2617-47-2Relevant articles and documents
Hydroperoxylation by hydroxyethylphosphonate dioxygenase
Whitteck, John T.,Cicchillo, Robert M.,Van Der Donk, Wilfred A.
, p. 16225 - 16232 (2009)
Hydroxyethylphosphonate dioxygenase (HEPD) catalyzes the O 2-dependent cleavage of the carbon-carbon bond of 2-hydroxyethylphosphonate (2-HEP) to afford hydroxymethylphosphonate (HMP) and formate without input of electrons or use of any organic
Organic-inorganic hybrid materials designed by controlled radical polymerization and mediated using commercial dual functional organophosphorous coupling agents
Cao, Edgar,Prouzet, Eric,Hroguez, Valrie
, p. 6081 - 6087 (2015/02/18)
Hybrid materials that are composed of a polymeric material interfaced with an inorganic, metal oxide material have been a rapidly expanding research area in the last few decades. However, interfacial regions remain an important area of focus, and as such hybrid materials do not always possess a very robust or stable interface. Tailor-made interfacial molecules have been successfully reported but material scientists wishing to develop composite interfacial materials would favorably use commercial solutions. Our study shows how we can leverage a commercially available organophosphonic acid group that is coupled with a 2-bromo isobutyrate initiator for surface initiated atom transfer radical polymerization (SI-ATRP) for use as a strong interfacial molecule. We illustrate this mechanism with both nanoparticles of titania and flat titania substrates used as the grafting support and polymerization anchoring points. We demonstrate that the size of the organophosphonic acid initiator, specifically the carbon spacer between the reactive groups, controls the stability of the molecule. The actual covalent linkage between the phosphonic acid group and the titania surface while also leaving the ATRP initiating group able to start the polymerization, is confirmed via31P solid state NMR spectroscopy, liquid 1H NMR spectroscopy XPS, DLS and SEM.
A study of the reaction of phosphorus trichloride with paraformaldehyde in the presence of carboxylic acids
Troev,Todorov,Naydenova,Mitova,Vassilev
, p. 1147 - 1155 (2013/09/23)
We investigated the mechanism of the reaction of paraformaldehyde with phosphorus trichloride in the presence of carboxylic acids (acetic, propanoic, and formic). Our results revealed that bisphosphonic acids were obtained without the use of water. The structures of the reaction products were studied by 1D and 2D homonuclear and heteronuclear 1H-, 13C-, 31P- NMR spectroscopy. [Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfer, and Silicon and the Related Elements for the following free supplemental files: Additional tables.]
METHOD FOR THE MANUFACTURE OF COMPOUNDS CONTAINING AN α-OXY PHOSPHORUS GROUP
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Page/Page column 45, (2012/08/07)
A method for the manufacture of compounds containing an α-oxy phosphorus group is disclosed. A P-O component having at least one P-O-P moiety, whereby at least one phosphorus has the +3 oxidation state, is added in specific proportions to a compound containing an α-oxy carboxylic acid group, followed by conducting the reaction and adding water subsequently. The compounds containing an α-oxy phosphorus group formed can then be recovered.