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CAS No.: | 7727-15-3 |
---|---|
Name: | Aluminum bromide |
Article Data: | 70 |
Molecular Structure: | |
Formula: | AlBr3 |
Molecular Weight: | 266.694 |
Synonyms: | Aluminumbromide (8CI);Aluminum tribromide;Aluminum tribromide (AlBr3);NSC 87608;Aluminum bromide(AlBr3); |
EINECS: | 231-779-7 |
Density: | 3.205 g/mL at 25 °C(lit.) |
Melting Point: | 94-98 °C(lit.) |
Boiling Point: | 265 °C |
Flash Point: | 268°C subl. |
Solubility: | decomposes in water |
Appearance: | white crystalline powder |
Hazard Symbols: | C,Xi,N,F |
Risk Codes: | 23/24/25-34-22-14-67-65-50/53-11 |
Safety: | 9-16-26-29-36/37/39-43-45-60-61-62-28-27 |
Transport Information: | UN 3264 8/PG 2 |
PSA: | 0.00000 |
LogP: | 2.53680 |
phenylaluminium dichloride
allyl bromide
A
allylbenzene
B
biphenyl
C
aluminium bromide
Conditions | Yield |
---|---|
bis(η3-allyl-μ-chloropalladium(II)) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h); | A 94% B <1 C n/a |
tetrakis(triphenylphosphine) palladium(0) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h); | A <1 B <1 C n/a |
diphenylaluminum chloride
allyl bromide
A
allylbenzene
B
biphenyl
C
aluminium bromide
Conditions | Yield |
---|---|
tetrakis(triphenylphosphine) palladium(0) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h); | A 37% B <1 C n/a |
Conditions | Yield |
---|---|
Erhitzen des Reaktionsprodukts im Vakuum auf 200grad; |
aluminum oxide
aluminium bromide
Conditions | Yield |
---|---|
With bromine; pyrographite In not given heating; | |
With bromine; pyrographite heating; | |
With sulfur dibromide In solid 350°C, with vaporous sulfur bromide; |
Conditions | Yield |
---|---|
reaction started at 350°C and accelerated by raising of temp.; excess of S2Br2 removed with HBr or nitrogen; | |
reaction started at 350°C and accelerated by raising of temp.; excess of S2Br2 removed with HBr or nitrogen; |
Conditions | Yield |
---|---|
With aluminum(III) sulfate In water heating on water bath with small amt. of Br2 and H2O; | |
With bisilicates; carbon heating; | |
With carbon; silicates heating; |
Conditions | Yield |
---|---|
In not given heating on water bath with small amt. of Br2; | |
In not given heating on water bath with small amt. of Br2; |
Conditions | Yield |
---|---|
In gas Al and Br2 in vac. were vaporized separately and reacted in gaseous state; distd. in vac.; | |
With air; water in moist air containing Br2 condensation of droplets of a soln. of AlBr3 occurs on a gray layer that has formed first;; | |
In neat (no solvent) start of react. by heating;; |
Conditions | Yield |
---|---|
With bromine reacted in the presence of AlBr3; | |
With bromine Al heated in combustion tube; with H2 or N2 deluted Br2 lead over Al; | |
With bromine Al sheet heated in combustion tube; vaporous Br2 leaded over Al; AlBr3 flowed out from tube; |
IUPAC Name: Tribromoalumane
Molecular Formula: AlBr3
Formula Weight: 266.69g/mol
EINECS: 231-779-7
Melting Point: 94-98 °C(lit.)
Boiling Point: 265 °C
Density: 3.205 g/mL at 25 °C(lit.)
Vapor Pressure: 1 mm Hg ( 81.3 °C)
Flash Point: 268°C subl.
Chemical Properties: White crystalline powder
Water Solubility: Decomposes
Sensitive: Moisture sensitive
Stability: Stable, but reacts violently with water. Incompatible with aqueous solutions, alcohols, acids.
Synonyms of Aluminium bromide (7727-15-3): Aluminum bromide ; Aluminum bromide Hexahydrate ; Aluminium tribromide ; AlBr3 ; Aluminum bromide (AlBr3); Aluminum bromide , anhydrous ; Aluminumbromide (albr3)
Product Categories of Aluminium bromide (7727-15-3): Inorganics ; Aluminum salts ; Aluminummetal and ceramic science ; Aluminumsynthetic reagents ; Catalysis and inorganic chemistry ; Chemical synthesis ; Crystal grade inorganics ; Lewis acids ; Salts
Structure of Aluminium bromide (7727-15-3):
Safety Statements: 9-16-26-29-36/37/39-43-45
9: Keep container in a well-ventilated place
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
29: Do not empty into drains
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
WGK Germany: 3
Hazard Note: Irritant
Hazard Class: 8
Risk Statements: 23/24/25-34-22-14-67-65-50/53-11
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
34: Causes burns
22: Harmful if swallowed
14: Reacts violently with water
67: Vapors may cause drowsiness and dizziness
65: Harmful: May cause lung damage if swallowed
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
11: Highly Flammable
General Description: A white to yellowish-red lumpy solid with a pungent odor.