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| CAS No.: | 2749-11-3 |
|---|---|
| Name: | L-Alaninol |
| Article Data: | 105 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H9NO |
| Molecular Weight: | 75.1106 |
| Synonyms: | 1-Propanol,2-amino-, (S)-;((S)-2-Hydroxy-1-methylethyl)amine;(+)-2-Aminopropanol;(+)-Alaninol;(2S)-2-Amino-1-propanol;(S)-2-Amino-1-propanol;(S)-Alaninol;2-(S)-Amino-propan-1-ol;L-(+)-Alaninol; |
| EINECS: | 220-388-7 |
| Density: | 0.943 g/cm3 |
| Melting Point: | -2 °C |
| Boiling Point: | 174.5 °C at 760 mmHg |
| Flash Point: | 83.9 °C |
| Solubility: | Completely miscible in water |
| Appearance: | Colorless liquid |
| Hazard Symbols: |
 Xi, C
|
| Risk Codes: | 34-36/37/38 |
| Safety: | 26-36/37/39-45-36 |
| Transport Information: | UN 2735 8/PG 2 |
| PSA: | 46.25000 |
| LogP: | 0.02620 |
- 483366-12-7(2S,4R)-1-Boc-2-cyano-4-hydroxypyrrolidine
- 361456-36-2METHYL (R)-(+)-ISOCYANATO-3-PHENYLPROPI&
- 5156-58-1N-(1-Benzyl-4-pipperidinyl)-N-phenylpropanamide HCl
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- 50288-62-5threo-Phenyl-2-piperidyl acetamide
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran Heating; | 97% |
| With lithium aluminium tetrahydride In tetrahydrofuran Heating; | 95% |
| With sulfuric acid; hydrogen In water at 39.84℃; under 60006 Torr; Concentration; Reagent/catalyst; | 93.7% |
- 2749-11-3
(S)-Alaninol
| Conditions | Yield |
|---|---|
| With potassium hydroxide In ethanol at 20℃; Reagent/catalyst; | 92.2% |
- 157985-07-4
(-)-(3R,5S)-5-methyl-3-phenylmorpholin-2-one
- 2749-11-3
(S)-Alaninol
| Conditions | Yield |
|---|---|
| With hydrogen; palladium on activated charcoal In methanol under 112509 Torr; for 72h; | 89% |
| With hydrogen; palladium on activated charcoal In methanol under 114000 Torr; for 72h; Hydrogenolysis; ring cleavage; methanolysis; | 89% |
- 10065-72-2
L-Alanine methyl ester
- 2749-11-3
(S)-Alaninol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride | 78% |
| With lithium aluminium tetrahydride In tetrahydrofuran for 4h; Heating; | 30% |
| With hydrogen; Nishimura catalyst <(45.9% Rh/19.9% Pt) oxide> In methanol at 25℃; under 75007.5 Torr; |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride | 74% |
| With sodium tetrahydroborate In ethanol Heating; | 16.9% |
| Conditions | Yield |
|---|---|
| With C24H20ClN2OPRu; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 2280.15 - 30402 Torr; for 48h; Inert atmosphere; Schlenk technique; Autoclave; | 65% |
- 6003-05-0, 16428-74-3, 25616-13-1, 26570-06-9
L-alanine hydrochloride
- 2749-11-3
(S)-Alaninol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 12h; Reflux; Inert atmosphere; | 51.1% |
| Conditions | Yield |
|---|---|
| With phosphoric acid; hydrogen In water at 79.84℃; under 7500.75 - 60006 Torr; for 4h; Concentration; Reagent/catalyst; | A 42.2% B n/a |
| With sulfuric acid; hydrogen In water at 79.84℃; under 60006 Torr; for 2h; Catalytic behavior; Autoclave; |
- 200434-95-3
(Z,E)-2-amino-6-chloro-9-[(2-carbethoxycyclopropylidene)methyl]purine
A
- 2749-11-3
(S)-Alaninol
B
- 200435-01-4
anti-2-amino-6-chloro-N9-(2-hydroxymethylcyclopropylidenemethyl)purine
| Conditions | Yield |
|---|---|
| With diisobutylaluminium hydride In tetrahydrofuran; cyclohexane at 0℃; for 2h; | A 41.8% B 23.3% |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; diethyl ether | |
| With lithium aluminium tetrahydride |
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Chemistry
The Molecular Structure of L-Alaninol (CAS NO.2749-11-3):
Empirical Formula: C3H9NO
Molecular Weight: 75.1097
IUPAC Name: 2-aminopropan-1-ol
Appearance: Colorless liquid
Nominal Mass: 75 Da
Average Mass: 75.1097 Da
Monoisotopic Mass: 75.068414 Da
Index of Refraction: 1.439
Molar Refractivity: 20.97 cm3
Molar Volume: 79.6 cm3
Surface Tension: 35.7 dyne/cm
Density: 0.943 g/cm3
Flash Point: 83.9 °C
Enthalpy of Vaporization: 47.83 kJ/mol
Boiling Point: 174.5 °C at 760 mmHg
Vapour Pressure: 0.373 mmHg at 25°C
Storage temp: 2-8°C
Sensitive: Hygroscopic
Product Categories: Pharmaceutical Intermediates;Pharmaceutical Raw Materials;Alcohols and Derivatives;Amino Alcohols;Alanine [Ala, A];Amino Alcohols (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry;Chiral Compound;Amino alcohols
InChI
InChI=1/C3H9NO/c1-3(4)2-5/h3,5H,2,4H2,1H3
Smiles
N[C@@H](CO)C
Synonyms: EINECS 220-388-7 ; (+)-2-Aminopropan-1-ol ; L-(+)-alaninol;l-alaninol ; L-(+)-2-amino propanol ; L-2-amino-propanol ; H-l-ala-ol ; H-alaninol ; H-ala-ol
Safety Profile
Hazard Codes: 
Xi
C
Risk Statements: 34-36/37/38
R34: Causes burns
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-36/37/39-45-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36: Wear suitable protective clothing
RIDADR: UN 2735 8/PG 2
WGK Germany: 3
F: 10-23
F 10: Keep under argon
F 23: Sensitive to air
HazardClass: 8
PackingGroup: III
Specification
HANDLING and STORAGE about L-Alaninol (CAS NO.2749-11-3):
Handling: Wash thoroughly after handling. Use only in a well-ventilated area.Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Handle under an inert atmosphere. Store protected from air. Discard contaminated shoes. Do not pressurize, cut, weld, braze,solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not expose to air.Store under an inert atmosphere.
FIRST AID MEASURES
Eyes:Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.