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CAS No.: | 118625-56-2 |
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Name: | 1-Hexadecene, 16-bromo- |
Article Data: | 3 |
Molecular Structure: | |
Formula: | C16H31Br |
Molecular Weight: | 303.326 |
Synonyms: | 16-Bromo-1-hexadecene;1-Hexadecene,16-bromo; |
PSA: | 0.00000 |
LogP: | 6.63860 |
Conditions | Yield |
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Stage #1: bromopentene With iodine; magnesium In tetrahydrofuran at 50℃; for 4h; Inert atmosphere; Stage #2: 1,11-dibromoundecane With 1-methyl-pyrrolidin-2-one; dilithium tetrachlorocuprate(II) In tetrahydrofuran at 0 - 20℃; for 16h; Inert atmosphere; | 57% |
Conditions | Yield |
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With dilithium tetrachlorocuprate; magnesium Yield given; |
Conditions | Yield |
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With magnesium; dilithium tetrachlorocuprate 1.) Et2O, ref., 6.0 h; 2.) THF, Et2O, from 0 deg C to r.t., 16 h; Yield given. Multistep reaction; |
10-Undecen-1-ol
ω-hexadecenyl bromide
Conditions | Yield |
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Multi-step reaction with 3 steps 2: LiBr 3: Mg, Li2CuCl4 View Scheme |
undec-10-en-1-yl methanesulfonate
ω-hexadecenyl bromide
Conditions | Yield |
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Multi-step reaction with 2 steps 1: LiBr 2: Mg, Li2CuCl4 View Scheme |
ω-hexadecenyl bromide
potassium phtalimide
N-(15-hexadecenyl)-1-phthalimide
Conditions | Yield |
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In N,N-dimethyl-formamide at 150℃; for 1.5h; | 90% |
Conditions | Yield |
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In N,N-dimethyl-formamide at 65℃; for 3h; | 79% |
Conditions | Yield |
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Stage #1: diiodomethane With diethylzinc; trifluoroacetic acid In hexane; dichloromethane at 0℃; for 0.333333h; Stage #2: ω-hexadecenyl bromide In hexane; dichloromethane Cooling with ice; | 79% |
Conditions | Yield |
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In dimethyl sulfoxide | 73% |
ω-hexadecenyl bromide
1-bromo-16-(trichlorosilyl)hexadecane
Conditions | Yield |
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With trichlorosilane; dihydrogen hexachloroplatinate | 70% |
With dihydrogen hexachloroplatinate; trichlorosilane In isopropyl alcohol at 60℃; | 70% |