1314-23-4 Usage
Oral Biomaterials
Crystalline zirconium dioxide (zirconium oxide), ZrO2, called zirconia (not to be confused with zircon, which is a mineral, and Zirkon?, which is a product in the market) is manufactured for use as a white pigment from minerals by conversion to Zr(SO4)2, followed by hydrolysis. ZrO2 is used also as a refractory material (crucibles, furnace lining), and it is insoluble in water, only slightly soluble in HCl and HNO3, and, however, slowly soluble in HF upon heating with 66% H2SO4.
Zirconia is considered one of the best currently known biocompatible ceramic materials along with the metallic titanium.
Zirconium dioxide, or zirconia, ZrO2, is the word in presentday dentistry. We may say that zirconia is a material of choice in contemporary restorative dentistry for several reasons. Moreover, restorative dentistry is about adhesion promotion and about durable bonding of restorations. Zirconia has found wide applications in dental restorations, such as bridges, crowns, dental implant abutments, and full dental implant systems.
Zirconia caught attraction due its superior mechanical properties as superior flexure strength (which is 1200 MPa compared to 1000 MPa for steel), high fracture toughness, high hardness, excellent fatigue, and damage resistance. The material is resistant to chemical attacks and does not react easily with strong acids, alkalis, or other corrosive material. Regarding its physical properties, ZrO2 is a white and opaque material that does not dissolve or react with water and other solvents. It is an excellent thermal and chemical insulator and is used in fuel cells.
Uses
Different sources of media describe the Uses of 1314-23-4 differently. You can refer to the following data:
1. Zirconium dioxide (ZrO2) as an abrasive is used to make grinding wheels and special sandpaper. It is also used in ceramic glazes, in enamels, and for lining furnaces and hightemperature molds. It resists corrosion at high temperatures, making it ideal for crucibles and other types of laboratory ware. ZrO2 is used as a "getter" to remove the last trace of air when producing vacuum tubes.
2. Lanthanum-modified lead zirconate titanate (PLZT) fibers with a diameter of around 300 microns were produced by a thermoplastic processing method. The main use of zirconia is in the production of ceramics with other uses including as a protective coating on particles of titanium dioxide pigments, as a refractory material, in insulation, abrasives and enamels. Stabilized zirconia is used in oxygen sensors and fuel cell membranes because it has the ability to allow oxygen ions to move freely through the crystal structure at high temperatures. This high ionic conductivity (and a low electronic conductivity) makes it one of the most useful electroceramics.Zirconium dioxide is also used as the solid electrolyte in electrochromic devices. Zirconia is a precursor to the electroceramic lead zirconate titanate (PZT), which is a high-K dielectric, which is found in myriad components.
3. Zirconium oxide occurs in nature as the mineral baddeleyite. The oxide has many industrial applications. It is used as a refractory material. It is used in making highly reflective glazes for ceramics, glasses, linings of metallurgical furnaces, crucibles, and laboratory equipment. The oxide is used to produce oxyhydrogen and incandescent lights. Other uses are in producing piezoelectric crystals, heat-resistant fibers, and high-frequency induction coils. The hydrous oxide is used in treating dermatitis resulting from poison ivy.
4. Instead of lime for the oxyhydrogen light; with earths of the yttrium group in incandescent lighting (Nernst lamps); as pigment, abrasive; manufacture of enamels, white glass, refractory crucibles, and furnace linings.
5. Zirconium oxide (ZrO2) is the most common compound of zirconium found in nature. It
has many uses, including the production of heat-resistant fabrics and high-temperature electrodes
and tools, as well as in the treatment of skin diseases. The mineral baddeleyite (known
as zirconia or ZrO2) is the natural form of zirconium oxide and is used to produce metallic
zirconium by the use of the Kroll process. The Kroll process is used to produce titanium metal
as well as zirconium. The metals, in the form of metallic tetrachlorides, are reduced with magnesium
metal and then heated to “red-hot” under normal pressure in the presence of a blanket
of inert gas such as helium or argon.
Chemical Properties
Different sources of media describe the Chemical Properties of 1314-23-4 differently. You can refer to the following data:
1. Heavy, white, amorphous powder. Mohs hardness 6.5, refr index 2.2. Insoluble in water and most acids or alkalies at room temperature; soluble in nitric acid and hot concentrated hydrochloric, hydrofluoric, and sulfuric acids. Most heat resistant of commercial refractories; dielectric.
2. Zirconium dioxide is a white, amorphous powder, insoluble
in water but slightly soluble in acid.
