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121-44-8

Basic Information
CAS No.: 121-44-8
Name: Triethylamine
Molecular Structure:
Molecular Structure of 121-44-8 (Triethylamine)
Formula: C6H15N
Molecular Weight: 101.19
Synonyms: Triethylamine(7CI,8CI);(Diethylamino)ethane;N,N-Diethylethanamine;AI3-15425;CCRIS 4881;Ethanamine, N,N-diethyl-;HSDB 896;Triaethylamin;Trietilamina;
EINECS: 204-469-4
Density: 0.75 g/cm3
Melting Point: -115 °C
Boiling Point: 90.495 °C at 760 mmHg
Flash Point: 20°F
Solubility: water: 133 g/L (20 °C)
Appearance: colorless liquid
Hazard Symbols: FlammableF,CorrosiveC
Risk Codes: 11-20/21/22-35
Safety: 3-16-26-29-36/37/39-45
Transport Information: UN 1296 3/PG 2
PSA: 3.24000
LogP: 1.34810
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  • Casno:

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    Product name: Triethylamine CAS No.: 121-44-8 Molecule Formula:C6H15N Molecule Weight:101.19 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TEST

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  • Triethylamine

  • Casno:

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  • Triethylamine 121-44-8

  • Casno:

    121-44-8

    Triethylamine 121-44-8

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    Synonyms: (C2H5)3N;(Diethylamino)ethane;ai3-15425;Ethanamine, N,N-diethyl-;ethanamine,n,n-diethyl-;N,N,N-Triethylamine;N,N-Diethylethanamin;n,n-diethyl-ethanamin Triethylamine Chemical Properties mp -115 °C bp 90 °C density 0.72

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Chemistry

Molecular Structure:

Molecular Formula: C6H15N
Molecular Weight: 101.19
IUPAC Name: N,N-Diethylethanamine
Synonyms of Triethylamine (CAS NO.121-44-8): (Diethylamino)ethane ; AI3-15425 ; CCRIS 4881 ; EINECS 204-469-4 ; Ethanamine, N,N-diethyl- ; HSDB 896 ; N,N-Diethylethanamine ; TEA ; TEN ; Triaethylamin ; Triaethylamin [German] ; Trietilamina ; Trietilamina [Italian] ; Triethylamine [UN1296] [Flammable liquid] ; UN1296
CAS NO: 121-44-8
Classification Code: Human Data ; Mutation data ; Skin / Eye Irritant ; Tumor data
Melting point: -115 °C
Index of Refraction: 1.412
Molar Refractivity: 33.56 cm3
Molar Volume: 134.8 cm3
Surface Tension: 23.4 dyne/cm
Density: 0.75 g/cm3
Enthalpy of Vaporization: 31.01 kJ/mol
Boiling Point: 90.5 °C at 760 mmHg
Vapour Pressure: 56.1 mmHg at 25°C

Uses

 Triethylamine (CAS NO.121-44-8) is commonly used in organic synthesis as a base, most often in the preparation of amides  and esters from acyl chlorides. Like other tertiary amines it catalyzes the formation of urethane foams and epoxy resins. It is also useful in dehydrohalogenation reactions and Swern oxidations. It is also the active ingredient for FlyNap, a product for anesthetizing Drosophila melanogaster.
 

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LCLo inhalation 1000ppm/4H (1000ppm)   Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 2, 1948.
human TCLo inhalation 6500ug/m3/4H (6.5mg/m3) SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE

SENSE ORGANS AND SPECIAL SENSES: CORNEAL DAMAGE: EYE

SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
Occupational and Environmental Medicine. Vol. 56, Pg. 1, 1999.
human TCLo inhalation 12mg/m3/11W-C (12mg/m3) SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE International Archives of Occupational and Environmental Health. Vol. 57, Pg. 297, 1986.
human TCLo inhalation 20mg/m3/8H (20mg/m3) SENSE ORGANS AND SPECIAL SENSES: CORNEAL DAMAGE: EYE Weisheng Dulixue Zazhi. Journal of Health Toxicology. Vol. 4, Pg. 45, 1990.
mammal (species unspecified) LC50 inhalation 6gm/m3 (6000mg/m3)   Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
mouse LC50 inhalation 6gm/m3 (6000mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: FATTY LIVER DEGERATION
Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 7, Pg. 56, 1965.
mouse LD50 intraperitoneal 405mg/kg (405mg/kg)   Yakugaku Zasshi. Journal of Pharmacy. Vol. 97, Pg. 1117, 1977.
mouse LD50 oral 546mg/kg (546mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: MUSCLE WEAKNESS

BEHAVIORAL: EXCITEMENT
Hygiene and Sanitation Vol. 30(7-9), Pg. 351, 1965.
rabbit LD50 skin 570uL/kg (0.57mL/kg)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 119, 1951.
rat LCLo inhalation 1000ppm/4H (1000ppm)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 119, 1951.
rat LD50 oral 460mg/kg (460mg/kg)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 119, 1951.
rat LDLo intraperitoneal 75mg/kg (75mg/kg)   Farmakologiya i Toksikologiya Vol. 31, Pg. 238, 1968.

Safety Profile

Hazard Codes of Triethylamine (CAS NO.121-44-8): FlammableF,CorrosiveC
Risk Statements: 11-20/21/22-35 
R11: Highly flammable. 
R20/22: Harmful by inhalation and if swallowed. 
R35: Causes severe burns.
Safety Statements: 3-16-26-29-36/37/39-45 
S3: Keep in a cool place. 
S16: Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S29: Do not empty into drains. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 1296 3/PG 2
WGK Germany: 1
RTECS: YE0175000
F: 34
Hazard Note: Highly Flammable/Corrosive
HazardClass: 3
PackingGroup: II
HS Code: 29211910