CAS No.6921-34-2,Magnesium,chloro(phenylmethyl)- Suppliers,MSDS download

Detail of "6921-34-2"

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CAS Number:

6921-34-2

Name:

Magnesium,chloro(phenylmethyl)-

Superlist Name:

Benzylmagnesium chloride

Molecular Structure:

Formula:

C₇H₇ClMg

Molecular Weight:

150.89

Synonyms:

Benzylmagnesiumchloride (6CI);Magnesium, benzylchloro- (7CI,8CI);Benzene, methyl-, magnesiumcomplex;(Phenylmethyl)magnesium chloride;Benzylchloromagnesium;

EINECS:

230-039-0

Density:

1.031 g/mL at 25 °C

Flash Point:

-17 °C

Solubility:

vigorous reaction in water

Appearance:

clear green-brown to brown-purple solution

Hazard Symbols:

Risk Codes:

11-14/15-19-45

Safety:

16-26-36/37/39-43-45-6 Details

Transport Information:

UN 2924

Reference

Synthesis of 2-ethyl-2-phenylacetophenone by alkylation of deoxybenzoin: Some chemicals with cas registry numbers like 100-47-0 and 6921-34-2 are also used. Synthesis of 2-ethyl-2-phenylacetophenone by alkylation of deoxybenzoin. Tanchuk, Yu. V.; Doroshenko, V. A. (Inst. Bioorg. Chem. and Petrochem., NAS of Ukraine, Kiev 02094, Ukraine). Kataliz i Neftekhimiya, (12), 89-91 (Ukrainian) 2004 Institut Bioorganicheskoi Khimii i Neftekhimii NAN Ukrainy. CODEN: KATNFD. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) 2-Ethyl-2-phenylacetophenone, an intermediate in the synthesis of anticancer agent Tamoxifen, was readily prepd. by ethylation of deoxybenzoin with EtBr under phase-transfer conditions. A simple procedure for prepn. of deoxybenzoin has also been developed. .

Ansa-di(phosphaneiminato)titanium chelates: novel isolobal analogues of ansa-titanocene derivatives: 6921-34-2 is also in the experiment. Ansa-di(phosphaneiminato)titanium chelates: novel isolobal analogues of ansa-titanocene derivatives. Siemeling, Ulrich; Koelling, Lars; Stammler, Anja; Stammler, Hans-Georg (Department of Physics, University of Kassel, Kassel D-34132, Germany). Journal of the Chemical Society, Dalton Transactions, (17), 3277-3279 (English) 2002 Royal Society of Chemistry. CODEN: JCSDAA. ISSN: 1472-7773. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 75 Dialkyltitanium complexes contg. eight-membered bis(phosphinoimidato)-N,N' chelate cycle are described. (Me3SiN)But2P(CH2)3PBut2(NSiMe3) (1) was obtained by the Staudinger reaction from Me3SiN3 and But2P(CH2)3PBut2. Transmetalation of 1 with TiCl4 in boiling toluene afforded the chelate [LTiCl2] (2) (L = [NBut2P(CH2)3PBut2N-kN,kN']). Dialkyltitanium complexes [LTiMe2] (3) and [LTi(CH2Ph)2] (4) were obtained from 2 by reaction with methyllithium and benzylmagnesium chloride, resp. The crystal structures of 3 and 4 were detd. Both compds. exhibit two quite different bond angles at their resp. nitrogen atoms (ca. 140° vs. ca. 160°). .

Detail of "6921-34-2"

Magnesium,chloro(phenylmethyl)-

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Reference