Detail of "12092-47-6"

CAS Number:
12092-47-6
Name:
Rhodium, di-m-chlorobis[(1,2,5,6-h)-1,5-cyclooctadiene]di-
Superlist Name:
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Molecular Structure:
Formula:
C₁₆H₂₄Cl₂Rh₂
Molecular Weight:
493.08
Deleted CAS:
11067-06-4|116464-46-1|58006-04-5|69039-68-5
Synonyms:
(1,5-Cyclooctadiene)rhodium chloride dimer;Bis((1,5-cyclooctadiene)(chloro)rhodium);Bis((m-chloro)(h4-1,5-cyclooctadiene)rhodium);Dichlorobis(1,5-cyclooctadiene)rhodium(I);Rhodium 1,5-cyclooctadiene chloridedimer;Rhodium,di-m-chlorobis(1,5-cyclooctadiene)di-(8CI);Bis(chloro(1,5-cyclooctadiene)rhodium);Bis(cyclooctadiene)dichlorodirhodium;Bis(cyclooctadienerhodium chloride);Bis(m-chloro)bis(1,5-cyclooctadiene)dirhodium;Bis(m2-chloro)bis(1,5-cyclooctadiene)dirhodium;Chloro(cyclooctadiene)rhodium dimer;Chlororhodium (1,5-cyclooctadiene) dimer;Di-m-Chlorobis(1,5-cyclooctadiene)dirhodium;Di-m-chlorobis(h4-1,5-cyclooctadiene)dirhodium(I);
EINECS:
235-157-6
Melting Point:
243 °C (dec.)(lit.)
Appearance:
orange crystals
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
26-37/39 Details

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CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Dichlorobis(1,5-cyclooctadiene) dirhodium(I) Molecular Formula C16H24Cl2Rh2 Molecular Weight 493.08 CAS Registry Number 12092-47-6 EINECS 235-157-6 Properties Melting point 255 oC (dec.) Safety Data Hazard Symbols Xi Risk Codes R36/

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CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Chloro (1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6 Standard: in-house standard One of Sitagliptin intermediates

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CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride

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CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

[Rh(C8H12)Cl]2

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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Reference

1,3-Diene polymerization catalyst: 1,3-Diene polymerization catalyst. Yoshioka, Akira; Sugimura, Takaaki; Takahashi, Mari (Nippon Zeon Co., Ltd., Japan). Japan. Kokai JP 52110293 16 Sep 1977 Showa, 5 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C08F004-80. APPLICATION: JP 76-26792 12 Mar 1976. DOCUMENT TYPE: Patent CA Section: 38 (Elastomers, Including Natural Rubber) C5-12 polyene-Rh complex (I) [optionally modified with 1-1000 mol (per mol I) of org. P or N compd., or an allyl alc. or ether] 1, anionic surfactant 31, and water 31 mol are mixed to give the title catalyst, which is used to prep. diene polymers with high 1,4 unit content. Thus, water 220, sodium dodecylbenzenesulfonate 5, and isoprene 100 g were emulsified, mixed with 0.3 g dichlorobis(cycloocta-1,5-diene)dirhodium [12092-47-6] in 15 g CHCl3 and 7.4 g allyl alc. [107-18-6], stirred at 50° for 4 days under N, added to phenyl-2-naphthylamine in MeOH, and sepd. Conversion was 89%, and the polymer contained cis-1,4 50.9, trans-1,4 44.6, and 1,2 4.5%. The intrinsic viscosity was 1.2, yield stress 0.5, breaking strength 0.8 kg/cm2, and breaking elongation 1200% as compared with 4.2, 1.0, 0.3, and 800 for a product prepd. with a Ziegler-Natta catalyst.

Rhodium complexes as catalysts for hydrosilylation crosslinking of silicone rubber: Rhodium complexes as catalysts for hydrosilylation crosslinking of silicone rubber. Heidingsfeldova, Marta; Capka, Martin (Inst. Chem. Technol., Prague 166 28/6, Czech.). J. Appl. Polym. Sci., 30(5), 1837-46 (English) 1985. CODEN: JAPNAB. ISSN: 0021-8995. DOCUMENT TYPE: Journal CA Section: 39 (Synthetic Elastomers and Natural Rubber) Vulcanization of silicone rubber compds. based on siloxanes contg. vinyl and Si-H groups catalyzed by [RhCl(CO)2]2 [14523-22-9], [RhCl(C2H4)2]2] [12081-16-2], [RhCl(1,5-COD)]2 [12092-47-6], [RhCl(NBD)]2 [12257-42-0], RhCl[P(C6H5)3]3 [14694-95-2], and Rh(acac)3 [14284-92-5] (1,5-COD = 1,5-cyclooctadiene, NBD = norbornadiene, acac = acetylacetonate) was studied with respect to the catalyst, solvent, and reaction conditions. The course of vulcanization as well as the crosslinking d. of the vulcanizate and the content of sol indicate that the above catalysts are comparable to, and in some cases even better than, the widely used hexachloroplatinic acid.

Detail of "12092-47-6"

Rhodium, di-m-chlorobis[(1,2,5,6-h)-1,5-cyclooctadiene]di-

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CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS No.12092-47-6 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Reference