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(3,3,3-Trifluoropropyl)dichloromethylsilane

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Name

(3,3,3-Trifluoropropyl)dichloromethylsilane

EINECS 211-623-4
CAS No. 675-62-7 Density 1.245 g/cm3
PSA 0.00000 LogP 3.48840
Solubility N/A Melting Point N/A
Formula C4H7Cl2F3Si Boiling Point 113.8 °C at 760 mmHg
Molecular Weight 211.086 Flash Point 22.6 °C
Transport Information N/A Appearance Colorless clear liquid
Safety 16-26-28-36/37/39-45 Risk Codes 11-34-37
Molecular Structure Molecular Structure of 675-62-7 ((3,3,3-Trifluoropropyl)dichloromethylsilane) Hazard Symbols CorrosiveC
Synonyms

(3,3,3-Trifluoropropyl)methyldichlorosilane;Dichloromethyl(3,3,3-trifluoropropyl)silane;Methyl-3,3,3-trifluoropropyldichlorosilane;

Article Data 10

(3,3,3-Trifluoropropyl)dichloromethylsilane Synthetic route

75-54-7

Dichloromethylsilane

677-21-4

1,1,1-trifluoropropylene

675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

Conditions
ConditionsYield
RhCl(PPh3)3 at 120℃; for 12h;85%
Irradiation.unter Einwirkung von UV-Licht;
With platinum at 250℃;
75-54-7

Dichloromethylsilane

677-21-4

1,1,1-trifluoropropylene

A

675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

B

Dichloro-methyl-((E)-3,3,3-trifluoro-propenyl)-silane

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium at 120℃; for 70h; Yield given. Yields of byproduct given;
819-59-0

Chlor-methyl-<3,3,3-trifluor-propyl>-silan

A

675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

B

690-96-0

methyl(3,3,3-trifluoropropyl)silane

Conditions
ConditionsYield
With tetrabutylammomium bromide at 105℃; for 24h; Equilibrium constant; Further Variations:; Temperatures; Disproportionation;
75-54-7

Dichloromethylsilane

754-12-1

2,3,3,3-tetrafluoro-propene

A

675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

B

dichloro(methyl)(2,3,3,3-tetrafluoropropyl)silane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate(IV) hexahydrate In neat (no solvent) at 100℃; for 20h;A 19 %Spectr.
B 56 %Spectr.
With dihydrogen hexachloroplatinate(IV) hexahydrate In neat (no solvent) at 80℃; for 48h; Temperature;A 59 %Spectr.
B 15 %Spectr.
75-54-7

Dichloromethylsilane

754-12-1

2,3,3,3-tetrafluoro-propene

675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

Conditions
ConditionsYield
With Wilkinson's catalyst In neat (no solvent) at 100℃; for 20h;48 %Spectr.
675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

107-05-1

3-chloroprop-1-ene

trifluoropropyl allyl methyl chlorosilane

Conditions
ConditionsYield
With iodine; magnesium In tetrahydrofuran at 30 - 40℃; for 4h;89%
3277-26-7

1,1,3,3-Tetramethyldisiloxane

675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

28364-07-0

C8H21F3O2Si3

Conditions
ConditionsYield
With hydrogenchloride at 10 - 20℃;85%
675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

947-42-2

diphenylsilanediol

67853-21-8

1,5-dichloro-1,5-dimethyl-1,5-bis(3,3,3-trifluoropropyl)-3,3-diphenyltrisiloxane

Conditions
ConditionsYield
With triethylamine In ethyl acetate at 0 - 10℃; for 2h; Temperature; Inert atmosphere;82.6%
675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

690-96-0

methyl(3,3,3-trifluoropropyl)silane

Conditions
ConditionsYield
With lithium aluminium tetrahydride In dibutyl ether at 40℃; for 2h; Reduction;82%
675-62-7

methyl(3,3,3-trifluoropropyl)dichlorosilane

106-95-6

allyl bromide

trifluoropropyl allyl methyl chlorosilane

Conditions
ConditionsYield
With iodine; magnesium In tetrahydrofuran at 30 - 40℃; for 4h;81%

(3,3,3-Trifluoropropyl)dichloromethylsilane Chemical Properties

IUPAC Name: Dichloro-methyl-(3,3,3-trifluoropropyl)silane 
Molecular Formula: C4H7Cl2F3Si
Molecular Weight: 211.10g/mol
EINECS: 211-623-4
Liansport Information: 2985
Appearance: clear, colorless Liquid
Density: 1.245 g/cm3
Boiling Point: 113.8 °C at 760 mmHg 
Flash Point: 22.6 °C 
Freely Rotating Bonds: 2 
Polar Surface Area: 0 Å2 
Index of Refraction: 1.382 
Molar Refractivity: 39.45 cm3 
Molar Volume: 169.4 cm3 
Polarizability: 15.64× 10-24 cm3 
Surface Tension: 18.3 dyne/cm 
Enthalpy of Vaporization: 33.77 kJ/mol 
Vapour Pressure: 24.2 mmHg at 25°C 
The chemical synonyms of Dichloromethyl-3,3,3-trifluoro-propylsilane (675-62-70) are Dichloromethyl(3,3,3-trifluoropropyl)-silan ; Dichloro-methyl-(3,3,3-trifluoro-propyl)-silane ; Dichloromethyl(3,3,3-trifluoropropyl)-Silane ; Dichloro-methyl-3,3,3-trifluoro-propyl-silane ; Dichloromethyl-3,3,3-trifluoropropylsilane ; (3,3,3-Trifluoropropyl)dichloromethylsilane ; (3,3,3-Trifluoropropyl)methyldichlorosilane ; Dichloromethyl(3,3,3-trifluoropropyl)silane ; (3,3,3)-Trifluoropropyl dichloromethylsilane .Product categories of  Dichloromethyl-3,3,3-trifluoro-propylsilane (675-62-70) are Fluoro ; Fluoro Silanes .The molecular structure of Dichloromethyl-3,3,3-trifluoro-propylsilane (675-62-70) is .

(3,3,3-Trifluoropropyl)dichloromethylsilane Toxicity Data With Reference

1.    

ihl-mus LC50:300 mg/m3/2H

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1223.

(3,3,3-Trifluoropropyl)dichloromethylsilane Consensus Reports

Reported in EPA TSCA Inventory.

(3,3,3-Trifluoropropyl)dichloromethylsilane Safety Profile

Poison by inhalation. When heated to decomposition it emits toxic vapors of F and Cl.
Hazard Codes:  C
C:  Corrosive 
Risk Statements:  11-34-37
11:  Highly Flammable
34:  Causes burns 
37:  Irritating to the respiratory system  
Safety Statements:  16-26-28-36/37/39-45
16:  Keep away from sources of ignition - No smoking 
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 
HazardClass:  3

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