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1-Naphthalenesulfonic acid

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Name

1-Naphthalenesulfonic acid

EINECS 201-610-1
CAS No. 85-47-2 Density 1.423 g/cm3
PSA 62.75000 LogP 3.16730
Solubility freely soluble in water Melting Point 77-79 °C(lit.)
Formula C10H8 O3 S Boiling Point 392oC
Molecular Weight 208.238 Flash Point 380.2oC
Transport Information UN 2583 Appearance grey fine crystalline powder
Safety 26-36/37/39-45-28A Risk Codes R34   
Molecular Structure Molecular Structure of 85-47-2 (1-Naphthalenesulfonic acid) Hazard Symbols
Synonyms

1-Sulfonaphthalene;HT 907; a-Naphthalenesulfonic acid

Article Data 77

1-Naphthalenesulfonic acid Synthetic route

91-20-3

naphthalene

85-47-2

1-naphthalenesulfonic acid

Conditions
ConditionsYield
With sulfur trioxide at 60℃; Temperature; Solvent;95.7%
With dipyridinium dichromate; sodium hydrogensulfite In neat (no solvent) at 100℃; under 1500.15 Torr; for 0.0916667h; Reagent/catalyst; Microwave irradiation;75%
With sulfuric acid; silica gel In 1,2-dichloro-ethane at 80℃; for 0.5h;60%
91-20-3

naphthalene

A

120-18-3

naphthalene-2-sulfonate

B

85-47-2

1-naphthalenesulfonic acid

Conditions
ConditionsYield
With sulfuric acid at 160 - 170℃; for 1.5h;A 88.3%
B 8.51%
With sulfuric acid at 120℃; Product distribution; Rate constant; Thermodynamic data; activation energy; microwave or irradiation; regioselectivity;
With sulfuric acid at 120℃; for 0.5h; Product distribution; microwave activation; various power, temperature, reaction time, H2SO4 concentration;
85-46-1

1-Naphthalenesulfonyl chloride

85-47-2

1-naphthalenesulfonic acid

Conditions
ConditionsYield
Stage #1: 1-Naphthalenesulfonyl chloride With N-ethyl-N,N-diisopropylamine; Wang resin In dichloromethane at 22℃;
Stage #2: With trifluoroacetic acid In dichloromethane for 1h; Further stages.;
85%
With sodium hydrogencarbonate In water at 80 - 90℃;0.25 g
With water In acetone at 30℃; Kinetics; Mechanism; Thermodynamic data; other temperatures; ΔH(excit.), ΔS(excit.); various concentrations of the reagent and substrate;
Multi-step reaction with 2 steps
1: alcohol; zinc
2: water
View Scheme
90-14-2

1-Iodonaphthalene

85-47-2

1-naphthalenesulfonic acid

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate; Aminoiminomethanesulfinic acid In dimethyl sulfoxide at 100℃; for 14h; Green chemistry;71%
15980-15-1

1,4-Oxathiane

91-20-3

naphthalene

85-47-2

1-naphthalenesulfonic acid

Conditions
ConditionsYield
With chlorosulphuric acid; benzene
91-20-3

naphthalene

A

85-47-2

1-naphthalenesulfonic acid

B

85-46-1

1-Naphthalenesulfonyl chloride

Conditions
ConditionsYield
With tetrachloromethane; chlorosulfonic acid at -5℃;
607-33-0

naphthalene-1-sulphinic acid

A

85-47-2

1-naphthalenesulfonic acid

B

49833-22-9

S-(naphthalen-1-yl) naphthalene-1-sulfonothioate

Conditions
ConditionsYield
With water
876483-30-6

naphthalene-1-sulfonic acid menthyl ester

A

85-47-2

1-naphthalenesulfonic acid

B

500-00-5

3-p-menthene

Conditions
ConditionsYield
under 4 Torr; bei der Destillation.Thermolysis; naphthalene-1-sulfonic acid l-menthyl ester;
91-20-3

naphthalene

A

120-18-3

naphthalene-2-sulfonate

B

85-47-2

1-naphthalenesulfonic acid

C

5724-16-3

naphthalene-1,7-disulphonic acid

D

525-37-1

naphthalene-1,6-disulfonic acid

E

81-04-9

naphthalene-1,5-disulfonate

Conditions
ConditionsYield
With sulfur trioxide; water Product distribution; multistep reaction; various reaction conditions;
91-20-3

naphthalene

A

120-18-3

naphthalene-2-sulfonate

B

85-47-2

1-naphthalenesulfonic acid

C

525-37-1

naphthalene-1,6-disulfonic acid

D

81-04-9

naphthalene-1,5-disulfonate

Conditions
ConditionsYield
With sulfur trioxide; water 1.) CH2Cl2, 22 deg C, 60 min, 2.) 70 - 80 deg C, 30 min; Multistep reaction. Further byproducts given. Title compound not separated from byproducts;

1-Naphthalenesulfonic acid Toxicity Data With Reference

Product Name: 1-Naphthalenesulfonic acid (CAS NO.85-47-2)


Molecular Formula: C10H8O3S
Molecular Weight: 208.23g/mol
Mol File: 85-47-2.mol
Einecs: 201-610-1
Melting Point: 77-79 °C(lit.)
Density: 1.423 g/cm3
Water Solubility: freely soluble
Product Categories: Intermediates of Dyes and Pigments ; Organic Building Blocks ; Sulfonic/Sulfinic Acids ; Sulfur Compounds
Synonyms of  1-Naphthalenesulfonic acid (CAS NO.85-47-2): 1-Naphthyl sulfonic acid ; Sulfonated naphthalene ; Naphthalene-1-sulfonic acid ; Alpha napthalene sulphonate ; Alpha-naphthalenesulfonic acid ; 1-Naphthalenesulfonic acid ; 1-Naphthalenesulfonic acid, dihydrate ; Naphthalene-1-sulfonic acid dihydrate .

1-Naphthalenesulfonic acid Safety Profile

Safety Information of 1-Naphthalenesulfonic acid (CAS NO.85-47-2):
Hazard Codes: C,F
Risk Statements: 34-11 
11:  Highly Flammable 
34:  Causes burns 
Safety Statements: 26-36/37/39-45-28-16
16:  Keep away from sources of ignition - No smoking
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)  
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
39:  Wear eye/face protection 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

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