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Sodium tartrate

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Name

Sodium tartrate

EINECS 212-773-3
CAS No. 868-18-8 Density 1.818 g/cm3
PSA 120.72000 LogP -4.79200
Solubility soluble in ~9 parts H2O, 2 parts boiling H2O; insoluble alcohol [MER06] Melting Point 302oFoC
Formula C4H4Na2O6 Boiling Point 399.3 °C at 760 mmHg
Molecular Weight 194.052 Flash Point 209.4 °C
Transport Information N/A Appearance Colorless crystals or white crystal powder
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 868-18-8 (Sodium tartrate) Hazard Symbols N/A
Synonyms

Butanedioicacid, 2,3-dihydroxy- (2R,3R)-, disodium salt (9CI);Butanedioic acid,2,3-dihydroxy-[R-(R*,R*)]-, disodium salt;Sodium tartrate (Na2(C4H4O6))(6CI,7CI);Tartaric acid, disodium salt (8CI);Bisodium tartrate;Disodium(+)-tartrate;Disodium L-(+)-tartrate;Disodium L-tartrate;L-Disodium tartrate;SodiumL-(+)-tartrate;

Article Data 58

Sodium tartrate Synthetic route

50-99-7

D-glucose

A

527-07-1

sodium D-gluconate

B

868-18-8

sodium tartrate

C

D-glucaric acid disodium salt

Conditions
ConditionsYield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.7;A n/a
B n/a
C 90%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.2; Product distribution; Further Variations:; pH-values; Reaction partners;A n/a
B n/a
C 64%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=9.5;

Bi(3+)*OH(1-)*C4H4O6(2-)=Bi(OH)C4H4O6

A

3Bi(3+)*7OH(1-)*C4H4O6(2-)=Bi(OH)*C4H4O6*2Bi(OH)3

B

868-18-8

sodium tartrate

Conditions
ConditionsYield
In sodium hydroxide solvation in aq. NaOH with formation of Na tartrate and the soluble coordination compound Bi(OH)C4H4O6*2Bi(OH)3;;

sodium hydrogen tartrate *H2O

141-52-6

sodium ethanolate

868-18-8

sodium tartrate

Conditions
ConditionsYield
In not given contact of NaOC2H5 with NaC4H5O6; slow reaction in the cold, fast reaction in the warmth;;
In not given contact of NaOC2H5 with NaC4H5O6; slow reaction in the cold, fast reaction in the warmth;;

sodium arsenyl tartrate * 2.5H2O

1310-73-2

sodium hydroxide

A

arsenic(III) trioxide

B

868-18-8

sodium tartrate

Conditions
ConditionsYield
In not given formed when neutralized with NaOH; As2O3 pptd. and Na2C4H4O6 remained dissolved;;

sodium tartrate dihydrate

A

497-19-8

sodium carbonate

B

868-18-8

sodium tartrate

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O, CO2, C; stepwise loss of H2O up to 154°C; decompn. of Na2C4H4O6 starting at 255°C; decompn. to Na2CO3 and C at 309°C: combustion of C up to 700°C; dissociation of Na2CO3 at 875°C;;
In neat (no solvent) byproducts: H2O, CO2, C; stepwise loss of H2O up to 154°C; decompn. of Na2C4H4O6 starting at 255°C; decompn. to Na2CO3 and C at 309°C: combustion of C up to 700°C; dissociation of Na2CO3 at 875°C;;

2Bi(3+)*4H(1+)*5C4H4O6(2-)=Bi2(C4H4O6)3*2C4H6O6

A

3Bi(3+)*7OH(1-)*C4H4O6(2-)=Bi(OH)*C4H4O6*2Bi(OH)3

B

868-18-8

sodium tartrate

Conditions
ConditionsYield
With sodium hydroxide In water dissolution in aq. NaOH;;
87-69-4

tartaric acid

868-18-8

sodium tartrate

Conditions
ConditionsYield
With sodium hydroxide pH=4.9;
62-76-0

sodium oxalate

868-18-8

sodium tartrate

Conditions
ConditionsYield
With sodium cyanide Alkaline conditions;
Conditions
ConditionsYield
With sodium cyanide; sodium hydroxide for 24h; Aldol Condensation;
868-18-8

sodium tartrate

micafungin sodium

Conditions
ConditionsYield
In ethanol; water99.53%

Sodium tartrate Consensus Reports

Reported in EPA TSCA Inventory.

Sodium tartrate Specification

The CAS registry number of Sodium tartrate is 868-18-8. Its EINECS registry number is 212-773-3. The systematic name is disodium (2R,3R)-2,3-dihydroxybutanedioate. In addition, the molecular formula is C4H4Na2O6 and the molecular weight is 194.05. Its crystal structure captures a very precise amount of water. And it is also a common primary standard for Karl Fischer titration. What's more, it should be stored in sealed container, and put in a cool and dry place.

Physical properties about this chemical are: (1)ACD/LogP: -1.43; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.86; (4)ACD/LogD (pH 7.4): -6.18; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 6; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 93.06 Å2; (13)Flash Point: 209.4 °C; (14)Enthalpy of Vaporization: 75.13 kJ/mol; (15)Boiling Point: 399.3 °C at 760 mmHg; (16)Vapour Pressure: 4.93E-08 mmHg at 25°C.

Preparation and uses of Sodium tartrate: it can be prepared by L-tartaric acid. Heat the L-tartaric acid at first. And then after a series of neutralization by sodium hydroxide, condensation and crystallization you can get the desired product. In addition, it is used as an emulsifier and a binding agent in food products such as jellies, margarine, and sausage casings. And it also can be used as a food additive, slow granule, emulsion salt, antioxidants, antioxidant synergistic agent and chelating agent.

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[Na+].O=C([O-])[C@H](O)[C@@H](O)C([O-])=O
(2)InChI: InChI=1/C4H6O6.2Na/c5-1(3(7)8)2(6)4(9)10;;/h1-2,5-6H,(H,7,8)(H,9,10);;/q;2*+1/p-2/t1-,2-;;/m1../s1
(3)InChIKey: HELHAJAZNSDZJO-NMAATZGSBY

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD10 oral 3686mg/kg (3686mg/kg)   Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 31, Pg. 12, 1942.
rabbit LDLo oral 5290mg/kg (5290mg/kg)   FAO Nutrition Meetings Report Series. Vol. 53A, Pg. 512, 1974.
rat LDLo oral 7500mg/kg (7500mg/kg)   National Technical Information Service. Vol. OTS0555808,

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