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Silver mesylate
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Name

Silver mesylate

 EINECS 219-199-2
CAS No. 2386-52-9 Density 1.511 g/cm3
PSA 65.58000 LogP 0.24220
Solubility Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane. Melting Point 252-256 °C(lit.)
Formula CH3AgO3S Boiling Point N/A
Molecular Weight 202.967 Flash Point N/A
Transport Information UN 1759 Appearance white to beige or light grey crystalline powder
Safety 26-36-36/37/39-22 Risk Codes 36/37/38-20/21/22
Molecular Structure Molecular Structure of 2386-52-9 (Silver mesylate) Hazard Symbols HarmfulXn, IrritantXi
Synonyms

Methanesulfonicacid, silver(1+) salt (8CI,9CI);Silver methanesulfonate;Silvermethylsulfonate;Silver(I) methanesulfonate;

Article Data 9

Silver mesylate Synthetic route

75-75-2

methanesulfonic acid

20667-12-3

silver(l) oxide

2386-52-9

silver methanesulfonate

Conditions
ConditionsYield
In water at 90℃; for 3h;99%
In tetrahydrofuran at 20℃; for 1h;95%
In water addn. of Ag2O to soln. of CH3SO3H in H2O; heating at 90°C for 3 h; cooling, filtration, evapn., washing with acetone, drying in vac.;91%
In water at 90℃; for 3h;91%
75-75-2

methanesulfonic acid

silver carbonate

2386-52-9

silver methanesulfonate

Conditions
ConditionsYield
In water (N2); addn. of aq. soln. of methanesulfonic acid to aq. suspn. of silvercompd. at 20°C, stirring for 1 h at 20°C; filtration through celite, evapn. at 50°C in vac.;83%
In water byproducts: H2O, CO2; CH3SO3H reacted with Ag2CO3 in H2O (Y.Y.Zhang, Y.Wang, X.Tao, N.Wang, F.L.Du, Y.Z.Chen Polyhedron 27 (2008) 2501-2505);
In isopropyl alcohol at 0℃;6.5 g
In acetonitrile at 20 - 60℃; for 1.25h;1.1 g
75-75-2

methanesulfonic acid

silver nitrate

2386-52-9

silver methanesulfonate

Conditions
ConditionsYield
In water stoich. amts.; crystn. on slow evapn., manual sepn. of needles, washing (Me2CO, Et2O), drying (reduced pressure, over P2O5); elem. anal.;25%

[silver(I)(pyridine-N-oxide)3](methanesulfonate) monohydrate

2386-52-9

silver methanesulfonate

Conditions
ConditionsYield
In neat (no solvent) at 250℃;
2386-52-9

silver methanesulfonate

C22H26N3(1-)*Cl(1-)*Zn(2+)

C22H26N3(1-)*CH3O3S(1-)*Zn(2+)

Conditions
ConditionsYield
In ethanol100%

C64H104N5O6(1+)*I(1-)

2386-52-9

silver methanesulfonate

C64H104N5O6(1+)*CH3O3S(1-)

Conditions
ConditionsYield
In tetrahydrofuran; water for 2h;100%

C69H106N5O6(1+)*I(1-)

2386-52-9

silver methanesulfonate

C69H106N5O6(1+)*CH3O3S(1-)

Conditions
ConditionsYield
In tetrahydrofuran; water for 2h;100%
725230-20-6

[Zn(II)Cl(2,8-diethyl-1,3,7,9-tetramethyl-5-(2-pyridyl)-dipyrromethene)]2

2386-52-9

silver methanesulfonate

725230-21-7

[Zn(II)(O3SMe)2(2,8-diethyl-1,3,7,9-tetramethyl-5-(2-pyridyl)-dipyrromethene)]2

Conditions
ConditionsYield
In ethanol to soln. of Zn-complex added Ag-salt, stirred overnight; filtered, solvent removed from filtrate;100%

hexammine cobalt(III) chloride

2386-52-9

silver methanesulfonate

hexaamminecobalt(III) methanesulfonate

Conditions
ConditionsYield
In water byproducts: AgCl; Co complex and CH3SO3Ag (molar ratio 1:3.7) dissolved in hot H2O with stirring for 0.5 h; filtered; filtrate cooled slowly to room temp. for 3 d; crystals filtered off and dried in air; elem. anal.;99%
162978-76-9

(2,2':6',2''-terpyridine)methylplatinum(II) chloride

2386-52-9

silver methanesulfonate

1127889-38-6

[Pt(CH3)(2,2':6',2''-terpyridine)]CH3SO3

Conditions
ConditionsYield
In water byproducts: AgCl; Pt complex (0.21 mmol) treated with stoich. amt. of aq. soln. of AgCH3SO3; stirred in the dark (room temp., 1 h); AgCl filtered off; evapd. (vac.); recrystd. from 2,2,2-trifluoroethanol/Et2O; elem. anal.;99%

Silver mesylate Chemical Properties

IUPAC Name:  Silver methanesulfonate
Synonyms:  Methanesulfonic acid silver salt ; Methanesulfonic acid, silver salt ; Methanesulfonic acid, silver(1+) salt ; Silver methanesulfonate ; Silver methanesulfonate (Ag(CH2SO3)) ; Silver methanesulphonate ; Silver methylsulfonate
The Molecular Formula of  Silver Methylsulfonate (CAS NO.2386-52-9):CH3AgO3S
The Molecular Weight of   Silver Methylsulfonate (CAS NO.2386-52-9):202.965920 g/mol
The Molecular Structure of  Silver Methylsulfonate (CAS NO.2386-52-9):

Polar Surface Area: 62.75Å2 
Polarizability: 10-24cm3
Melting Point: 252-256 °C(lit.) 
Appearance: white to beige or light grey crystalline powder

Silver mesylate Uses

  Silver Methylsulfonate  ,whose Cas Register Number is 2386-52-9, can be used in organic synthesis.

Silver mesylate Toxicity Data With Reference

1.    

ivn-mus LD50:18 mg/kg

     CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00622 .

Silver mesylate Consensus Reports

Silver and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Silver mesylate Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of SOx. See also SULFONATES and SILVER COMPOUNDS.
Hazard Codes: IrritantXi,HarmfulXn
Risk Statements: 36/37/38-20/21/22
 R36/37/38:Irritating to eyes, respiratory system and skin. 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-36-36/37/39-22
 S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S22:Do not breathe dust.
RIDADR: 1759
WGK Germany: 3
RTECS: PB2685000
HazardClass: 8
PackingGroup: III

Silver mesylate Standards and Recommendations

OSHA PEL: TWA 0.01 mg(Ag)/m3
ACGIH TLV: TWA 0.01 mg(Ag)/m3

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