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Name	2-Amino-3-hydroxyphenazine	EINECS	N/A
CAS No.	4569-77-1	Density	1.46g/cm³
PSA	72.03000	LogP	2.65200
Solubility	N/A	Melting Point	>300℃
Formula	C12H9 N3 O	Boiling Point	381.6°Cat760mmHg
Molecular Weight	211.223	Flash Point	184.6°C
Transport Information	N/A	Appearance	N/A
Safety	Mutation data reported. When heated to decomposition it emits toxic vapors of NO_x.	Risk Codes	N/A
Molecular Structure		Hazard Symbols
Synonyms	2-Amino-3-hydroxyphenazine;2-Hydroxy-3-aminophenazine; 3-Amino-2-hydroxyphenazine; 3-Amino-2-phenazinol;NSC 52575	Article Data	19

2-Amino-3-hydroxyphenazine Synthetic route

: 95-54-5
1,2-diamino-benzene

A: 655-86-7
2,3-diaminephenazine

B: 4569-77-1
2-amino-3-hydroxy-phenazine

Conditions

Conditions	Yield
With hydrogenchloride; iron(III) chloride at 20℃;	A 78% B n/a
With hydrogenchloride; iron(III) chloride
With hydrogenchloride; iron(III) chloride at 20℃; under 760 Torr; Title compound not separated from byproducts;

: 775347-31-4
2-amino-5-hydroxy-[1,4]benzoquinone

: 39145-59-0
o-phenylenediamine hydrochloride

: 4569-77-1
2-amino-3-hydroxy-phenazine

Conditions

Conditions	Yield
With ethanol

: 95-54-5
1,2-diamino-benzene

: 4569-77-1
2-amino-3-hydroxy-phenazine

Conditions

Conditions	Yield
With hydrogenchloride; iron(III) chloride In water at 60 - 70℃;

: 4569-77-1
2-amino-3-hydroxy-phenazine

: 95-54-5
1,2-diamino-benzene

: 111076-33-6
5,14-dihydro-5,7,12,14-tetraazapentacene

Conditions

Conditions	Yield
With hydrogenchloride; sodium chloride In water at 320℃; for 0.0833333h;	100%

: 4569-77-1
2-amino-3-hydroxy-phenazine

: C12H8N3O(1-)*Na(1+)

Conditions

Conditions	Yield
With sodium hydroxide In ethanol at 20℃;	98%

: 4569-77-1
2-amino-3-hydroxy-phenazine

: 3171-45-7
4,5-dimethyl-1,2-phenylenediamine

: 8,9-dimethyl-5,14-dihydro-5,7,12,14-tetraazapentacene

Conditions

Conditions	Yield
With hydrogenchloride; sodium chloride In water at 320℃; for 0.0833333h;	95%

: 4569-77-1
2-amino-3-hydroxy-phenazine

: 446-52-6
2-Fluorobenzaldehyde

: 105-56-6
ethyl 2-cyanoacetate

: ethyl 3,5-diamino-1-(2-fluorophenyl)-1H-pyrano[3,2-a]phenazine-2-carboxylate

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol Reflux;	93%

: 4569-77-1
2-amino-3-hydroxy-phenazine

: 89-98-5
2-chloro-benzaldehyde

: 109-77-3
malononitrile

: 3,5-diamino-1-(2-chlorophenyl)-1H-pyrano[3,2-a]phenazine-2-carbonitrile

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol Reflux;	91%

: 3132-99-8
m-bromobenzoic aldehyde

: 4569-77-1
2-amino-3-hydroxy-phenazine

: 105-56-6
ethyl 2-cyanoacetate

: ethyl 3,5-diamino-1-(3-bromophenyl)-1H-pyrano[3,2-a]phenazine-2-carboxylate

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol Reflux;	90%

: 4569-77-1
2-amino-3-hydroxy-phenazine

: 100-52-7
benzaldehyde

: 109-77-3
malononitrile

: C22H15N5O

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In ethanol Reflux; Inert atmosphere;	89%

2-Amino-3-hydroxyphenazine Chemical Properties

The IUPAC name of 2-Amino-3-hydroxyphenazine (CAS NO.4569-77-1): 3-Amino-10H-phenazin-2-one
Synonyms: 2-Amino-3-phenazinol ; 3-Amino-2-phenazino ; 3-Amino-2-Phenazinol
CAS: 4569-77-1
Molecular Formula:C₁₂H₉N₃O
Molecular Structure:

Formula Weight: 211.22 g/mol
Index of Refraction: 1.758
Density: 1.46 g/cm³
Flash Point: 184.6 °C
Boiling Point: 381.6 °C at 760 mmHg

2-Amino-3-hydroxyphenazine Toxicity Data With Reference

The toxicity information of 2-Amino-3-hydroxyphenazine (CAS NO.4569-77-1):

mic-bac-sat 80 ng/plate

MUREAV Mutation Research. 321 (1994),43.

2-Amino-3-hydroxyphenazine Safety Profile

The Hazard Codes of 2-Amino-3-hydroxyphenazine (CAS NO.4569-77-1): Irritant Xi
Mutation data reported. When heated to decomposition it emits toxic vapors of NO_x.

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