Detail of "875-72-9"

CAS Number:
875-72-9
Name:
Tricyclo[3.3.1.13,7]decane,2-methylene-
Superlist Name:
2-Methylideneadamantane
Molecular Structure:
Formula:
C₁₁H₁₆
Molecular Weight:
148.24
Synonyms:
Adamantane,2-methylene- (6CI,7CI,8CI);Tricyclo[3.3.1.13,7]decane, methylene- (9CI);2-Methyleneadamantane;Methyleneadamantane;
Density:
0.97 g/cm³
Boiling Point:
203.4 °C at 760 mmHg
Flash Point:
67.2 °C

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Dichloromethane Activation: Dichloromethane Activation. Direct Methylenation of Ketones and Aldehydes with CH2Cl2 Promoted by Mg/TiCl4/THF. Yan, Tu-Hsin; Tsai, Chia-Chung; Chien, Ching-Ting; Cho, Chia-Ching; Huang, Pei-Chen (Department of Chemistry, National Chung-Hsing University, Taichung 400, Taiwan). Organic Letters, 6(26), 4961-4963 (English) 2004 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 21 (General Organic Chemistry) This Mg-TiCl4-promoted CH2-transfer reaction of CH2Cl2 represents an extremely simple, practical, and efficient methylenation of a variety of ketones and aldehydes, esp. in enolizable or sterically hindered ketones such as 2,2-dimethylcyclohexanone, camphor, and fenchone.Except for chemicals metioned above, 875-72-9 and 2359-69-5 are also used. .