Products Categories
| CAS No.: | 2457-80-9 | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Name: | 5'-DEOXY-5'-METHYLTHIOADENOSINE | ||||||||
| Article Data: | 34 | ||||||||
| Molecular Structure: | |||||||||
|
|
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| Formula: | C11H15 N5 O3 S | ||||||||
| Molecular Weight: | 297.338 | ||||||||
| Synonyms: | 5'-(Methylthio)-5'-deoxyadenosine;5'-(Methylthio)adenosine; 5'-Deoxy(methylthio)adenosine;5'-Deoxy-5'-(methylthio)adenosine; 5'-S-Methyl-5'-thioadenosine;5'-S-Methylthioadenosine; NSC 335422; Vitamin L2; b-D-Ribofuranose,1-(6-amino-9H-purin-9-yl)-1-deoxy-5-S-methyl-5-thio- | ||||||||
| Density: | 1.85g/cm3 | ||||||||
| Melting Point: |
210-213 °C (dec.) |
||||||||
| Boiling Point: | 642.7°Cat760mmHg | ||||||||
| Flash Point: | 342.5°C | ||||||||
| Safety: |
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| PSA: | 144.61000 | ||||||||
| LogP: | -0.02810 | ||||||||
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- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide -30 deg C to r.t., overnight; | 86% |
| With sodium hydroxide In methanol; water at 75℃; for 24h; | 75% |
| With sodium hydride In N,N-dimethyl-formamide | |
| With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl-formamide at 40℃; for 12h; |
- 892-48-8
5'-deoxy-5'-chloroadenosine
- 5188-07-8
sodium thiomethoxide
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| In water at 75℃; for 24h; | 65% |
| In N,N-dimethyl-formamide at 20℃; | 50% |
| Conditions | Yield |
|---|---|
| With tributylphosphine In N,N-dimethyl-formamide for 240h; | 38% |
- 69660-30-6
9-((3aR,4R,6S,6aS)-2,2-dimethyl-6-((methylthio)methyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)-9H-purin-6-amine
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| With sulfuric acid | |
| With sulfuric acid; acetone | |
| With sulfuric acid; acetic acid |
- 119771-16-3
2',3'-Di-O-acetyl-5'-deoxy-5'-(methylthio)adenosine sulfoxide
A
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
B
- 118560-47-7
5'-Deoxy-5'-<(monofluoromethyl)thio>adenosine
| Conditions | Yield |
|---|---|
| With dimethylaminosulphur trifluoride; ammonia 1) CHCl3, 55 deg C, 2.5-3 h, 2) MeOH, r.t., 2.5 h; Yield given. Multistep reaction. Yields of byproduct given; |
- 83332-24-5
[(2S,3S,4R,5R)-5-(6-Amino-purin-9-yl)-3,4-dihydroxy-tetrahydro-furan-2-ylmethyl]-[3-(2-hydroxy-phenyl)-3-methyl-butyl]-methyl-sulfonium
A
- 40614-27-5
4,4-dimethylchromane
B
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| With acetate buffer In water at 40℃; pH 4 to 10; | |
| With acetate buffer In water at 40℃; Mechanism; other oxyanion buffers; amine buffers; |
- 83332-24-5
[(2S,3S,4R,5R)-5-(6-Amino-purin-9-yl)-3,4-dihydroxy-tetrahydro-furan-2-ylmethyl]-[3-(2-hydroxy-phenyl)-3-methyl-butyl]-methyl-sulfonium
A
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| With amine buffer In water at 40℃; pH > 10; |
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| With extractene from cultures of yeast | |
| With aerobacter aerogenes |
A
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| With water pH 4-6; |
- 662131-88-6
5'-chloro-5'-deoxy-2',3'-O-sulfinyladenosine
- 2457-80-9
5'-Deoxy-5'-methylthioadenosine
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 98 percent / water; methanol / 20 °C 2: 50 percent / dimethylformamide / 20 °C View Scheme | |
| Multi-step reaction with 2 steps 1: conc. aq. NH4OH / methanol / 1 h / Ambient temperature 2: 75 percent / NaOH / H2O; methanol / 24 h / 75 °C View Scheme |
