- 2-(2-Methoxyphenoxy)ethylamine
- 2-(2-Methoxyphenoxy)ethylamine hydrochloride
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Cas Database |
| Name |
2-(2-Methoxyphenoxy)ethylamine |
EINECS | 606-000-2 |
| CAS No. | 1836-62-0 | Density | 1.06 g/cm3 |
| PSA | 44.48000 | LogP | 1.73300 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C9H13NO2 | Boiling Point | 261.1 °C at 760 mmHg |
| Molecular Weight | 167.208 | Flash Point | 120.7 °C |
| Transport Information | UN 2735 | Appearance | Colorless or slightly yellowish liquid |
| Safety | Risk Codes | 22 | |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Ethylamine,2-(o-methoxyphenoxy)- (7CI,8CI);2-(o-Methoxyphenoxy)ethylamine;Guaiacoxyethylamine; |
Article Data | 28 |
2-(2-Methoxyphenoxy)ethylamine Synthetic route
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| With hydrogenchloride for 21h; Reflux; | 100% |
| Stage #1: N-[2-(2-methoxyphenoxy)ethyl]acetamide With hydrogenchloride; water for 4h; Heating / reflux; Stage #2: With sodium hydroxide In water pH=8 - 9; | 74.8% |
- 64464-07-9
2-[(2-methoxy)phenoxy]ethylamine hydrochloride
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 0℃; pH=12 - 14; | 97% |
- 26646-63-9
2-[2-(2-methoxyphenoxy)ethyl]-1H-isoindole-1,3(2H)-dione
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 110℃; for 7h; | 91.2% |
| With hydrazine hydrate In water at 20℃; for 5h; Gabriel synthesis; | 86% |
| With hydrazine hydrate; acetic acid In methanol for 4h; Reflux; | 86% |
- 214778-48-0
2-(2-Methoxy-phenoxy)-ethyl-carbamic acid tert-butyl ester
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| Stage #1: 2-(2-Methoxy-phenoxy)-ethyl-carbamic acid tert-butyl ester With hydrogenchloride In 1,4-dioxane for 2h; Heating / reflux; Stage #2: With sodium hydroxide In water; ethyl acetate | 90% |
| With trifluoroacetic acid In dichloromethane | 88% |
- 183427-87-4
2-(2-methoxyphenoxy)acetamide
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| With dimethylsulfide borane complex In tetrahydrofuran at 90℃; for 16h; Inert atmosphere; | 88% |
| With dimethylsulfide borane complex In diethylene glycol dimethyl ether at 90℃; for 18h; | 55% |
| With diethylene glycol dimethyl ether; diborane |
- 4463-59-6
2-(methoxyphenoxy)ethylbromide
A
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
B
- 3258-70-6
2-(2-methoxyphenoxy)-N-[2-(2-methoxyphenoxy)ethyl]ethanamine
| Conditions | Yield |
|---|---|
| With ammonia |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 3 steps 1: aq. NaOH / 7 h / 100 °C 2: dimethylformamide / Heating 3: NH2NH2*H2O / ethanol / Heating View Scheme | |
| Multi-step reaction with 2 steps 1.1: NaOEt / ethanol / 0.5 h / Heating 1.2: 83 percent / KI / ethanol / Heating 2.1: 55 percent / BH3*Me2S / bis-(2-methoxy-ethyl) ether / 18 h / 90 °C View Scheme | |
| Multi-step reaction with 3 steps 1: NaOH / H2O / 100 °C 2: dimethylformamide / 0.5 h 3: hydrazine hydrate / ethanol / 0.75 h / Heating View Scheme |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: dimethylformamide / Heating 2: NH2NH2*H2O / ethanol / Heating View Scheme | |
| Multi-step reaction with 2 steps 1: dimethylformamide / 0.5 h 2: hydrazine hydrate / ethanol / 0.75 h / Heating View Scheme | |
| Stage #1: 2-(methoxyphenoxy)ethylbromide With 18-crown-6 ether; potassium phtalimide In N,N-dimethyl-formamide at 50℃; for 3h; Gabriel Amine Synthesis; Stage #2: With methylamine In water at 50℃; for 2h; Gabriel Amine Synthesis; Stage #3: With sodium hydroxide In water at 20℃; for 1h; Gabriel Amine Synthesis; | |
| Multi-step reaction with 2 steps 1.1: 18-crown-6 ether / N,N-dimethyl-formamide / 3 h / 50 °C 2.1: methylamine / water / 2 h / 50 °C 2.2: 1 h / 20 °C View Scheme |
- 136918-14-4
phthalimide
- 53815-60-4
1-(2-chloroethoxy)-2-methoxybenzene
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| With water; sodium hydroxide at 130℃; for 13h; |
- 53815-60-4
1-(2-chloroethoxy)-2-methoxybenzene
- 1836-62-0
2-(2-methoxy-phenoxy)-ethylamine
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: tetrabutylammomium bromide / 180 - 185 °C 2: water; potassium hydroxide / 13 h / 130 °C View Scheme |
2-(2-Methoxyphenoxy)ethylamine Chemical Properties
IUPAC Name: 2-(2-Methoxyphenoxy)ethanamine
Following is the structure of Ethanamine,2-(2-methoxyphenoxy)- (CAS NO.1836-62-0):
Empirical Formula: C9H13NO2
Molecular Weight: 167.205
Index of Refraction: 1.518
Molar Refractivity: 47.77 cm3
Molar Volume: 157.6 cm3
Density: 1.06 g/cm3
Flash Point: 120.7 °C
Surface Tension: 37.2 dyne/cm
Enthalpy of Vaporization: 49.88 kJ/mol
Boiling Point: 261.1 °C at 760 mmHg
Vapour Pressure of Ethanamine,2-(2-methoxyphenoxy)- (CAS NO.1836-62-0): 0.0118 mmHg at 25 °C
Product Categories of Ethanamine,2-(2-methoxyphenoxy)- (CAS NO.1836-62-0): Anilines, Aromatic Amines and Nitro Compounds; Amines; (intermediate of carvedilol); Carvedilol Intermediate
Canonical SMILES: COC1=CC=CC=C1OCCN
InChI: InChI=1S/C9H13NO2/c1-11-8-4-2-3-5-9(8)12-7-6-10/h2-5H,6-7,10H2,1H3
InChIKey: CKJRKLKVCHMWLV-UHFFFAOYSA-N
2-(2-Methoxyphenoxy)ethylamine Safety Profile
Hazard Codes: 
Xi
RIDADR: UN2735
HazardClass: 8
PackingGroup: III
2-(2-Methoxyphenoxy)ethylamine Specification
Ethanamine,2-(2-methoxyphenoxy)- , its cas register number 1836-62-0. It also can be called 2-(2-Methoxyphenoxy)ethanamin ; and 2-(2-Methoxyphenoxy)ethanamine .
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