Physical properties
White, heavy, amorphous powder or monoclinic crystals; refractive index 2.13; density 5.68 g/cm3; Mohs hardness 6.5; transforms to tetragonal structure above 1,100°C and cubic form above 1,900°C; melts at 2,710°C and vaporizes at about 4,300°C; insoluble in water; soluble in hydrofluoric acid and hot sulfuric, nitric and hydrochloric acids.
Preparation
Zirconium oxide occurs in nature as mineral baddeleyite. Ore is mined from natural deposits and subjected to concentration and purifcation by various processes. The oxide, however, is more commonly obtained as an intermediate in recovering zirconium from zircon, ZrSiO4 (See Zirconium, Recovery).
Also, the oxide may be prepared in the laboratory by thermal decomposition of zirconium hydroxide or zirconium carbonate:
Zr(OH)4 → ZrO2 + 2H2O
Zr(CO3)2 → ZrO2 + 2CO2
General Description
Zirconium(IV) oxide (ZrO2) which is also known as zirconia is a ceramic nanoparticle that can be used as a nano-filler. It can be incorporated in a variety of polymer and metal composites to improve the thermo-mechanical properties of the base material.
Flammability and Explosibility
Nonflammable
Industrial uses
There are several types of zirconia: a pure(monoclinic) oxide and a stabilized (cubic)form, and a number of variations such asyttria- and magnesia-stabilized zirconia andnuclear grades. Stabilized zirconia has a highmelting point, about 2760°C, low thermal conductivity,and is generally unaffected by oxidizingand reducing atmospheres and mostchemicals. Yttria- and magnesia-stabilized zirconiasare widely used for equipment and vesselsin contact with liquid metals. Monoclinicnuclear zirconia is used for nuclear fuel elements,reactor hardware, and related applicationswhere high purity (99.7%) is needed.Zirconia has the distinction of being an electricalinsulator at low temperatures, graduallybecoming a conductor as temperaturesincrease.
Carcinogenicity
To simulate the chronic alpha radiation of Thorotrast, the
liver of female Wistar rats was exposed to fractionated
neutron irradiation at 14-day intervals (0.2Gy per fraction)
over 2 years to a total dose of 10.0Gy. Before the start of
irradiation, half of the animals received 120 mL of nonradioactive
Zirconotrast (ZrO2), which is comparable to
Thorotrast in all other physical and chemical properties.
The first liver tumor was detected 1 year after the beginning
of irradiation. At the end of the life span study, the
incidence of irradiated animals with liver tumors was about
40%. In the animals treated additionally with ZrO2, the
incidence, time of onset, and overall number of liver
tumors were nearly equal, indicating that the fractionated
neutron irradiation was the exclusive cause of tumor
development. The lifelong-deposited ZrO2 colloid had
no influence on tumor induction or development. Histological
types of benign and malignant liver tumors seen in
this study were the same as those seen in animals treated
with Thorotrast.
Check Digit Verification of cas no
The CAS Registry Mumber 1314-23-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,3,1 and 4 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1314-23:
(6*1)+(5*3)+(4*1)+(3*4)+(2*2)+(1*3)=44
44 % 10 = 4
So 1314-23-4 is a valid CAS Registry Number.
InChI:InChI=1/2O.Zr/q2*-2;+4
1314-23-4Relevant articles and documents
MODIFIED ORGANOMETALLIC FRAMEWORK AND CATALYST FOR HYDROGENATION REACTION INCLUDING SAME
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, (2022/03/14)
The present disclosure relates to an organometallic framework modified using a compound having a hydroxyl group (—OH), a catalyst for a hydrogenation reaction including the same, and a method of manufacturing the same. The catalyst according to the present disclosure has high activity to the hydrogenation reaction even at a low temperature of 30 to 40° C., thus making low-grade waste heat usable.
Dental Posts
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Page/Page column, (2013/03/28)
The present invention pertains to the technical field of dental restorations, especially dental posts. One aspect of the present invention is a radio-opaque coated dental post. The post essentially consists of a core embedded in a thermoplastic or duroplastic material. The core is further coated with yet another resin with at least one radio-opaque additive. X-ray visibility especially at the outer margin of the post is significantly improved.
Ruthenium-based catalyst and use thereof in the selective hydrogenation of aromatic or polyunsaturated compounds
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, (2012/05/20)
Catalyst suitable for the hydrogenation of aromatic or polyunsaturated compounds comprising a zirconia carrier (ZrO2), containing ruthenium, as catalyst, and iron oxide (Fe2O3), as promoter, characterized in that at least one metal oxide, selected from those of the groups IB, IIB and IIIA, is present on the carrier as further promoter.
