Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
trans-Methyl crotonate |
EINECS | 210-793-7 |
CAS No. | 623-43-8 | Density | 0.925 g/cm3 |
PSA | 26.30000 | LogP | 0.73550 |
Solubility | Immiscible with water | Melting Point |
-42°C |
Formula | C5H8O2 | Boiling Point | 121 °C at 760 mmHg |
Molecular Weight | 100.117 | Flash Point | 4.4 °C |
Transport Information | UN 3272 3/PG 2 | Appearance | colorless Liquid |
Safety | 16-26-36-9-33 | Risk Codes | 11-36/37/38 |
Molecular Structure | Hazard Symbols | F,Xi | |
Synonyms |
2-Butenoicacid, methyl ester, (E)-;Crotonic acid, methyl ester, (E)- (8CI);(2E)-2-Butenoic acid methyl ester;(E)-2-Butenoic acid methyl ester;(E)-Crotonic acid methyl ester;Methyl (E)-2-butenoate;Methyl E-crotonate;Methyl E-propene-1-carboxylate;Methyl trans-2-butenoate;Methyltrans-crotonate;trans-2-Butenoic acid methyl ester; |
Article Data | 119 |
Conditions | Yield |
---|---|
With sulfuric acid for 0.25h; Esterification; Irradiation; | 94% |
With sulfuric acid for 12h; Heating; | 82% |
With thionyl chloride |
methanol
2-(diethylamino)ethyl crotonate
A
crotonic acid methyl ester
B
2-(Diethylamino)ethanol
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid for 4h; Heating; | A 90% B 82% |
2-(diethylamino)ethyl crotonate
A
crotonic acid methyl ester
B
2-(Diethylamino)ethanol
Conditions | Yield |
---|---|
With methanol; toluene-4-sulfonic acid for 4h; Heating; | A 90% B 82% |
2-ethylthio methyl ester
crotonic acid methyl ester
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; ammonium chloride In ethanol electrolysis; | 90% |
Conditions | Yield |
---|---|
With perchloric acid; sodium percarbonate; vanadia for 1h; Heating; | 90% |
With tert.-butylhydroperoxide In decane at 25℃; for 8h; Inert atmosphere; | 72% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran at 20℃; for 0.583333h; | 90% |
Conditions | Yield |
---|---|
Ni(CO)4 In methanol; aqueous KCl | 90% |
sodium methylate
2-Chloro-2-(1-chloroethyl)oxirane
A
Methyl β-methoxybutyrate
B
crotonic acid methyl ester
C
ethylglyoxal dimethylacetal
Conditions | Yield |
---|---|
In methanol | A 11% B 3% C 86% |
In methanol | A 11 % Chromat. B 3 % Chromat. C 86 % Chromat. |
In methanol Product distribution; -50 deg C, then 3h, roomtemp.; | A 11 % Chromat. B 3 % Chromat. C 86 % Chromat. |
erythro 2,3-dibromo-butenoate
crotonic acid methyl ester
Conditions | Yield |
---|---|
With indium(III) chloride; sodium tetrahydroborate In acetonitrile at -10℃; for 3h; | 78% |
methyl-4-bromo-2-butenoate
A
crotonic acid methyl ester
B
methyl but-3-enoate
C
5-Vinyl-trans-hexen-2-disaeuredimethylester
Conditions | Yield |
---|---|
With zinc In dimethyl sulfoxide for 4h; Yields of byproduct given; | A n/a B n/a C 75% |
1. | skn-rbt 500 mg/24H MOD | FCTXAV Food and Cosmetics Toxicology. 17 (1979),865. | ||
2. | orl-mus LD50:1600 mg/kg | FCTXAV Food and Cosmetics Toxicology. 17 (1979),865. | ||
3. | skn-gpg LD50:10 g/kg | FCTXAV Food and Cosmetics Toxicology. 17 (1979),865. |