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Name |
(-)-beta-Citronellol |
EINECS | 231-415-7 |
CAS No. | 7540-51-4 | Density | 0.845 g/cm3 |
PSA | 20.23000 | LogP | 2.75130 |
Solubility | SLIGHTLY SOLUBLE | Melting Point |
77-83oC(lit.) |
Formula | C10H20O | Boiling Point | 224.5 °C at 760 mmHg |
Molecular Weight | 156.268 | Flash Point | 98.3 °C |
Transport Information | N/A | Appearance | Clear colorless liquid |
Safety | 26-36 | Risk Codes | 36/37/38 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
6-Octen-1-ol,3,7-dimethyl-, (-)- (8CI);6-Octen-1-ol, 3,7-dimethyl-, (S)-;(-)-(S)-Citronellol;(-)-Citronellol;(-)-b-Citronellol;(S)-(-)-Citronellol;(S)-(-)-b-Citronellol;(S)-3,7-Dimethyl-6-octen-1-ol;(S)-Citronellol;(S)-b-Citronellol;L-Citronellol; |
Article Data | 61 |
Conditions | Yield |
---|---|
With bis(norbornadiene)rhodium(l)tetrafluoroborate; (RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene; hydrogen In dichloromethane at 20℃; under 19001.3 Torr; for 20h; Inert atmosphere; Autoclave; enantioselective reaction; | 99% |
With [RuCl(p-cymene)((R)-Tol-BINAP)]Cl; potassium hydroxide In isopropyl alcohol for 2h; Inert atmosphere; Reflux; | 70% |
Multi-step reaction with 2 steps 1: in Ficus retusa Linn. 2: in Ficus retusa Linn. nach Injektion View Scheme |
Conditions | Yield |
---|---|
With dichloro(1,5-cyclooctadiene)ruthenium(II); (R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine; niobium pentachloride; HSiPh3 In toluene at 40℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction; | 98.59% |
With (η4-cyclooctadiene)((R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)rhodium(I) tetrfluoroborate; hydrogen In methanol at 60℃; under 33753.4 Torr; for 5h; Autoclave; enantioselective reaction; | 88% |
(S)-3,7-dimethyl-6-octen-1-ol
Conditions | Yield |
---|---|
With indium; water; ammonium chloride In methanol for 1h; Heating; | 98% |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In diethyl ether | 96% |
With lithium aluminium tetrahydride In diethyl ether | 94% |
With sodium tetrahydroborate In ethanol at 0℃; | 93% |
(S)-3,7-dimethyl-6-octen-1-ol
Conditions | Yield |
---|---|
With indium; water; ammonium chloride In methanol for 0.5h; Heating; | 95% |
(S)-3,7-dimethyl-6-octen-1-ol
Conditions | Yield |
---|---|
With sodium perborate; water In tetrahydrofuran at 20℃; for 4h; enantioselective reaction; | 95% |
2,2-dimethyl-propionic acid (3S)-3,7-dimethyl-oct-6-enyl ester
(S)-3,7-dimethyl-6-octen-1-ol
Conditions | Yield |
---|---|
With sodium hydroxide In methanol Ambient temperature; | 94% |
(S)-3,7-dimethyl-6-octen-1-ol
Conditions | Yield |
---|---|
Stage #1: (S)-8-(allyloxy)-2,6-dimethyloct-2-ene With C12H37NiP4(1+)*C2F6NO4S2(1-) In tetrahydrofuran at 20℃; for 0.5h; Glovebox; Schlenk technique; Inert atmosphere; Stage #2: With toluene-4-sulfonic acid In tetrahydrofuran for 1.5h; Glovebox; Schlenk technique; Reflux; Inert atmosphere; | 94% |
(S)-3,7-Dimethyl-oct-6-enoic acid (1S,2R,3S,4R)-3-(2,2-dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester
A
(S)-3,7-dimethyl-6-octen-1-ol
B
(1R,2S,3R,4S)-2-(2,2-dimethylpropoxy)-1,7,7-trimethylbicyclo<2.2.1>heptan-3-ol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride | A 88% B 81% |
(S)-((3,7-dimethyloct-6-enyloxy)methyl)benzene
(S)-3,7-dimethyl-6-octen-1-ol
Conditions | Yield |
---|---|
With ammonia; lithium In tetrahydrofuran at -30℃; for 0.666667h; | 82% |
Molecular structure of 6-Octen-1-ol, 3,7-dimethyl-, (3S)- (CAS NO.7540-51-4) is:
Product Name: 6-Octen-1-ol, 3,7-dimethyl-, (3S)-
CAS Registry Number: 7540-51-4
IUPAC Name: 3,7-dimethyloct-6-en-1-ol
Molecular Weight: 156.2652 [g/mol]
Molecular Formula: C10H20O
XLogP3-AA: 3.2
H-Bond Donor: 1
H-Bond Acceptor: 1
EINECS: 231-415-7
Surface Tension: 28.5 dyne/cm
Density: 0.845 g/cm3
Flash Point: 98.3 °C
Enthalpy of Vaporization: 53.6 kJ/mol
Boiling Point: 224.5 °C at 760 mmHg
Vapour Pressure: 0.0183 mmHg at 25°C
Vapor pressure: ~0.02 mm Hg ( 25 °C)
Refractive index: n20/D 1.456
Storage temp.: 2-8°C
Product Categories: All Aliphatics ;Acyclic Monoterpenes ;Biochemistry ;Terpenes ;Aliphatics ;Chiral Reagents
Safty information about 6-Octen-1-ol, 3,7-dimethyl-, (3S)- (CAS NO.7540-51-4) is:
Hazard Codes: Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany: 2
F: 8-10
6-Octen-1-ol, 3,7-dimethyl-, (3S)- , its cas register number is 7540-51-4. It also can be called AI3-09552 ; EINECS 231-415-7 ; FEMA No. 2309 ; beta-Citronellol ; l-Citronellol ; (-)-3,7-Dimethyloct-6-en-1-ol ; 6-Octen-1-ol, 3,7-dimethyl-, (S)- .It is a clear colorless liquid.