10H2
InChIKey: JHQVCQDWGSXTFE-UHFFFAOYAG
Std. InChI: InChI=1S/C12H18O7/c1-3-5-16-11(13)18-9-7-15-8-10-19-12(14)17-6-4-2/h3-4H,1-2,5-10H2
Std. InChIKey: JHQVCQDWGSXTFE-UHFFFAOYSA-N
Diallyl 2,2'-oxydiethyl dicarbonate Uses
Allyl diglycol carbonate (142-22-3) can be used for the production of eyeglasses.
Diallyl 2,2'-oxydiethyl dicarbonate Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 270mg/kg (270mg/kg) | LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)" | Journal of Pharmacology and Experimental Therapeutics. Vol. 90, Pg. 338, 1947. |
| mouse | LD50 | oral | 279mg/kg (279mg/kg) | BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Toksikologicheskii Vestnik. Vol. (2), Pg. 35, 1999. |
| rat | LC50 | inhalation | 1205mg/m3 (1205mg/m3) | BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION | Toksikologicheskii Vestnik. Vol. (2), Pg. 35, 1999. |
| rat | LD50 | oral | 426mg/kg (426mg/kg) | BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Toksikologicheskii Vestnik. Vol. (2), Pg. 35, 1999 |
Diallyl 2,2'-oxydiethyl dicarbonate Consensus Reports
Reported in EPA TSCA Inventory.
Diallyl 2,2'-oxydiethyl dicarbonate Safety Profile
Poison by intraperitoneal route. A human skin irritant. The allyl compounds are generally toxic. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizing material. To fight fire, use water mist or spray, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.
Hazard Codes: Xn.gif){kind=small}
Risk Statements:
22: Harmful if swallowed
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
Diallyl 2,2'-oxydiethyl dicarbonate Specification
Allyl diglycol carbonate (142-22-3) also can be called Diallyl oxydi-2,1-ethanediyl biscarbonate ; Baryotrak ; Seiko Plax ; Oxydiethane-2,1-diyl diprop-2-en-1-yl biscarbonate and carbonic acid, oxydi-2,1-ethanediyl di-2-propen-1-yl ester .
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