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2-ETHYLHEXYLOXYPROPYLAMINE
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Name

2-ETHYLHEXYLOXYPROPYLAMINE

 EINECS 226-420-6
CAS No. 5397-31-9 Density 0.849 g/cm3
PSA 35.25000 LogP 3.26850
Solubility Slightly soluble in water Melting Point N/A
Formula C11H25NO Boiling Point 262.4 °C at 760 mmHg
Molecular Weight 187.326 Flash Point 96.1 °C
Transport Information UN 2922 8/PG 3 Appearance Colorless liquid
Safety 26-27-36-45 Risk Codes 22-24-34-52
Molecular Structure Molecular Structure of 5397-31-9 (2-Ethylhexyloxypropylamine) Hazard Symbols ToxicT
Synonyms

Propylamine,3-[(2-ethylhexyl)oxy]- (6CI,7CI,8CI);2-Ethylhexyl 3-aminopropyl ether;3-(2-Ethylhexoxy)propylamine;3-(2-Ethylhexyloxy)-1-propanamine;3-(2-Ethylhexyloxy)propylamine;3-Aminopropyl 2-ethylhexyl ether;NSC 1078;PA12EH;

 

2-ETHYLHEXYLOXYPROPYLAMINE Synthetic route

10213-75-9

3-(2-ethyl-hexyloxy)-propionitrile

5397-31-9

3-(2-ethylhexoxy)propylamine

Conditions
ConditionsYield
With ammonia; nickel at 60 - 100℃; under 51485.6 Torr; Hydrogenation;
2461-15-6

2-ethyl-hexyl glycidyl ether

5397-31-9

3-(2-ethylhexoxy)propylamine

C33H69NO5

Conditions
ConditionsYield
at 60 - 120℃; for 10.67h;98%
5397-31-9

3-(2-ethylhexoxy)propylamine

66003-78-9

triphenylsulfonium trifluoromethanesulfonate

N-(3-((2-ethylhexyl)oxy)propyl)-N-phenylaniline

Conditions
ConditionsYield
With potassium tert-butylate In toluene at 80℃; for 24h; Inert atmosphere; Sealed tube; Glovebox;98%
5397-31-9

3-(2-ethylhexoxy)propylamine

10213-75-9

3-(2-ethyl-hexyloxy)-propionitrile

Conditions
ConditionsYield
With nickel(II) sulphate; sodium hydroxide; dipotassium peroxodisulfate In dichloromethane for 24h; Ambient temperature;96%
With sodium hypochlorite In ethanol for 0.25h; Ambient temperature;67%
With oxygen; RuHAP In toluene at 110℃; for 24h;94 % Chromat.
5397-31-9

3-(2-ethylhexoxy)propylamine

81-86-7

4-bromo-1,8-naphthalenedicarboxylic anhydride

C23H28BrNO3

Conditions
ConditionsYield
In ethanol at 50℃; for 8h;95.6%
5397-31-9

3-(2-ethylhexoxy)propylamine

875-35-4

2,6-dichloro-4-methylnicotinonitrile

861395-95-1

C29H52N4O2

Conditions
ConditionsYield
In water at 120℃; for 4h;93.2%
5397-31-9

3-(2-ethylhexoxy)propylamine

4,4-dimethyl pyroglutamine acid

1311195-37-5

C18H36N2O4

Conditions
ConditionsYield
In methanol at 70℃; for 3h;93%
5397-31-9

3-(2-ethylhexoxy)propylamine

81-86-7

4-bromo-1,8-naphthalenedicarboxylic anhydride

C34H52N2O4

Conditions
ConditionsYield
at 120℃; for 8h;75.6%
5397-31-9

3-(2-ethylhexoxy)propylamine

118129-60-5

1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride

1444106-92-6

C46H52Br2N2O6

Conditions
ConditionsYield
With butyric acid In 1-methyl-pyrrolidin-2-one at 150℃; for 24h; Inert atmosphere;70%
In 1-methyl-pyrrolidin-2-one; acetic acid at 150℃; for 24h; Inert atmosphere;70%
5397-31-9

3-(2-ethylhexoxy)propylamine

66003-78-9

triphenylsulfonium trifluoromethanesulfonate

N-(3-((2-ethylhexyl)oxy)propyl)aniline

Conditions
ConditionsYield
With potassium tert-butylate In toluene at 80℃; for 28h; Glovebox; Inert atmosphere; Sealed tube;65%

2-ETHYLHEXYLOXYPROPYLAMINE Chemical Properties

IUPAC Name: 2-Ethylhexyloxypropylamine
The MF of 2-Ethylhexyloxypropylamine (5397-31-9) is C11H25NO.

                                 
The MW of 2-Ethylhexyloxypropylamine (5397-31-9) is 187.32.
Synonyms of 2-Ethylhexyloxypropylamine (5397-31-9): 2-Ethylhexyloxypropylamine ; 1-Propanamine, 3-[(2-ethylhexyl)oxy]- ; 3-(2-Ethylhexyloxy)-propylamine ; 3-[(2-ethylhexyl)oxy]propan-1-amine ; 3-[(2-Ethylhexyl)oxy]-1-propanamine 
Product Categories: Industrial/Fine Chemicals;Amines;C11 to C38;Nitrogen Compounds
Water Solubility: 0.1-0.5 g/100 mL at 20.5 ºC 
Index of Refraction: 1.441 
Form: Colorless liquid
EINECS: 226-420-6
Density: 0.849 g/ml 
Flash Point: 96.1 °C
Boiling Point: 262.4 °C

2-ETHYLHEXYLOXYPROPYLAMINE Uses

   2-Ethylhexyloxypropylamine (5397-31-9) is used as a dye intermediate.

2-ETHYLHEXYLOXYPROPYLAMINE Toxicity Data With Reference

1.    

skn-rbt 10 mg/24H open SEV

     AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.
2.    

eye-rbt 50 µg open SEV

     AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.
3.    

orl-rat LD50:320 mg/kg

     AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.
4.    

skn-rbt LD50:360 mg/kg

     AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.

2-ETHYLHEXYLOXYPROPYLAMINE Consensus Reports

Reported in EPA TSCA Inventory.

2-ETHYLHEXYLOXYPROPYLAMINE Safety Profile

Poison by ingestion and skin contact. A severe skin and eye irritant. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of NOx. See also ETHERS and AMINES.
Safety information of 2-Ethylhexyloxypropylamine (5397-31-9):
Hazard Codes  T
Risk Statements 
22  Harmful if swallowed
24  Toxic in contact with skin
34  Causes burns
52  Harmful to aquatic organisms
Safety Statements 
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27  Take off immediately all contaminated clothing
36  Wear suitable protective clothing
45  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR  UN 2922 8/PG 3
WGK Germany  3
RTECS  UI2820000

2-ETHYLHEXYLOXYPROPYLAMINE Specification

 2-Ethylhexyloxypropylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

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