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CAS No.: | 1193-81-3 |
---|---|
Name: | 1-Cyclohexylethanol |
Article Data: | 202 |
Molecular Structure: | |
Formula: | C8H16O |
Molecular Weight: | 128.214 |
Synonyms: | (1-Hydroxyethyl)cyclohexane;1-Cyclohexane-1-ethanol;1-Cyclohexyl-1-ethanol;Cyclohexylmethylcarbinol;Ethanol, 1-cyclohexyl-;Methanol, cyclohexylmethyl-;Methylcyclohexylcarbinol;Methylcyclohexylmethanol;NSC 44898;NSC 9476;Surflot 944;a-Methylcyclohexanemethanol; |
EINECS: | 214-780-7 |
Density: | 0.928 g/mL at 25 °C(lit.) |
Melting Point: | 140 °C |
Boiling Point: | 189 °C(lit.) |
Flash Point: | 163 °F |
Solubility: | 5.163g/L at 24℃ |
Risk Codes: | 36/37/38 |
Safety: | 23-24/25 |
PSA: | 20.23000 |
LogP: | 1.94750 |
Conditions | Yield |
---|---|
With hydrogen In water at 100℃; under 15001.5 Torr; for 0.333333h; | 100% |
With ruthenium nanoparticles at 120℃; under 90009 Torr; for 2h; Ionic liquid; Autoclave; | 99% |
With ruthenium; hydrogen In water at 30℃; under 22801.5 Torr; for 12h; Autoclave; | 94% |
Conditions | Yield |
---|---|
Stage #1: Cyclohexyl methyl ketone With formic acid; tricarbonyl (4S,7S)-4,7-bis(benzyloxy)-1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one iron; triethylamine for 0.166667h; Inert atmosphere; Stage #2: With trimethylamine-N-oxide at 60℃; for 48h; Reagent/catalyst; Concentration; Temperature; | 97% |
With sodium isopropylate; isopropyl alcohol; ruthenium complex C38H42N2O4P2Ru for 5h; Catalytic hydrogenation; Catalytic transfer hydrogenation; | 91% |
With methanol; sodium tetrahydroborate at 0 - 20℃; for 0.666667h; Inert atmosphere; | 88% |
rac-1-cyclohexylethanol
Conditions | Yield |
---|---|
With water; scandium tris(trifluoromethanesulfonate) In acetonitrile for 4h; Ambient temperature; | 97% |
methyltrichlorotitanium
cyclohexanone
A
1-Methylcyclohexanol
B
rac-1-cyclohexylethanol
Conditions | Yield |
---|---|
With Methyltitantrichlorid,Triphenylphosphin; cyclohexanecarbaldehyde In dichloromethane at -25℃; for 6h; Product distribution; other phosphane-complexes and reagents; | A 95% B 3% |
Conditions | Yield |
---|---|
With Methyltitantrichlorid,Triphenylphosphin; cyclohexanecarbaldehyde In dichloromethane at 0℃; for 6h; | A 95% B 3% |
2-methyl-1-oxaspiro[2.5]octane
A
1-ethylcyclohexanol
B
rac-1-cyclohexylethanol
Conditions | Yield |
---|---|
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran Product distribution; Mechanism; Ambient temperature; other epoxides, reaction without cyclohexa-1,4-diene; | A 1.5% B 92% C 0.9% |
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran Ambient temperature; | A 1.5% B 92% C 0.9% |
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran for 0.666667h; Product distribution; Mechanism; other epoxides; other H-atom donors; var. temperature, var. time; | A 1.5% B 64% C 0.9% |
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran for 0.25h; | A n/a B 64% C 0.9% |
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran for 0.25h; Yields of byproduct given; | A n/a B n/a C 0.9% |
2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol
A
1,3-dimethoxy-2-hydroxy-benzene
B
ethylbenzene
C
rac-1-cyclohexylethanol
Conditions | Yield |
---|---|
With Ni0.85Ru0.15; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst; | A 92% B 58% C 22% |
rac-1-cyclohexylethanol
Conditions | Yield |
---|---|
With water; boric acid at 20℃; for 1h; | 90% |
methyltrichlorotitanium
cyclohexanecarbaldehyde
A
n-hexan-2-one
B
rac-1-cyclohexylethanol
Conditions | Yield |
---|---|
With n-hexan-2-one; Methyltitantrichlorid,Triphenylphosphin In dichloromethane at -25℃; for 6h; Product distribution; other phosphane-complexes and reagents; | A 6% B 89% |
Conditions | Yield |
---|---|
With n-hexan-2-one; Methyltitantrichlorid,Triphenylphosphin In dichloromethane at -25℃; for 6h; | A 6% B 89% |
Chemical Name: 1-Cyclohexylethanol
IUPAC NAME: 1-Cyclohexylethanol
CAS No.: 1193-81-3
EINECS: 214-780-7
RTECS: GV5776500
RTECS Class: Primary Irritant
Molecular Formula: C8H16O
Molecular Weight: 128.21 g/mol
Density: 0.884 g/cm3
Flash Point: 80.2 °C
Boiling Point: 192 °C at 760 mmHg
Following is the structure of 1-Cyclohexylethanol (CAS No.1193-81-3):
The chemical synonymous of 1-Cyclohexylethanol (CAS No.1193-81-3) are (R,S)-1-Cyclohexyl-ethanol ; 1-Cyclohexyl-1-ethanol ; 2-Methylcyclohexylmethanol ; alpha-Methyl-cyclohexanemethano ; Cyclohexanemethanol, alpha-methyl- ; Ethanol, 1-cyclohexyl- ; Methanol, cyclohexylmethyl- ; Methylcyclohexylcarbinol
1. | skn-rbt 500 µL/24H SEV | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 . | ||
2. | eye-rbt 100 µL/24H MLD | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 . | ||
3. | orl-rat LD50:2100 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 . | ||
4. | skn-rbt LDLo:1 g/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 . |
Moderately toxic by ingestion and skin contact. A severe skin and mild eye irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Statements about 1-Cyclohexylethanol (CAS No.1193-81-3):
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements about 1-Cyclohexylethanol (CAS No.1193-81-3):
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.