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Basic Information
CAS No.: 506-64-9
Name: Silver cyanide
Article Data: 122
Molecular Structure:
Molecular Structure of 506-64-9 (Silver cyanide)
Formula: AgCN
Molecular Weight: 133.886
Synonyms: Silvercyanide (Ag2(CN)2);Silver monocyanide;Silver(1+) cyanide;Silver(I) cyanide;
EINECS: 208-048-6
Density: 3.95 g/cm3
Melting Point: 300 °C
Boiling Point: 25.7°C at 760 mmHg
Solubility: insoluble in water
Appearance: white to off-white powder
Hazard Symbols: ToxicT,DangerousN,VeryT+
Risk Codes: 25-32-33-41-50/53-26/27/28
Safety: 7-26-45-60-61-29-28A
Transport Information: UN 1684 6.1/PG 2
PSA: 23.79000
LogP: 0.01678
Synthetic route
74-90-8

hydrogen cyanide

silver sulfate

506-64-9

silver(I) cyanide

Conditions
ConditionsYield
addition of Ag2SO4 to liquid HCN;;100%
In neat (no solvent) byproducts: H2SO4; shaking in a closed tube for several hours;;
In neat (no solvent) byproducts: H2SO4; shaking in a closed tube for several hours;;
74-90-8

hydrogen cyanide

3315-16-0

silver cyanate

506-64-9

silver(I) cyanide

Conditions
ConditionsYield
addition of AgNCO to liquid HCN at 25°C;;42%
563-63-3

silver(I) acetate

592-04-1

mercury(II) cyanide

506-64-9

silver(I) cyanide

71680-52-9, 130166-69-7

ammonium cyanide

506-64-9

silver(I) cyanide

Conditions
ConditionsYield
With sodium carbonate; silver nitrate
With potassium carbonate; silver nitrate
With silver nitrate

ethyl-malononitrile; silver (I)-compound

506-64-9

silver(I) cyanide

Conditions
ConditionsYield
at 0℃; Sehr zersetzlich;

trimethyl-amine; cyanide, compound with silver (I)-cyanide

506-64-9

silver(I) cyanide

Conditions
ConditionsYield
at 25℃;

tetramethyl-ammonium; cyanide, compound with silver (I)-cyanide

A

593-75-9, 685498-28-6

methyl isocyanate

B

506-64-9

silver(I) cyanide

C

75-05-8

acetonitrile

D

75-50-3

trimethylamine

Conditions
ConditionsYield
bei der Destillation;

4-bromo-benzenediazonium; cyanide, compound with silver (I)-cyanide

64-19-7

acetic acid

506-64-9

silver(I) cyanide

silver nitrate

1187-42-4

diaminomaleonitrile

506-64-9

silver(I) cyanide

513-96-2

3,3,3-trichloro-2-hydroxy-propionitrile

silver nitrate

506-64-9

silver(I) cyanide

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Consensus Reports

Silver and its compounds, as well as cyanide and its compounds, are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Standards and Recommendations

DOT Classification:  6.1; Label: Poison
OSHA PEL: TWA 5 mg(CN)/m3
ACGIH TLV: CL 5 mg(CN)/m3 (skin)
DFG MAK: 5 mg/m3
NIOSH REL: (Cyanide) CL 5 mg(CN)/m3/10M

Specification

The IUPAC name of Silver cyanide is silver cyanide. With the CAS registry number 506-64-9, it is also named as Kyanid stribrny. The product's categories are Inorganics; Metal and Ceramic Science; Salts; Silver Salts, and the other registry numbers are 12351-98-3; 29829-51-4. Besides, it is white to off-white powder, which should be stored in sealed package in a cool, dry and well ventilated warehouse away from fire and heat source. It forms structurally complex materials upon reaction with other anions. In addition, this chemical is insoluble in water and incompatible with strong acids, ammonia, hydrogen peroxide. It forms an explosive mixture with fluorine, which may decompose in light.

The other characteristics of this product can be summarized as: (1)EINECS: 208-048-6; (2)H-Bond Donor: 0; (3)H-Bond Acceptor: 2; (4)Rotatable Bond Count: 0; (5)Exact Mass: 132.908167; (6)MonoIsotopic Mass: 132.908167; (7)Topological Polar Surface Area: 23.8; (8)Heavy Atom Count: 3; (9)Complexity: 10; (10)Density: 3.95 g/cm3; (11)Melting point: 300 °C.

Preparation of Silver cyanide: you can add the solution of Silver nitrate to the solution of Potassium cyanide or Sodium cyanide to precipitate. And you will obtain this chemical. The reaction equations are as follows:



or

Uses of Silver cyanide: this chemical is used as lining of autoclave which is used in medicine, silver plating and protective coating. It is also used for electrofacing of electrical contact and engine bearings of airplane. Additionally, it is used as plating reagent and additive of precious metal, analytical reagent. Furthermore, it can be used to produce Oxalonitrile.



This reaction will occur at temperature of 350 °C. The yield is 75 %.

When you are using this chemical, please be cautious about it as the following: it is very toxic by inhalation, in contact with skin and if swallowed. It contacts with acid liberates very toxic gas. Please keep container tightly closed. It is danger of cumulative effects and risk of serious damage to the eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. What's more, it is toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste. Please do not empty into drains. And you should avoid release to the environment. Refer to special instructions / safety data sheets. Moreover, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.).

People can use the following data to convert to the molecule structure.
(1)SMILES: [C-]#N.[Ag+]
(2)InChI: InChI=1/CN.Ag/c1-2;/q-1;+1
(3)InChIKey: LFAGQMCIGQNPJG-UHFFFAOYAM
(4)Std. InChI: InChI=1S/CN.Ag/c1-2;/q-1;+1
(5)Std. InChIKey: LFAGQMCIGQNPJG-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 123mg/kg (123mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 13, 1972.