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Name |
2,4-Dichlorophenoxyacetic acid |
EINECS | 202-361-1 |
CAS No. | 94-75-7 | Density | 1.488 g/cm>3 |
PSA | 46.53000 | LogP | 2.45680 |
Solubility | slightly soluble in water; decomposes: 0.0890 g/100 mL | Melting Point |
137 °C |
Formula | C8H6Cl2O3 | Boiling Point | 345.6 °C at 760 mmHg |
Molecular Weight | 221.04 | Flash Point | 162.8 °C |
Transport Information | UN 3077 9/PG 3 | Appearance | light yellow crystalline powder |
Safety | 24/25-26-36/37/39-46-61-2-45-36/37-27-16 | Risk Codes | 22-37-41-43-52/53-39/23/24/25-23/24/25-36/37/38-11 |
Molecular Structure | Hazard Symbols | Xn,Xi,T,F | |
Synonyms |
Aceticacid, (2,4-dichlorophenoxy)- (7CI,8CI,9CI);(2,4-Dichlorophenoxy)acetic acid;2,4-Dichlorophenoxyacetic acid ester;2,4-Dichlorophenoxyethanoic acid;2,4-PA;2-(2,4-Dichlorophenoxy)acetic acid;Aminopielik 50SL;Amoxone;B-Selektonon;Barrage HF;Barrage hydrofluoride;Basalcoat;Deherban;Desormone;Dezormon;Diclordon;Dicopur;Esterone;Fernimine;Foredex 75;HM 2010;Hedonal;Hedonal(herbicide);Huragan;Ipaner;Isadiamineyeom;Monosan herbi;Mota Maskros;NSC190751;NSC 2925;Netagrone;Pielik;Tiller S;Unison;Verton 2D;Vidon638;2,4-D series; |
Article Data | 141 |
Conditions | Yield |
---|---|
With hydrogenchloride; para-dodecylbenzenesulfonic acid In water at 160℃; for 1h; Temperature; Reagent/catalyst; | 99.6% |
With toluene-4-sulfonic acid In water at 106℃; for 3h; | 99.9% |
With hydrogenchloride; water for 3h; Reflux; | 98.3% |
Conditions | Yield |
---|---|
With (phthalocyaninato)iron(II); chlorine; acetic acid In water at 75℃; for 0.5h; Concentration; Time; | 99.8% |
With dihydrogen peroxide; chlorine In benzene at 100℃; for 1h; | 99% |
With iron(III) chloride; dimethylsulfide; chlorine In chloroform at 70℃; for 5h; Reagent/catalyst; Solvent; Temperature; | 99.4% |
Conditions | Yield |
---|---|
Stage #1: bromoacetic acid With water; potassium hydroxide at 110℃; for 2h; Green chemistry; Stage #2: 2,4-dichlorophenol With water; sodium hydroxide at 100 - 130℃; for 4.5h; Green chemistry; Stage #3: With sulfuric acid at 140℃; under 3000.3 Torr; for 2h; Green chemistry; | 99.8% |
Conditions | Yield |
---|---|
With N-chloro-N-(benzenesulfonyl)benzenesulfonamide In acetonitrile at 20 - 25℃; for 0.0833333h; Green chemistry; | 99.7% |
With hydrogenchloride; sodium chlorate; acetic acid |
Conditions | Yield |
---|---|
Stage #1: chloroacetic acid With sodium hydroxide In water for 1h; Stage #2: 2,4-dichlorophenol With potassium hydroxide In water for 1h; Stage #3: With tetrabutylammomium bromide; potassium bromide In water at 130℃; for 2h; Reagent/catalyst; Temperature; | 99.6% |
Stage #1: chloroacetic acid With water; sodium carbonate at 100℃; for 1h; Green chemistry; Stage #2: 2,4-dichlorophenol With water; potassium hydroxide at 90 - 100℃; for 6h; Green chemistry; Stage #3: With hydrogenchloride In water at 150℃; under 4500.45 Torr; for 2h; Reagent/catalyst; Temperature; Green chemistry; | 99.7% |
With sodium hydroxide Irradiation; | 95% |
Conditions | Yield |
---|---|
With sodium hydroxide at 100℃; for 2h; | 99.5% |
With water; sodium hydroxide for 0.5h; Reflux; | 99.5% |
With water; sodium hydroxide for 0.5h; Reflux; | 99.6% |
methyl 2,4-dichlorophenoxyacetate
A
2,4-Dichlorophenoxyacetic acid
B
methylene chloride
Conditions | Yield |
---|---|
With hydrogenchloride; zinc(II) chloride In water at 140℃; for 4h; Reagent/catalyst; Temperature; | A 99.6% B 98.1% |
Conditions | Yield |
