3396-72-3

Basic information

• Product Name: 3-deoxy-1,2-O-(1-methylethylidene)-α-D-erythro-pentofuranose 4-methylbenzenesufonate
• Synonyms: 3-deoxy-1,2-O-(1-methylethylidene)-α-D-erythro-pentofuranose 4-methylbenzenesufonate
• CAS NO: 3396-72-3
• Molecular Weight: 328.386
• Mol File: 3396-72-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-deoxy-1,2-O-(1-methylethylidene)-α-D-erythro-pentofuranose 4-methylbenzenesufonate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-deoxy-1,2-O-(1-methylethylidene)-α-D-erythro-pentofuranose 4-methylbenzenesufonate(3396-72-3)
• EPA Substance Registry System: 3-deoxy-1,2-O-(1-methylethylidene)-α-D-erythro-pentofuranose 4-methylbenzenesufonate(3396-72-3)

Safety Data

• Hazardous Substances Data: 3396-72-3(Hazardous Substances Data)

Upstream product

• 4005-46-3 3-deoxy-1,2-O-isopropylidene-D-glucose 
• 4613-68-7 O¹,O²-isopropylidene-α-D-erythro-3-deoxy-pentodiald-1,4-ose 
• 6022-96-4 5-O-benzoyl-α-D-xylofuranose 
• 20881-04-3 1,2:3,5-di-O-isopropylidene-D-xylofuranose 
• 532-20-7 D-xylofuranose 
• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 
• 98-59-9 p-toluenesulfonyl chloride 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 691389-04-5 Toluene-4-sulfonic acid (3aR,5R,6S,6aR)-2,2-dimethyl-6-methylsulfanylthiocarboxyoxy-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethyl ester 
• 3396-71-2 3-deoxy-1,2-O-isopropylidene-α-D-ribofuranose 

Downstream Products

• 127682-75-1 IsoddA 
• 127682-82-0 (2R-cis)-4-(6-chloro-9H-purin-9-yl)-tetrahydro-2-furanmethanol 
• 127682-78-4 (2R-trans)-tetrahydro-4-[[(4-methylphenyl)-sulfonyl]oxy]-2-furanmethanol 
• 127682-80-8 (2R-cis)-4-aminotetrahydro-2-furanmethanol 
• 86040-20-2 4-O-Benzoyl-2,3,5-tridesoxy-L-glycero-pentose-trimethylendithioacetal 
• 127682-77-3 (3S-trans)-tetrahydro-5-(dimethoxymethyl)-3-furanol 4-methylbenzenesulfonate 
• 127682-82-0 (2R-cis)-4-(6-chloro-9H-purin-9-yl)tetrahydrofuran-2-methanol 
• 127682-78-4 (2R-trans)-tetrahydro-4-<<(4-methylphenyl)sulfonyl>oxy>-2-furanmethanol 
• 127682-80-8 (2R-cis)-4-aminotetrahydro-2-furanmethanol 
• 127682-77-3 2(R)-<(dimethoxy)methyl>-4(S)-tetrahydrofuran 
• 127682-76-2 (3R,5S)-5-Dimethoxymethyl-tetrahydro-furan-3-ol 
• 127682-76-2 (2R,4S)-4-hydroxy-2-dimethoxymethyltetrahydrofuran 

Relevant articles and documents

Synthesis and structure analyses of 1,2,4-tri-O-acetyl-3,5-di-deoxy-5-C- (isopropyl- and phenyl-phosphinyl)-D-erythro-pentopyranoses

1H NMR spectroscopy for phosphorus containing hetero sugars (phospha sugars 9a-d and 17a-d) revealed the stereoisomeric configurations and the chair conformations for α - and β -1,2,4-tri-O-acetyl-3,5-di- deoxy-5-C-(isopropyl- and phenyl-phosphinyl)-D-erythro-pentopyranoses. The conformations of the title compounds were characterized as 4C 1 chair form in CDCl3 by 1H NMR (500 MHz), and the conformations were in accord with those in the solid state determined by X-ray crystallographic analyses.

THE SYNTHESIS OF (S) AND (R) ENANTIOMERS OF NOVEL HYDROXYMETHYLATED ISODIDEOXYNUCLEOSIDES

Novel isomeric dideoxynucleosides, with symmetry introduced at the 2'-position (4'-position using normal nucleoside numbernig) through the introduction of an additional hydroxymethyl group, have been synthesized.Both (R) and (S) enantiomeric series were investigated.The methodologies developed have generality and the presence of the hydroxymethyl group trans to the base may be used to introduce a wide variety of functionalities at this position.