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Cas Database |
| Name |
2-Methoxyethyl acrylate |
EINECS | 221-499-3 |
| CAS No. | 3121-61-7 | Density | 1.012 |
| PSA | 35.53000 | LogP | 0.36200 |
| Solubility | 144g/L at 20℃ | Melting Point |
-30°C |
| Formula | C6H10 O3 | Boiling Point | 56 ºC (12 mmHg) |
| Molecular Weight | 130.144 | Flash Point | 60 ºC |
| Transport Information | UN 1992 | Appearance | Clear colorless liquid with a sharp musty odor. |
| Safety | Poison by skin contact. Moderately toxic by ingestion and inhalation. Experimental reproductive effects. A skin irritant. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS. | Risk Codes | R20/22;R24;R60;R61 |
| Molecular Structure |
|
Hazard Symbols |
|
| Synonyms |
Acrylicacid, 2-methoxyethyl ester (6CI,7CI,8CI); 2-Methoxyethyl acrylate; 2MTA; DC 1;DC 1 (acrylate); Ethylene glycol monomethyl ether acrylate; Methoxyethylacrylate; NSC 24153; SR 244; Viscoat 2MTA |
Article Data | 6 |
2-Methoxyethyl acrylate Synthetic route
| Conditions | Yield |
|---|---|
| With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide In 2-Methylpentane; cyclohexane at 85 - 100℃; for 12h; Temperature; Solvent; | 95% |
| With copper; toluene-4-sulfonic acid; hydroquinone Abdestillieren des entstandenen Methanols als Azeotrop mit Methylacrylat; |
| Conditions | Yield |
|---|---|
| With copper; toluene-4-sulfonic acid; hydroquinone Abdestillieren des entstandenen Aethanols als Azeotrop mit Aethylacrylat; |
| Conditions | Yield |
|---|---|
| With triethylamine In chloroform at 10℃; for 12h; | |
| In dichloromethane |
- 3121-61-7
2-methoxyethyl acrylate
- 31020-47-0
bis((methyldiethoxysilyl)propyl)amine
| Conditions | Yield |
|---|---|
| In ethanol at 20℃; for 8h; Inert atmosphere; | 98.327% |
- 3121-61-7
2-methoxyethyl acrylate
- 13497-18-2
bis-(3-triethoxysilylpropyl)amine
| Conditions | Yield |
|---|---|
| In ethanol at 20℃; for 8h; Inert atmosphere; | 97.3% |
| Conditions | Yield |
|---|---|
| With scandium tris(trifluoromethanesulfonate) In neat (no solvent) at 20℃; for 2h; Green chemistry; regioselective reaction; | 97% |
- 3121-61-7
2-methoxyethyl acrylate
| Conditions | Yield |
|---|---|
| In ethanol at 20℃; for 8h; Inert atmosphere; | 96.7% |
| Conditions | Yield |
|---|---|
| With [RhCl2(p-cymene)]2; potassium acetate In methanol at 70℃; Sealed tube; | 96% |
| With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; acetic acid In methanol at 25℃; for 6h; | 91% |
- 64-17-5
ethanol
- 3121-61-7
2-methoxyethyl acrylate
- 120-46-7
1,3-diphenylpropanedione
- 73172-56-2
ethyl 4-benzoylbutanoate
| Conditions | Yield |
|---|---|
| With potassium carbonate at 85℃; Sealed tube; | 95% |
| Conditions | Yield |
|---|---|
| With palladium diacetate; triethylamine; triphenylphosphine In N,N-dimethyl-formamide at 85℃; for 0.333333h; Time; Heck Reaction; | 93% |
2-Methoxyethyl acrylate Chemical Properties
Product Name: Methyl cellosolve acrylate (CAS NO.3121-61-7)
Molecular Formula: C6H10O3
Molecular Weight: 130.14g/mol
Mol File: 3121-61-7.mol
Einecs: 221-499-3
Appearance: Clear colorless to slightly yellow liquid
Melting Point: -30°C
Boiling point: 151.7 °C at 760 mmHg
Flash Point: 51.8 °C
Density: 1.012 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.427(lit.)
Surface Tension: 27.7 dyne/cm
Enthalpy of Vaporization: 38.85 kJ/mol
Vapour Pressure: 3.62 mmHg at 25°C
XLogP3: 0.3
H-Bond Donor: 0
H-Bond Acceptor: 3
2-Methoxyethyl acrylate Toxicity Data With Reference
| 1. | skn-rbt 500 mg open MLD | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 9/17 ,1969. | ||
| 2. | orl-mus TDLo:5200 mg/kg (female 6-13D post):REP | TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. 7 (1987),29. | ||
| 3. | orl-rat LD50:810 mg/kg | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 9/17 ,1969. | ||
| 4. | ihl-rat LC50:500 ppm/4H | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 9/17 ,1969. | ||
| 5. | skn-rbt LD50:250 mg/kg | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 9/17 ,1969. |
2-Methoxyethyl acrylate Consensus Reports
Glycol ether compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.
2-Methoxyethyl acrylate Safety Profile
Poison by skin contact. Moderately toxic by ingestion and inhalation. Experimental reproductive effects. A skin irritant. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.
Safety Information of Methyl cellosolve acrylate (CAS NO.3121-61-7):
Hazard Codes: T.gif){kind=small}
Risk Statements: 20/22-24-41-61-60
20: Harmful by inhalation
22: Harmful if swallowed
24: Toxic in contact with skin
41: Risk of serious damage to eyes
60: May impair fertility
61: May cause harm to the unborn child
Safety Statements: 16-26-36/37/39-45-53
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
2-Methoxyethyl acrylate Specification
Methyl cellosolve acrylate ,its CAS NO. is 3121-61-7,the synonyms is 2-Methoxy-ethanoacrylate ; 2-Methoxyethanol,acrylate ; 2-Propenoicacid,2-methoxyethylester ; Glycolmonomethyletheracrylate ; Methylcellosolveacrylate ; Sipomermca ; Acrylic acid 2-methoxyethyl ester ; 2-Methoxyethyl acrylate .
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