Detail of > 69610-40-8
- CAS Number:
- 69610-40-8
- Name:
1-Pyrrolidinecarboxylicacid, 2-(hydroxymethyl)-, 1,1-dimethylethyl ester, (2S)-
- Superlist Name:
- (S)-(-)-1-Boc-2-pyrrolidinemethanol
- Formula:
- C10H19NO3
- Molecular Structure:
- Synonyms:
- 1-Pyrrolidinecarboxylicacid, 2-(hydroxymethyl)-, 1,1-dimethylethyl ester, (S)-;(2S)-1-(tert-Butoxycarbonyl)-2-pyrrolidinemethanol;(2S)-2-Hydroxymethylpyrrolidine-1-carboxylic acid tert-butyl ester;(2S)-Hydroxymethylpyrrolidine-1-carboxylicacid tert-butyl ester;(S)-(+)-N-Boc-prolinol;(S)-(-)-1-(tert-Butoxycarbonyl)-2-pyrrolidinemethanol;(S)-1-BOC-2-Pyrrolidinemethanol;(S)-2-(Hydroxymethyl)pyrrolidine-1-carboxylic acid tert-butyl ester;(S)-N-tert-Butoxycarbonyl-2-pyrrolidinemethanol;(S)-tert-Butyl2-(hydroxymethyl)pyrrolidine-1-carboxylate;1-BOC-2-(S)-Pyrrolidinemethanol;BOC-L-prolinol;Boc-(S)-(-)-2-pyrrolidinemethanol;N-[(tert-Butoxy)carbonyl]-L-prolinol;tert-Butyl(2S)-2-(Hydroxymethyl)-1-pyrrolidinecarboxylate;
- Molecular Weight:
- 201.26
- Density:
- 1.084 g/cm3
- Melting Point:
- 62-64 °C(lit.)
- Boiling Point:
- 289.5 °C at 760 mmHg
- Flash Point:
- 128.9 °C
- Solubility:
- insoluble in water
- Appearance:
- White powder
- Hazard Symbols:
Xi- Risk Codes:
- 36/37/38
- Safety:
- 26-36Details
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Reference
- Optically active a-amino aldehydes
- Optically active a-amino aldehydes.Some chemicals with cas registry numbers like 69610-40-8 and 73343-60-9 are also used. (Daiichi Kagaku Yakuhin K. K., Japan). Jpn. Kokai Tokkyo Koho JP 58150556 A2 7 Sep 1983 Showa, 5 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07C125-06. APPLICATION: JP 82-31818 2 Mar 1982. DOCUMENT TYPE: Patent CA Section: 34 (Amino Acids, Peptides, and Proteins) Section cross-reference(s): 23 Thirteen optically active a-amino aldehydes RR1NCR2R3CHO [R = NH2-protecting groups; R1, R2 = H, alkyl; R3 = H, (un)substituted alkyl, aryl] were prepd. by oxidizing the corresponding optically active alcs. by SO3 complexes in Me2SO in the presence of Et3N. Thus, 955 mg pyridine-SO3 in Me2SO was added to a mixt. of 570 mg L-PhCH2CH(NHZ)CH2OH (Z = PhCH2O2C) and 607 mg Et3N in Me2SO at room temp. to give, after 10 min, 85% L-PhCH2CH(NHZ)CHO. .
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