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CAS No.: | 4875-10-9 |
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Name: | 2-NITROTHIOPHENOL |
Article Data: | 50 |
Molecular Structure: | |
Formula: | C6H5 N O2 S |
Molecular Weight: | 155.177 |
Synonyms: | Benzenethiol,o-nitro- (6CI,7CI,8CI); 2-Nitrobenzenethiol; 2-Nitrothiophenol;o-Mercaptonitrobenzene; o-Nitrobenzenethiol; o-Nitrothiophenol |
Density: | 1.362g/cm3 |
Melting Point: | 56 °C |
Boiling Point: | 262.5°Cat760mmHg |
Flash Point: | 112.6°C |
PSA: | 84.62000 |
LogP: | 2.40670 |
Conditions | Yield |
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With sodium tetrahydroborate In tetrahydrofuran | 100% |
With triisopropoxyborohydride In tetrahydrofuran at 0℃; for 0.25h; | 92% |
With triphenylphosphine; 2-hydroxyethanethiol In tetrahydrofuran; water at 50℃; for 21h; Inert atmosphere; | 90% |
Conditions | Yield |
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With sodium tetrahydroborate; zirconium(IV) chloride In tetrahydrofuran at 35℃; for 0.5h; Reduction; | A 10% B 90% |
With sodium tetrahydroborate; zirconium(IV) chloride In tetrahydrofuran at 35℃; for 0.166667h; Reduction; | A 80% B 20% |
Conditions | Yield |
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With sodium sulfide In N,N-dimethyl-formamide for 62h; Ambient temperature; | 87% |
With thiourea In ethanol Heating; | 60% |
With ethanol; sodium disulfide |
4-o-nitrophenylthio-1,2-naphthoquinone
A
2-Hydroxy-1,4-naphthoquinone
B
2-nitrothiophenol
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water for 0.0333333h; | A 80% B n/a |
Conditions | Yield |
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In hydrogenchloride | 61% |
Conditions | Yield |
---|---|
With sodium sulfide In N,N-dimethyl-formamide for 62h; Ambient temperature; | A 60% B 25% |
With sodium sulfide In dimethyl sulfoxide at 50℃; for 0.5h; Product distribution; further reagents, further solvent, further substituted o-chloronitrobenzenes, further times and temp.; | A 10% B 50% |
bis(2-nitrophenyl)disulfide
ethanol
glucose
2-nitrothiophenol
methanol
bis(phenylsulfonyl)methane
sodium methylate
A
2-nitrothiophenol
B
Bis(phenylsulfonyl)(phenylthio)methane
Conditions | Yield |
---|---|
anschliessendes Behandeln mit <2-Nitro-phenyl>-phenyl-disulfid; |
ethanol
(2-nitro-phenyl)-phenyl disulfide
potassium thiophenolate
A
bis(2-nitrophenyl)disulfide
B
2-nitrothiophenol
C
diphenyldisulfane
2-nitrobenzenesulfenyl bromide
2-nitrothiophenol
Conditions | Yield |
---|---|
With phosphorus tribromide Verduennen mit Aether und anschliessendes Versetzen mit Wasser; |