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| CAS No.: | 112-70-9 |
|---|---|
| Name: | 1-Tridecanol |
| Molecular Structure: | |
|
|
|
| Formula: | C13H28 O |
| Molecular Weight: | 200.365 |
| Synonyms: | NSC 5252;Tridecyl alcohol; n-Tridecan-1-ol; n-Tridecanol; n-Tridecyl alcohol |
| EINECS: | 203-998-8 |
| Density: | 0.822 g/mL at 25 °C(lit.) |
| Melting Point: | 29-34 °C(lit.) |
| Boiling Point: | 272.1 °C at 760 mmHg |
| Flash Point: | 121.1 °C |
| Solubility: | chloroform: 0.1 g/mL, clear,insoluble in water |
| Appearance: | white solid. |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | Mildly toxic by ingestion and skin contact. A skin irritant. Combustible when exposed to heat or flame. To fight fire, use mist, spray, dry chemical, foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S.. |
| PSA: | 20.23000 |
| LogP: | 4.28970 |
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| Conditions | Yield |
|---|---|
| With hydrogen; Rh/Al2O3; molybdenum hexacarbonyl In 1,2-dimethoxyethane at 150℃; under 76000 Torr; for 16h; | 97% |
- 112-70-9
tridecan-1-ol
| Conditions | Yield |
|---|---|
| With lithium borohydride; sodium hydroxide In isopropyl alcohol Temperature; Jocic Reaction; Heating; Inert atmosphere; | 95% |
| Conditions | Yield |
|---|---|
| Stage #1: methyl tridecanoate With bis(acetylacetonato)dioxidomolybdenum(VI); 1,1,3,3-Tetramethyldisiloxane; Triphenylphosphine oxide In toluene at 100℃; for 20h; Inert atmosphere; Sealed tube; Stage #2: With tetrabutyl ammonium fluoride In tetrahydrofuran; toluene for 2h; Inert atmosphere; | 94% |
- 1436673-44-7
C18H36O2
- 112-70-9
tridecan-1-ol
| Conditions | Yield |
|---|---|
| With methanol; toluene-4-sulfonic acid at 20℃; for 2h; | 90% |
- 32466-55-0
(E)-tridec-2-enoic acid
- 112-70-9
tridecan-1-ol
| Conditions | Yield |
|---|---|
| With hydrogen; Rh/Al2O3; molybdenum hexacarbonyl In 1,2-dimethoxyethane at 150℃; under 76000 Torr; for 16h; | 89% |
- 110023-67-1
1-Methyl-4-(1-methylsulfanyl-tridecane-1-sulfinyl)-benzene
- 112-70-9
tridecan-1-ol
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate In 1,4-dioxane; water Irradiation; | 80% |
- 28267-29-0
ethyl tridecanoate
- 112-70-9
tridecan-1-ol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In diethyl ether at 0 - 20℃; | 79% |
| With ethanol; sodium |
- 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene
A
- 629-76-5
pentadecanol
B
- 112-70-9
tridecan-1-ol
C
- 36653-82-4
1-Hexadecanol
D
- 62643-46-3
20-hydroxyeicosanoic acid
| Conditions | Yield |
|---|---|
| With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given; | A 2.8% B 3.5% C 12.6% D 65% |
- 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene
A
- 112-70-9
tridecan-1-ol
B
- 112-72-1
1-Tetradecanol
C
- 36653-82-4
1-Hexadecanol
D
- 62643-46-3
20-hydroxyeicosanoic acid
| Conditions | Yield |
|---|---|
| With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given; | A 3.5% B 6% C 12.6% D 65% |
- 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene
A
- 112-70-9
tridecan-1-ol
B
- 112-72-1
1-Tetradecanol
C
- 117197-09-8
tridecyl hexanoate
D
- 62643-46-3
20-hydroxyeicosanoic acid
| Conditions | Yield |
|---|---|
| With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given; | A 3.5% B 6% C 0.5% D 65% |
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Chemistry
IUPAC Name: Tridecan-1-ol
Synonyms : N-Tridecanol ; N-Tridecyl alcohol ; Rarechem al bd 0158 ; Tridecanol ; Tridecyl alcohol ; 1-Hydroxytridecane ; C13 linear primary alcohol ; N-Tridecan-1-ol
Product Categories: 1-Alkanols;Biochemistry;Higher Fatty Acids & Higher Alcohols;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes;Saturated Higher Alcohols
CAS NO: 112-70-9
Molecular Formula: C13H28O
Molecular Weight: 200.36
Molecular Structure: 
EINECS: 203-998-8
BRN : 1739991
Mol File: 112-70-9.mol
Index of Refraction: 1.443
Surface Tension: 30.6 dyne/cm
Density: 0.832 g/cm3
Flash Point: 121.1 °C
Enthalpy of Vaporization: 59.25 kJ/mol
Boiling Point: 272.1 °C at 760 mmHg
Vapour Pressure: 0.000807 mmHg at 25°C
Melting point: 29-34 °C(lit.)
Appearance: 1-Tridecanol (CAS NO.112-70-9) is white low melting solid.
Solubility: 1-Tridecanol (CAS NO.112-70-9) is soluble in alcohol and ether, insoluble in water.
Uses
1-Tridecanol (CAS NO.112-70-9) is used raw materials in production of lubricants, surfactants, pesticides, and ink solvents.
Toxicity Data With Reference
| 1. | skn-rbt 410 mg open MLD | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 10/14 ,1964. | ||
| 2. | orl-rat LD50:17,200 mg/kg | NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),114. | ||
| 3. | skn-rbt LD50:5600 mg/kg | NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),114. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes 
Xi
Risk Statements 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany 3
RTECS YD4200000
Specification
1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
2.Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Store 1-Tridecanol (CAS NO.112-70-9) in a cool, dry place. Keep container closed when not in use.