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Cas Database |
| Name |
Glycidyl butyrate |
EINECS | N/A |
| CAS No. | 2461-40-7 | Density | 1.069 g/cm3 |
| PSA | 38.83000 | LogP | 0.72850 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C7H12O3 | Boiling Point | 196.258 °C at 760 mmHg |
| Molecular Weight | 144.17 | Flash Point | 85 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Butanoicacid, oxiranylmethyl ester (9CI);Butyric acid, 2,3-epoxypropyl ester(6CI,7CI,8CI);(?à)-Glycidylbutyrate;2-Oxiranylmethyl butyrate;Glycidyl butanoate;Glycidyl butyrate;Glydicyl butyrate;NSC 83144; |
Article Data | 12 |
Glycidyl butyrate Synthetic route
| Conditions | Yield |
|---|---|
| at 60℃; for 8h; | 95% |
| With 15-crown-5 In acetonitrile for 14h; Ambient temperature; | 92% |
| With tetrabutylammomium bromide In toluene for 5h; Solvent; Reflux; | 90% |
| With 1,4-dioxane at 200℃; | |
| With tetrabutylammomium bromide at 100℃; Kinetics; Temperature; |
| Conditions | Yield |
|---|---|
| With tetrabutylammomium bromide In toluene for 5h; Solvent; Reflux; | 70% |
| Conditions | Yield |
|---|---|
| With triethylamine In toluene at 0℃; for 0.833333h; | |
| Stage #1: oxiranyl-methanol With trimethylamine In dichloromethane for 0.5h; Cooling with ice; Stage #2: butyryl chloride In dichloromethane at 20℃; for 3h; |
- 105-54-4
butanoic acid ethyl ester
- 107-18-6
allyl alcohol
A
- 2461-40-7
(+/-)-glycidyl butyrate
B
- 2051-78-7
allyl butyrate
C
- 556-52-5
oxiranyl-methanol
| Conditions | Yield |
|---|---|
| With Novozym 435; dihydrogen peroxide 1.) 15 min, 2.) 40 deg C, 16 h; Yield given. Multistep reaction. Yields of byproduct given; |
- 107-18-6
allyl alcohol
A
- 2461-40-7
(+/-)-glycidyl butyrate
B
- 2051-78-7
allyl butyrate
C
- 556-52-5
oxiranyl-methanol
| Conditions | Yield |
|---|---|
| With Novozym 435; C3H7COOC2H5; dihydrogen peroxide 1.) 15 min, 2.) 40 deg C, 16 h; Yield given. Multistep reaction. Yields of byproduct given; |
- 2461-40-7
(+/-)-glycidyl butyrate
- 31027-31-3
4-isopropylphenylisocyanate
- 121373-21-5
<3-(4-isopropylphenyl)-2-oxo-5-oxazolidinyl>methyl butyrate
| Conditions | Yield |
|---|---|
| With Tributylphosphine oxide; lithium bromide In xylene for 2h; Heating; | 100% |
| Conditions | Yield |
|---|---|
| With potassium (1S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylate; palladium diacetate; XPhos In 1-methyl-pyrrolidin-2-one at 60℃; for 12h; Glovebox; Inert atmosphere; Sealed tube; | 97% |
| Conditions | Yield |
|---|---|
| With palladium diacetate; potassium bicyclo[2.2.1]hept-2-ene-5-carboxylate; XPhos In 1-methyl-pyrrolidin-2-one at 60℃; for 12h; | 97% |
| Conditions | Yield |
|---|---|
| With 18-crown-6 ether at 120℃; under 39003.9 Torr; for 16h; Autoclave; | 93% |
- 2461-40-7
(+/-)-glycidyl butyrate
- 75-86-5
2-hydroxy-2-methylpropanenitrile
- 142944-71-6
Butyric acid 3-cyano-2-hydroxy-propyl ester
| Conditions | Yield |
|---|---|
| With triethylamine In tetrahydrofuran for 3.5h; Heating; | 91% |
Glycidyl butyrate Chemical Properties
Product Name: Glycidyl butyrate (2461-40-7)
Molecular Formula: C7H12O3
Molecular Weight: 144.17g/mol
Mol File: 2461-40-7.mol
Boiling point: 196.3 °C at 760 mmHg
Flash Point: 85 °C
Density: 1.069 g/cm3
Product Categories: API intermediates
Synonyms of Glycidyl butyrate (2461-40-7): glycidyl butyrate ; (r)-2,3-epoxypropyl butyrate ; 2,3-epoxypropyl ester butyric acid .
Glycidyl butyrate Uses
Glycidyl butyrate (2461-40-7) is widely used in chiral drugs, pesticides, spices chiral synthesis.Ink. Resin. Acrylic paint. Adhesives. Latex. Plastic alloy. Photosensitive materials, organic synthesis, polymer synthesis of modified.
Glycidyl butyrate Specification
Glycidyl butyrate (2461-40-7) is a colorless and transparent liquid, insoluble in water, almost insoluble in all organic solvents, on the skin and mucous membrane irritant, almost non-toxic. Because of its carbon-carbon molecule that contains both the double bond, but also contains epoxy groups, both to free radical-type reaction, but also for ion-type reaction, therefore, has a very high response flexibility to separate the different reactions. widely used in medicine, photosensitive materials, organic synthesis and polymer-modified and other fields. derived products have excellent anti-UV, water-resistant heat-resistant characteristics, is an important fine chemical raw material.
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