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31140-40-6

Basic Information
CAS No.: 31140-40-6
Name: 4-METHOXYCARBONYLPHENYL CHLOROFORMATE
Article Data: 7
Molecular Structure:
Molecular Structure of 31140-40-6 (4-METHOXYCARBONYLPHENYL CHLOROFORMATE)
Formula: C9H7 Cl O4
Molecular Weight: 214.605
Synonyms: Benzoicacid, p-hydroxy-, methyl ester, chloroformate (8CI); 4-Methoxycarbonylphenylchloroformate; 4-[(Chlorocarbonyl)oxy]benzoic acid methyl ester;p-Carbomethoxyphenyl chloroformate; p-Methoxycarbonylphenyl chloroformate
Density: 1.342g/cm3
Melting Point: 51-54oC
Boiling Point: 283.3°Cat760mmHg
Flash Point: 120°C
PSA: 52.60000
LogP: 2.21080
Synthetic route
75-44-5

phosgene

99-76-3

methyl 4-hydroxylbenzoate

31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

Conditions
ConditionsYield
With quinoline; benzene
In benzene
With pyridine In toluene
With quinoline; toluene
31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

156286-12-3

1,2-(2,3-dihydro-1H-azirino)-<60>fullerene

C69H7NO4

Conditions
ConditionsYield
With pyridine In various solvent(s) at 70℃; for 1h;78%
909015-28-7

1-cyanopyrazolidine

31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

4-[(methyloxy)carbonyl]phenyl 2-cyanopyrazolidine-1-carboxylate

Conditions
ConditionsYield
In dichloromethane at 20℃;45.2%

bis(tetrabutylammonium)-closo-dodecahydroxy-dodecaborate

31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

2C16H36N(1+)*C108H84B12O60(2-)

Conditions
ConditionsYield
With pyridine In acetonitrile at 0 - 20℃; Inert atmosphere;32%

closo-B12(OH)12(2-)

31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

B12(OCO2C6H4COOCH3)12(2-)

Conditions
ConditionsYield
With pyridine In acetonitrile B12(OH)12(2-), chloroformate, pyridine, acetonitrile (excess), 96 h, room temp.; filtered, the solvent was removed under vac., the residue was pptd. fromCH2Cl2 with diethyl ether, benchtop flash column chromy. using gradient of CH2Cl2 and CH3CN over neutral alumina;32%
1191406-61-7

C14H22N2S8

31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

1191406-63-9

C30H40N4O2S16

Conditions
ConditionsYield
With pyridine In tetrahydrofuran at 20℃; Inert atmosphere;30%
31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

283-38-5

1,4-diazabicyclo[3.2.2]nonane

1,4-diaza-bicyclo[3.2.2]nonane-4-carboxylic acid 4-methoxycarbonyl-phenyl ester

Conditions
ConditionsYield
25%
909015-29-8

1-cyanohexahydropyridazine

31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

4'-[(methyloxy)carbonyl]phebyl 2-cyanotetrahydropyridazine-1-carboxylate

Conditions
ConditionsYield
In dichloromethane at 20℃;1%
31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

100-37-8

2-(Diethylamino)ethanol

carbonic acid-(2-diethylamino-ethyl ester)-(4-methoxycarbonyl-phenyl ester)

Conditions
ConditionsYield
With benzene
With benzene
31140-40-6

methyl 4-[(chlorocarbonyl)oxy]benzoate

100-37-8

2-(Diethylamino)ethanol

A

carbonic acid-(2-diethylamino-ethyl ester)-(4-methoxycarbonyl-phenyl ester)

B

74721-70-3

dimethyl 4,4′-(carbonylbis(oxy))dibenzoate

Conditions
ConditionsYield
With benzene
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