chlorobenzene basic information |
|
chlorobenzene chemical properties |
mp |
-45 °c |
bp |
132 °c(lit.) |
density |
1.1075 |
vapor density |
3.86 (vs air) |
vapor pressure |
11.8 mm hg ( 25 °c) |
refractive index |
n20/d 1.524(lit.) |
fp |
75 °f |
storage temp. |
0-6°c |
water solubility |
0.4 g/l (20 ºc) |
freezingpoint |
-45.6℃ |
merck |
14,2121 |
brn |
605632 |
stability: |
stable. incompatible with oxidizing agents. flammable. attacks some types of plastics, rubber and coatings. |
cas database reference |
108-90-7(cas database reference) |
nist chemistry reference |
benzene, chloro-(108-90-7) |
epa substance registry system |
benzene, chloro-(108-90-7) |
|
chlorobenzene usage and synthesis |
chemical properties |
colourless liquid |
usage |
chlorobenzene is a halogenated benzene used in chemical toxicity qsar research for agricultural pollution. |
general description |
a colorless to clear, yellowish liquid with a sweet almond-like odor. flash point 84°f. practically insoluble in water and somewhat denser than water (9.2 lb / gal). vapors heavier than air. used to make pesticides, dyes, and other chemicals. |
air & water reactions |
highly flammable. insoluble in water. |
reactivity profile |
chlorobenzene undergoes a sometimes explosive reaction with powdered sodium or phosphorus trichloride + sodium. may react violently with dimethyl sulfoxide. reacts vigorously with oxidizing agents. attacks some forms of plastic, rubber and coatings. forms a shock sensitive solvated salt with silver perchlorate. . |
health hazard |
irritating to skin, eyes and mucous membranes. repeated exposure of skin may cause dermatitis due to defatting action. chronic inhalation of vapors or mist may result in damage to lungs, liver, and kidneys. acute vapor exposures can cause symptoms ranging from coughing to transient anesthesia and central nervous system depression. |
|
chlorobenzene preparation products and raw materials |
preparation products |
4-chlorobenzenesulfonyl chloride-->2-tert-butylpyridine-4-carbonitrile-->2-chloroacetophenone-->atrazine-->phenyltrichlorosilane-->5-bromothiophene-2-carbaldehyde-->5-chloro-3-methylbenzo[b]thiophene-->6-bromo-3,4-dihydro-1h-quinolin-2-one-->3-chlorobenzo[b]thiophene-2-carboxamide-->fluoxastrobin-->5-chlorobenzothiophene-->5-dimethylamino-thiophene-2-carbaldehyde-->3,4'-dichlorodiphenyl ether-->methyl 3-chlorobenzo[b]thiophene-2-carboxylate-->naphthol as-d-->3-hydroxy-n-(3-nitrophenyl)-2-naphthalenecarboxamide-->2,2'-(1,3,4-oxadiazole-2,5-diyl)bis[1-aminoanthraquinone] -->2-bromo-4-nitroimidazole-->3-chloro-benzo[b]thiophene-2-carboxylic acid hydrazide-->2,5-thiophenedicarboxylic acid-->ethyl alpha-chlorophenylacetate-->baclofen-->4,4'-ddt-->3-hydroxy-2-naphthoyl-ortho-phenetidide-->3-hydroxy-n-naphthalen-1-ylnaphthalene-2-carboxamide-->3-chlorobenzo[b]thiophene-2-carboxylic acid-->2-chloro-1,3-dinitrobenzene-->3-chlorobenzo[b]thiophene-2-carbonyl chloride-->2-thenoylacetonitrile-->2-hydroxy-n-(4-methoxyphenyl)-11h-benzo[a]carbazole-3-carboxamide-->pigment yellow 155-->dimethyl 4-chloropyridine-2,6-dicarboxylate-->1-benzyl-2-methyl-1h-imidazole-->3-(4-chlorobenzoyl)propionic acid-->2-chloroanthraquinone-->2-amino-5,6-dimethylbenzothiazole-->naphthol as-lt-->3-hydroxy-4'-methoxy-2-naphthanilide-->4,4'-dichlorodiphenyl sulfone-->diclomezine |
raw materials |
hydrochloric acid-->benzene-->chlorine-->aluminum oxide -->1,2-dichlorobenzene-->flow cell-->p-dichlorobenzene-->anhydrous ferric chloride |
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