38858-73-0

Basic information

• Product Name: Silane, trimethyl[(1-phenylcyclopropyl)oxy]-
• Synonyms: Silane,trimethyl[(1-phenylcyclopropyl)oxy];1-(trimethylsilyloxy)-1-phenylcyclopropane;1-phenyl-1-trimethylsiloxycyclopropane;1-Trimethylsilyloxy-1-phenylcyclopropan
• CAS NO: 38858-73-0
• Molecular Formula: C12H18OSi
• Molecular Weight: 206.36
• Mol File: 38858-73-0.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 90-95 °C(Press: 10 Torr)
• Density: 0.97±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Silane, trimethyl[(1-phenylcyclopropyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(1-phenylcyclopropyl)oxy]-(38858-73-0)
• EPA Substance Registry System: Silane, trimethyl[(1-phenylcyclopropyl)oxy]-(38858-73-0)

Safety Data

• Hazardous Substances Data: 38858-73-0(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 75-11-6 diiodomethane 
• 75-77-4 chloro-trimethyl-silane 
• 7257-94-5 1-phenyl-2-(p-tolylsulfonyloxy)ethanone 
• 31729-70-1 bis(iodozinc)methane 
• 98-86-2 acetophenone 
• 29636-75-7 3-bromo-1-phenylpropan-1-one 
• 29526-96-3 1-phenylcyclopropan-1-ol 

Downstream Products

• 7334-41-0 3-acetoxypropiophenone 
• 29526-96-3 1-phenylcyclopropan-1-ol 
• 3375-38-0 1,4-dibenzoylbutane 
• 62559-30-2 1-phenylpropyl trimethylsilyl ether 
• 13788-90-4 3,3-dimethoxy-1-phenylpropan-1-one 
• 93-55-0 1-phenyl-propan-1-one 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 71268-59-2 (E)-1-phenyl-1-(trimethylsiloxy)propene 
• 768-03-6 Phenyl vinyl ketone 
• 127931-48-0 1-(naphthalen-1-yl)-4-phenylbutane-1,4-dione 
• 94227-05-1 5-methyl-1-phenylhex-5-en-1-one 
• 5650-41-9 3-hydroxy-1-phenylpropan-1-one 
• 1435517-99-9 1-phenyl-5-(p-tolyl)pent-4-yn-1-one 
• 3558-69-8 2,6-diphenylpyridine 

Relevant articles and documents

Trialkylaluminum-Alkylidene Iodide. A Powerful Cyclopropanation Agent with Unique Selectivity

A highly convenient and versatile method for the synthesis of cyclopropanes has been described which involves treatment of olefins with a variety of trialkylaluminiums and alkylidene iodide under mild conditions.

Aryl Pyrazoles from Photocatalytic Cycloadditions of Arenediazonium

A photocatalytic synthesis of 1,5-diaryl pyrazoles from arenediazoniums and arylcyclopropanols is reported. The reaction proceeded under mild conditions (rt, 20 min) with catalytic [Ru(bpy)3]2+ under blue-light irradiation and exhibited compatibility with several functional groups (e.g., I, SF5, SO2NH2, N3, CN) and perfect levels of regiocontrol. Mechanistic studies (luminescence spectroscopy, CV, DFT, radical trapping, quantum yield determination) documented an initial oxidative quenching of the excited photocatalyst and the operation of a radical-chain mechanism.

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

The FeIII- or AgI-catalyzed oxidative fluorination of cyclopropanols via radical rearrangement is disclosed. This process features a straightforward and highly effective protocol for the site-specific synthesis of β-fluoroketones and represents an expedient method for the synthesis of γ-, δ- and ε-fluoroketones. Notably, this reaction proceeds at room temperature and tolerates a diverse array of cyclopropanols.