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Synthesis and structure of the first transition metal complex with methanesulfonylhydrazine as a ligand

Synthesis and structure of the first transition metal complex with methanesulfonylhydrazine as a ligand. Ienco, A.In this study， 10393-86-9 and 476631-08-0 are also used.; Mealli, C.; Dodoff, N. I. (ICCOM CNR, Florence 50139, Italy). Zeitschrift fuer Naturforschung, B: Chemical Sciences, 57(8), 865-867 (English) 2002 Verlag der Zeitschrift fuer Naturforschung. CODEN: ZNBSEN. ISSN: 0932-0776. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75 The article reports the first transition metal complex of methanesulfonylhydrazine, a mol. known for important pharmacol. and chem. applications. [ZnCl2(MSH)2], MSH = CH3SO2NHNH2, was synthesized and its structure characterized by x-ray anal. The coordination geometry is pseudo-tetrahedral and the ligand MSH adopts a conformation that was found by previous ab initio calcns. to be a transition state and not a stationary point for the free ligand. .