---|---|
With sulfuric acid for 3h; Reagent/catalyst; Reflux; | 99.5% |
With sulfuric acid for 3h; Reflux; | 99.3% |
With hydrogenchloride In water for 6h; Reagent/catalyst; Reflux; | 222 g |
Conditions | Yield |
---|---|
With water; sodium hydroxide Reflux; | 99.5% |
With sulfuric acid at 90℃; for 2h; Large scale; | 2202.1 g |
With hydrogenchloride In water at 60℃; for 4h; Large scale; | 2200.7 g |
With hydrogenchloride; water at 60℃; for 4h; Large scale; | 2196.3 g |
With hydrogenchloride In water at 60℃; for 4h; | 219.49 g |
Conditions | Yield |
---|---|
With water; sodium hydroxide for 0.5h; Reflux; | 99.3% |
With toluene-4-sulfonic acid In water; butan-1-ol at 120℃; for 2h; | 99.3% |
Stage #1: Fernesta With sodium hydroxide at 100℃; for 23h; Stage #2: With sulfuric acid | 2200 kg |
IUPAC Name: 2-(2,4-Dichlorophenoxy)acetic acid
Molecular Formula: C8H6Cl2O3
Molecular Weight: 221.04g/mol
EINECS: 202-361-1
Melting Point: 137-141 ºC
Freely Rotating Bonds: 3
Polar Surface Area: 35.53 Å2
Index of Refraction: 1.572
Molar Refractivity: 48.91 cm3
Molar Volume: 148.4 cm3
Polarizability: 19.39 ×10-24cm3
Surface Tension: 51.2 dyne/cm
Density: 1.488 g/cm3
Flash Point: 162.8 °C
Enthalpy of Vaporization: 62.24 kJ/mol
Boiling Point: 345.6 °C at 760 mmHg
Vapour Pressure: 2.31E-05 mmHg at 25°C
The Cas Register Number of 2,4-D Acid is 94-75-7 .The chemical synonyms of 2,4-D Acid (CAS No. 94-75-7) are Rarechem al bo 0361 ; Verton(r) ; Weedar(r) ; (2,4-Dichloor-fenoxy)-azijnzuur ; (2,4-Dichlorophenoxy)-aceticaci ; (2,4-Dichlorophenyloxy)acetic acid ; (2,4-Dichlorphenoxy)acetic acid ; (2,4-Dichlor-phenoxy)-essigsaeure .Product categories of 2,4-D Acid (CAS No. 94-75-7) are Pharmaceutical raw materials ; Acetics acid and esters ; Organic acids ; Plant growth regulator ; Analytical chemistry ; Auxins ; Biochemistry ; Chlorinated compounds (environmental endocrine disruptors) ; Environmental endocrine disruptors ; Plant growth regulators ; Aromatics ; Da - dhmethod specific ; Pesticidespesticides&Metabolites ; Alphabetic ; D ; Endocrine disruptors (draft)Method specific ; EPA ; Herbicides ; Oeko-tex standard 100 ; Phenoxy structure .The molecular structure of 2,4-D Acid (CAS No. 94-75-7) is.
1. | ratLD50:1500mg/kg | World Review of Pest Control. Vol. 9, Pg. 119, 1970. | ||
2. | ratLD50:375mg/kg | Farm Chemicals Handbook. Vol. -, Pg. C174, 1991. | ||
3. | rabbitLDLo:800mg/kg | Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 12, Pg. 26, 1951. | ||
4. | mouseLD50:347mg/kg | Roczniki Panstwowego Zakladu Higieny. Vol. 31, Pg. 373, 1980. |
Hazard Codes: Xn Xi T F
Risk Statements: 22-37-41-43-52/53-39/23/24/25-23/24/25-36/37/38-11
R22: Harmful if swallowed.
R37: Irritating to respiratory system
R41: Risk of serious damage to the eyes.
R43: May cause sensitization by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
R11: Highly flammable.
Safety Statements: 24/25-26-36/37/39-46-61-2-45-36/37-27-16
S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S46: If swallowed, seek medical advice immediately and show this container or label.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
S2: Keep out of the reach of children.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37: Wear suitable protective clothing and gloves.
S27: Take off immediately all contaminated clothing.
S16: Keep away from sources of ignition.
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
RTECS: AG6825000
HazardClass: 6.1
PackingGroup: III
HS Code: 29189090