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CAS No.: | 6971-51-3 |
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Name: | m-Anisyl alcohol |
Article Data: | 187 |
Molecular Structure: | |
Formula: | C8H10O2 |
Molecular Weight: | 138.166 |
Synonyms: | 3-methoxy benzylalcohol;Benzylalcohol, m-methoxy- (6CI,7CI,8CI);(3-Methoxyphenyl)methanol;1-(Hydroxymethyl)-3-methoxybenzene;3-Methoxybenzenemethanol;NSC 66559;[3-(Methyloxy)phenyl]methanol;m-Anisalcohol;m-Methoxybenzyl alcohol;Benzenemethanol,3-methoxy-; |
EINECS: | 230-200-5 |
Density: | 1.085 g/cm3 |
Melting Point: | 29 - 30oC |
Boiling Point: | 247.4 °C at 760 mmHg |
Flash Point: | 109.9 °C |
Solubility: | Immiscible with water |
Appearance: | Colorless to light yellow liquid |
Hazard Symbols: | Xn, Xi |
Risk Codes: | 36/37/38-22 |
Safety: | 23-24/25-37/39-26-36 |
PSA: | 29.46000 |
LogP: | 1.18750 |
Conditions | Yield |
---|---|
With hydrogen; Pd as electrode electrochemical reaction; | 100% |
With sodium tetrahydroborate In methanol at 20℃; for 1h; | 100% |
With sodium tetrahydroborate; Dowex1-x8 In tetrahydrofuran at 20℃; for 0.5h; | 99% |
Conditions | Yield |
---|---|
Stage #1: methyl 3-methoxybenzoate With diethylzinc; lithium chloride In tetrahydrofuran; hexane at 20℃; for 6h; Inert atmosphere; Stage #2: With sodium hydroxide In tetrahydrofuran; hexane; water at 20℃; for 8h; Inert atmosphere; chemoselective reaction; | 98% |
With HN(CH2CH2C3H3N2Mes)2Cl2; potassium tert-butylate; hydrogen; cobalt(II) chloride In tetrahydrofuran at 100℃; under 22502.3 Torr; for 16h; Autoclave; Glovebox; | 91% |
With methanol; sodium tetrahydroborate In tetrahydrofuran at 65℃; for 4h; | 90% |
(3-Methoxy-benzyloxy)-trimethyl-silane
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
With Oxone In methanol for 0.4h; Heating; | 98% |
With bismuth(lll) trifluoromethanesulfonate In methanol at 20℃; for 0.0333333h; | 97% |
With poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite In methanol at 20℃; for 0.00833333h; | 96% |
2-(3-methoxybenzyloxy)tetrahydro-2H-pyran
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
With bismuth(lll) trifluoromethanesulfonate In methanol for 0.05h; | 97% |
With sulfuric acid; silica gel In methanol at 20℃; for 0.5h; | 95% |
With Oxone In methanol for 1.5h; Heating; | 80% |
ethyl 3-methoxybenzoate
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
With lithium borohydride In diethyl ether; toluene at 100℃; for 0.5h; | 95% |
2-tert-butylsulfinyl-3-methoxyphenylmethanol
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
With nickel In ethanol for 3h; Reflux; | 94% |
2-(3-methoxyphenyl)-1,3-dioxolane
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
With sulfuric acid; zinc at 38℃; for 2h; Temperature; | 93.5% |
3-methoxy-1-[(ethoxymethoxy)methyl]benzene
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
phosphotungstic acid In ethanol for 3h; Heating; | 93% |
With 1-methylimidazole hydrogen sulfate at 50℃; for 1.25h; chemoselective reaction; | 92% |
3-methoxy-1-(methoxymethoxy)methyl benzene
3-methoxybenzyl alcohol
Conditions | Yield |
---|---|
With 1-methylimidazole hydrogen sulfate at 120℃; for 0.05h; Microwave irradiation; chemoselective reaction; | 93% |
phosphotungstic acid In ethanol for 3h; Heating; | 89% |
Conditions | Yield |
---|---|
With triethylamine; zinc(II) iodide In toluene at 80℃; for 12h; Schlenk technique; Inert atmosphere; | A n/a B 93% |
1. Introduction of 3-Methoxybenzyl alcohol
3-Methoxybenzyl alcohol is clear colorless liquid for API intermediartes, the IUPAC Name of it is (3-Methoxyphenyl)methanol.
2. Properties of 3-Methoxybenzyl alcohol
Melting Point: 89-91 °C
Product Categories: Benzhydrols, Benzyl & Special Alcohols ; Alcohol
Polar Surface Area: 18.46 Å2
Index of Refraction: 1.531
Molar Refractivity: 39.38 cm3
Molar Volume: 127.2 cm3
Surface Tension: 38.7 dyne/cm
Density of Benzenemethanol,3-methoxy-: 1.085 g/cm3
Flash Point: 109.9 °C
Enthalpy of Vaporization: 51.2 kJ/mol
Boiling Point: 247.4 °C at 760 mmHg
Vapour Pressure: 0.0136 mmHg at 25°C
3. Structure Descriptors of 3-Methoxybenzyl alcohol
InChI=1S/C8H10O2/c1-10-8-4-2-3-7(5-8)6-9/h2-5,9H,6H2,1H3
InChIKey: IIGNZLVHOZEOPV-UHFFFAOYSA-N
4. Safety Information of 3-Methoxybenzyl alcohol
Hazard Codes : Xn,Xi
Risk Statements: 36/37/38-22
R36/37/38: Irritating to eyes, respiratory system and skin.
R22:Harmful if swallowed.
Safety Statements: 23-24/25-37/39-26-36
S23: Do not breathe vapour.
S24/25: Avoid contact with skin and eyes.
S37/39: Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
WGK Germany: 3
HS Code: 29094990