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Basic Information
CAS No.: 8032-32-4
Name: PETROLEUM ETHER
Molecular Structure:
Molecular Structure of 8032-32-4 (PETROLEUM ETHER)
Formula: C7H7BrMg
Molecular Weight: 195.33948
Synonyms: BP 2;BP 2(solvent);Benzine (light petroleum distillate);Benzoline;Canadol;Naphtha, ligroine;Painters' naphtha;Refined solvent naphtha;Skellysolve F;Skellysolve G;V.M. and P. naphtha;P. naphtha;Varnishmakers' and painters' naphtha;Varnish makers' naphtha;Varnish makers' naphtha and painters' naphtha;Petroleum ether 90-120℃;Ligroin;
EINECS: 232-453-7
Density: 0.64
Melting Point: -40oC
Boiling Point: 35-60oC
Flash Point: -30oC
Solubility: Insoluble in water.
Appearance: Clear liquid
Hazard Symbols: R11:Highly flammable.;
Risk Codes:  F:Highly flammable;
">  F:Highly flammable;
Safety: 62-45-53-61-16-60-23-36/37-24
PSA: 0.00000
LogP: 0.00000
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Chemistry

Product Name: Ligroin
Synonyms of Ligroin (CAS NO.8032-32-4): BP 2 ; BP 2 (solvent) ; Benzine ; Benzine (light petroleum distillate) ; Benzoline ; Canadol ; EINECS 232-453-7 ; HSDB 7177 ; Naphtha, ligroine ; Painters' naphtha ; Petroleum ether ; Refined solvent naphtha ; Skellysolve F ; Skellysolve G ; V.M. and P. naphtha ; VM and P Naphtha ; Varnish makers' and painters naphtha ; Varnish makers' naphtha ; Varnish makers' naphtha and painters' naphtha ; Varnish marker's naphtha ; Isoparaffinic hydrocarbons ; Mineral spirits ; Naphtha, varnish makers' and painters' ; VM & P naphtha
CAS NO: 8032-32-4 
Classification Code: Reproductive Effect ; Skin / Eye Irritant ; TSCA UVCB

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LCLo inhalation 153gm/m3/31M (153000mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Biochemische Zeitschrift. Vol. 115, Pg. 235, 1921.
mouse LD50 intravenous 40mg/kg (40mg/kg)   Pharmaceutical Chemistry Journal Vol. 7, Pg. 765, 1973.
rat LC50 inhalation 3400ppm/4H (3400ppm) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: MUSCLE WEAKNESS
Toxicology and Applied Pharmacology. Vol. 32, Pg. 263, 1975.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes of Ligroin (CAS NO.8032-32-4): HarmfulXn,ToxicT,FlammableF,DangerousN,HighlyF+
Risk Statements: 12-65-45-67-51/53-38-11-22-50-10-39-23/24/25 
R12: Extremely flammable. 
R65: Harmful: may cause lung damage if swallowed. 
R45: May cause cancer. 
R67: Vapours may cause drowsiness and dizziness. 
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R38: Irritating to skin. 
R11: Highly flammable. 
R22: Harmful if swallowed. 
R50: Very toxic to aquatic organisms. 
R10: Flammable. 
R39: Danger of very serious irreversible effects. 
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 62-45-53-61-16-60-23-36/37 
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S53: Avoid exposure - obtain special instructions before use. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
S16: Keep away from sources of ignition. 
S60: This material and its container must be disposed of as hazardous waste. 
S23: Do not breathe vapour. 
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 3295 3/PG 2
WGK Germany: 3
RTECS: OI6180000
HazardClass: 3
PackingGroup: I

Standards and Recommendations

OSHA PEL: TWA 300 ppm; STEL 400 PPM
ACGIH TLV: TWA 300 ppm; Animal Carcinogen
NIOSH REL: (VM & P Naphtha) TWA 350 mg/m3; CL 1800 mg/m3/15M
DOT Classification:  3; Label: Flammable Liquid

Analytical Methods

For occupational chemical analysis use NIOSH: Naphthas, 1550.