Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
tris(2,2'-bipyridine)nickel(II) tetrafluoroborate In N,N-dimethyl-formamide Ambient temperature; electrolysis; | A 55% B 97% |
1,2-dibromooctane
n-octyne
Conditions | Yield |
---|---|
With potassium hydroxide; tetraoctyl ammonium bromide In Petroleum ether at 90℃; for 6h; | 95% |
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 60℃; for 2h; without <18>krone-6; | 92% |
With tetrabutylammomium bromide; potassium hydroxide In water at 150℃; for 10h; | 90% |
(Z)-1-bromo-1-octene
n-octyne
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 25℃; for 2h; | 92% |
2-bromo-1-octene
n-octyne
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 60℃; for 1h; | 90% |
With 1,2,4-Trimethylbenzene; sodium amide at 150℃; | |
With ammonia; sodium amide |
(E)-1-bromo-1-octene
n-octyne
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 60℃; for 2h; | 90% |
1,2-dichlorooctane
n-octyne
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 80℃; for 8h; | 84% |
Conditions | Yield |
---|---|
With potassium carbonate In ethanol at 80℃; for 8h; Sonogashira Cross-Coupling; | 80% |
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In Petroleum ether at 80℃; for 12h; Title compound not separated from byproducts; | A 15% B 62% C 7% |
Conditions | Yield |
---|---|
In chloroform-d1 at 40℃; for 6h; Irradiation; other ditelluroalkenes; | A 60% B n/a |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium peroxide; magnesium 1.) 22 deg C, 30 min, diethyl ether; Yield given. Multistep reaction; | A 28% B n/a |
With hydrogenchloride; sodium peroxide; magnesium 1.) 22 deg C, 30 min, diethyl ether; Yield given. Multistep reaction; |
Empirical Formula: C8H14
Molecular Weight: 110.1968 g/mol
EINECS: 211-069-3
Index of Refraction: 1.425
Density: 0.763 g/cm3
Flash Point: 17.8 °C
Enthalpy of Vaporization: 35.83 kJ/mol
Boiling Point: 126 °C at 760 mmHg
Vapour Pressure: 14.4 mmHg at 25°C
Melting point: -80 °C
Storage tempreture: Flammables area
Appearance: Clear colourless to yellow liquid
Structure of 1-Octyne (CAS NO.629-05-0):
IUPAC Name: Oct-1-yne
Product Categories of 1-Octyne (CAS NO.629-05-0): Miscellaneous;Alkynes;Acetylenic Hydrocarbons;Organic Building Blocks;Terminal
1. | dns-ham:lvr 100 µmol/L | CRNGDP Carcinogenesis. 6 (1985),1201. |
Reported in EPA TSCA Inventory.
Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes of 1-Octyne (CAS NO.629-05-0): F,Xn,Xi
Risk Statements: 11-65-36/37/38
R11:Highly flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
R65:Harmful: may cause lung damage if swallowed.
Safety Statements: 16-62-33-26
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33:Take precautionary measures against static discharges.
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
1-Octyne ,its cas register number is 629-05-0. It also can be called Oct-1-in .