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Conditions | Yield |
---|---|
With sodium hydroxide; cetylpyridinium bromide for 2h; Heating; | 95% |
With sodium hydroxide In water at 65 - 95℃; Reagent/catalyst; | 94.6% |
With sodium hydroxide at 20℃; for 4h; | 80% |
1,2,3-trichloropropane
A
2,3-Dichloroprop-1-ene
B
1,2-propanediene
C
3-chloroprop-1-ene
Conditions | Yield |
---|---|
In sodium hydroxide at 45℃; for 4h; electrolysis; | A n/a B n/a C 60% |
In sodium hydroxide at 45℃; for 4h; Product distribution; electrolysis; variation of concentration of NaOH; | A n/a B n/a C 60% |
Conditions | Yield |
---|---|
With chlorine at 512℃; | |
With chlorine | |
With oxygen; chlorine at 0℃; im Dunkeln; |
Conditions | Yield |
---|---|
With hydrogenchloride; mercury dichloride In acetic acid |
methanol
1,2,3-trichloropropane
A
2,3-Dichloroprop-1-ene
B
1,2-Dichlor-3-methoxy-propane
C
(Z)-1,3-dichloropropene
D
2-chloro-3-methoxypropene
F
(E)-1,3-dichloro-prop-1-ene
Conditions | Yield |
---|---|
With aluminium at 250℃; Product distribution; Mechanism; other temp.; |
Conditions | Yield |
---|---|
In gas at 336.9 - 451.9℃; under 10.5 Torr; Kinetics; Product distribution; |
chlorine
3-chloroprop-1-ene
A
2,3-Dichloroprop-1-ene
B
(Z)-1,3-dichloropropene
C
3,3-dichloropropene
D
(E)-1,3-dichloro-prop-1-ene
Conditions | Yield |
---|---|
at 510℃; nach Vorwaermen auf 100grad; | |
at 510℃; nach Vorwaermen auf 100grad; |
Conditions | Yield |
---|---|
at 0℃; im Dunkeln; |
2,3-Dichloroprop-1-ene
Conditions | Yield |
---|---|
With water |
The 2,3-Dichloropropene is an organic compound with the formula C3H4Cl2. The IUPAC name of this chemical is 2,3-dichloroprop-1-ene. With the CAS registry number 78-88-6, it is also named as 1-propene, 2,3-dichloro-. The product's categories are Alkenyl; Halogenated Hydrocarbons; Organic Building Blocks. Besides, it is a clear colorless to pink-brownish liquid, which should be stored in a cool dry and well-ventilated area which be away from incompatible substances. It used as a dwarf-like pigment intermediates.
Physical properties about 2,3-Dichloropropene are: (1)ACD/LogP: 2.19; (2)ACD/LogD (pH 5.5): 2.19; (3)ACD/LogD (pH 7.4): 2.19; (4)ACD/BCF (pH 5.5): 26.96; (5)ACD/BCF (pH 7.4): 26.96; (6)ACD/KOC (pH 5.5): 367.85; (7)ACD/KOC (pH 7.4): 367.85; (8)#Freely Rotating Bonds: 1; (9)Index of Refraction: 1.439; (10)Molar Refractivity: 25.21 cm3; (11)Molar Volume: 95.7 cm3; (12)Polarizability: 9.99×10-24cm3; (13)Surface Tension: 24.7 dyne/cm; (14)Density: 1.159 g/cm3; (15)Flash Point: 18.7 °C; (16)Enthalpy of Vaporization: 32.29 kJ/mol; (17)Boiling Point: 97.3 °C at 760 mmHg; (18)Vapour Pressure: 48 mmHg at 25°C.
Preparation: this chemical can be prepared by 1,2,3-trichloro-propane. This reaction will need reagent potash.
Uses of 2,3-Dichloropropene: it can be used to produce 1-(2-chloro-allyl)-piperidine by heating. It will need reagent K2CO3, KI and solvent acetonitrile with reaction time of 6 hours. The yield is about 77%.
When you are using this chemical, please be cautious about it as the following:
It is highly flammable and harmful by inhalation, in contact with skin and if swallowed and harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. You should keep container in a well-ventilated place, keep away from sources of ignition - No smoking, do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to respiratory system and skin. It limited evidence of a carcinogenic effect and risk of serious damage to eyes. When you are using it, wear suitable gloves and eye/face protection. Avoid release to the environment. Refer to special instructions/safety data sheet.
You can still convert the following datas into molecular structure:
(1)SMILES: Cl/C(=C)CCl
(2)InChI: InChI=1/C3H4Cl2/c1-3(5)2-4/h1-2H2
(3)InChIKey: FALCMQXTWHPRIH-UHFFFAOYAN
(4)Std. InChI: InChI=1S/C3H4Cl2/c1-3(5)2-4/h1-2H2
(5)Std. InChIKey: FALCMQXTWHPRIH-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LC50 | inhalation | 3100mg/m3/2H (3100mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 48, 1982. | |
rabbit | LD50 | skin | 1580uL/kg (1.58mL/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. | |
rat | LCLo | inhalation | 500ppm/4H (500ppm) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. | |
rat | LD50 | oral | 320mg/kg (320mg/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. |