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| CAS No.: | 5397-31-9 |
|---|---|
| Name: | 2-Ethylhexyloxypropylamine |
| Molecular Structure: | |
|
|
|
| Formula: | C11H25NO |
| Molecular Weight: | 187.326 |
| Synonyms: | Propylamine,3-[(2-ethylhexyl)oxy]- (6CI,7CI,8CI);2-Ethylhexyl 3-aminopropyl ether;3-(2-Ethylhexoxy)propylamine;3-(2-Ethylhexyloxy)-1-propanamine;3-(2-Ethylhexyloxy)propylamine;3-Aminopropyl 2-ethylhexyl ether;NSC 1078;PA12EH; |
| EINECS: | 226-420-6 |
| Density: | 0.849 g/cm3 |
| Boiling Point: | 262.4 °C at 760 mmHg |
| Flash Point: | 96.1 °C |
| Solubility: | Slightly soluble in water |
| Appearance: | Colorless liquid |
| Hazard Symbols: |
 T
|
| Risk Codes: | 22-24-34-52 |
| Safety: | 26-27-36-45 |
| Transport Information: | UN 2922 8/PG 3 |
| PSA: | 35.25000 |
| LogP: | 3.26850 |
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3-(2-ethyl-hexyloxy)-propionitrile
- 5397-31-9
3-(2-ethylhexoxy)propylamine
| Conditions | Yield |
|---|---|
| With ammonia; nickel at 60 - 100℃; under 51485.6 Torr; Hydrogenation; |
| Conditions | Yield |
|---|---|
| at 60 - 120℃; for 10.67h; | 98% |
- 5397-31-9
3-(2-ethylhexoxy)propylamine
- 66003-78-9
triphenylsulfonium trifluoromethanesulfonate
| Conditions | Yield |
|---|---|
| With potassium tert-butylate In toluene at 80℃; for 24h; Inert atmosphere; Sealed tube; Glovebox; | 98% |
- 5397-31-9
3-(2-ethylhexoxy)propylamine
- 10213-75-9
3-(2-ethyl-hexyloxy)-propionitrile
| Conditions | Yield |
|---|---|
| With nickel(II) sulphate; sodium hydroxide; dipotassium peroxodisulfate In dichloromethane for 24h; Ambient temperature; | 96% |
| With sodium hypochlorite In ethanol for 0.25h; Ambient temperature; | 67% |
| With oxygen; RuHAP In toluene at 110℃; for 24h; | 94 % Chromat. |
| Conditions | Yield |
|---|---|
| In ethanol at 50℃; for 8h; | 95.6% |
- 5397-31-9
3-(2-ethylhexoxy)propylamine
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C29H52N4O2
| Conditions | Yield |
|---|---|
| In water at 120℃; for 4h; | 93.2% |
| Conditions | Yield |
|---|---|
| In methanol at 70℃; for 3h; | 93% |
| Conditions | Yield |
|---|---|
| at 120℃; for 8h; | 75.6% |
- 5397-31-9
3-(2-ethylhexoxy)propylamine
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| Conditions | Yield |
|---|---|
| With butyric acid In 1-methyl-pyrrolidin-2-one at 150℃; for 24h; Inert atmosphere; | 70% |
| In 1-methyl-pyrrolidin-2-one; acetic acid at 150℃; for 24h; Inert atmosphere; | 70% |
- 5397-31-9
3-(2-ethylhexoxy)propylamine
- 66003-78-9
triphenylsulfonium trifluoromethanesulfonate
| Conditions | Yield |
|---|---|
| With potassium tert-butylate In toluene at 80℃; for 28h; Glovebox; Inert atmosphere; Sealed tube; | 65% |
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Chemistry
IUPAC Name: 2-Ethylhexyloxypropylamine
The MF of 2-Ethylhexyloxypropylamine (5397-31-9) is C11H25NO.
The MW of 2-Ethylhexyloxypropylamine (5397-31-9) is 187.32.
Synonyms of 2-Ethylhexyloxypropylamine (5397-31-9): 2-Ethylhexyloxypropylamine ; 1-Propanamine, 3-[(2-ethylhexyl)oxy]- ; 3-(2-Ethylhexyloxy)-propylamine ; 3-[(2-ethylhexyl)oxy]propan-1-amine ; 3-[(2-Ethylhexyl)oxy]-1-propanamine
Product Categories: Industrial/Fine Chemicals;Amines;C11 to C38;Nitrogen Compounds
Water Solubility: 0.1-0.5 g/100 mL at 20.5 ºC
Index of Refraction: 1.441
Form: Colorless liquid
EINECS: 226-420-6
Density: 0.849 g/ml
Flash Point: 96.1 °C
Boiling Point: 262.4 °C
Uses
2-Ethylhexyloxypropylamine (5397-31-9) is used as a dye intermediate.
Toxicity Data With Reference
| 1. | skn-rbt 10 mg/24H open SEV | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. | ||
| 2. | eye-rbt 50 µg open SEV | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. | ||
| 3. | orl-rat LD50:320 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. | ||
| 4. | skn-rbt LD50:360 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by ingestion and skin contact. A severe skin and eye irritant. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of NOx. See also ETHERS and AMINES.
Safety information of 2-Ethylhexyloxypropylamine (5397-31-9):
Hazard Codes .gif){kind=small}
T
Risk Statements
22 Harmful if swallowed
24 Toxic in contact with skin
34 Causes burns
52 Harmful to aquatic organisms
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27 Take off immediately all contaminated clothing
36 Wear suitable protective clothing
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 2922 8/PG 3
WGK Germany 3
RTECS UI2820000
Specification
2-Ethylhexyloxypropylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.